Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate
The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(8)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geomet...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010
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| Online Access: | http://eprints.um.edu.my/8031/1/Tajidi-2010-Diaqua%281%2C4%2C8%2C11-tetr.pdf |
| _version_ | 1796945679628632064 |
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| author | Tan, Kong Wai Ng, S.W. Tajidi, N.S.A. Abdullah, N. Arifin, Z. |
| author_facet | Tan, Kong Wai Ng, S.W. Tajidi, N.S.A. Abdullah, N. Arifin, Z. |
| author_sort | Tan, Kong Wai |
| collection | UM |
| description | The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(8)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (001). |
| first_indexed | 2024-03-06T05:20:16Z |
| format | Article |
| id | um.eprints-8031 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:20:16Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-80312019-01-30T08:38:47Z http://eprints.um.edu.my/8031/ Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate Tan, Kong Wai Ng, S.W. Tajidi, N.S.A. Abdullah, N. Arifin, Z. QD Chemistry The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)][CH(3)(CH(2))(8)CO(2)](2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (001). International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8031/1/Tajidi-2010-Diaqua%281%2C4%2C8%2C11-tetr.pdf Tan, Kong Wai and Ng, S.W. and Tajidi, N.S.A. and Abdullah, N. and Arifin, Z. (2010) Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66. M888-U293. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810025699 <https://doi.org/10.1107/s1600536810025699>. http://journals.iucr.org/e/issues/2010/08/00/bt5286/bt5286.pdf 10.1107/s1600536810025699 |
| spellingShingle | QD Chemistry Tan, Kong Wai Ng, S.W. Tajidi, N.S.A. Abdullah, N. Arifin, Z. Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate |
| title | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate |
| title_full | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate |
| title_fullStr | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate |
| title_full_unstemmed | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate |
| title_short | Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa4 N1,N4,N8,N11)copper(II) didecanoate dihydrate |
| title_sort | diaqua 1 4 8 11 tetraazacyclotetradecane kappa4 n1 n4 n8 n11 copper ii didecanoate dihydrate |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/8031/1/Tajidi-2010-Diaqua%281%2C4%2C8%2C11-tetr.pdf |
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