N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide
In the title compound, C(30)H(36)N(2)O(2)S, the dihedral angle between the two aromatic rings of the biphenyl residue is 31.2 (1)degrees. The two methylene C atoms subtend an angle of 99.9 (1)degrees at the S atom. In the crystal, molecules form inversion dimers linked by pairs of N-H center dot cen...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010
|
| Subjects: | |
| Online Access: | http://eprints.um.edu.my/8091/1/Yehye-2010-N_%27-_%28Biphenyl-4-yl%29.pdf |
| _version_ | 1825719484277587968 |
|---|---|
| author | Ariffin, Azhar Ng, S.W. Yehye, W.A. Rahman, N.A. |
| author_facet | Ariffin, Azhar Ng, S.W. Yehye, W.A. Rahman, N.A. |
| author_sort | Ariffin, Azhar |
| collection | UM |
| description | In the title compound, C(30)H(36)N(2)O(2)S, the dihedral angle between the two aromatic rings of the biphenyl residue is 31.2 (1)degrees. The two methylene C atoms subtend an angle of 99.9 (1)degrees at the S atom. In the crystal, molecules form inversion dimers linked by pairs of N-H center dot center dot center dot O hydrogen bonds. The hydroxyl group is shielded by the tert-butyl residues and is therefore not involved in any hydrogen bonding. |
| first_indexed | 2024-03-06T05:20:27Z |
| format | Article |
| id | um.eprints-8091 |
| institution | Universiti Malaya |
| language | English |
| last_indexed | 2024-03-06T05:20:27Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-80912019-01-31T01:03:18Z http://eprints.um.edu.my/8091/ N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide Ariffin, Azhar Ng, S.W. Yehye, W.A. Rahman, N.A. QD Chemistry In the title compound, C(30)H(36)N(2)O(2)S, the dihedral angle between the two aromatic rings of the biphenyl residue is 31.2 (1)degrees. The two methylene C atoms subtend an angle of 99.9 (1)degrees at the S atom. In the crystal, molecules form inversion dimers linked by pairs of N-H center dot center dot center dot O hydrogen bonds. The hydroxyl group is shielded by the tert-butyl residues and is therefore not involved in any hydrogen bonding. International Union of Crystallography 2010 Article PeerReviewed application/pdf en http://eprints.um.edu.my/8091/1/Yehye-2010-N_%27-_%28Biphenyl-4-yl%29.pdf Ariffin, Azhar and Ng, S.W. and Yehye, W.A. and Rahman, N.A. (2010) N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide. Acta Crystallographica Section E: Structure Reports Online, 66 (4). O734-U1479. ISSN 1600-5368, DOI https://doi.org/10.1107/s1600536810006884 <https://doi.org/10.1107/s1600536810006884>. http://journals.iucr.org/e/issues/2010/04/00/bt5202/bt5202.pdf 10.1107/s1600536810006884 |
| spellingShingle | QD Chemistry Ariffin, Azhar Ng, S.W. Yehye, W.A. Rahman, N.A. N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide |
| title | N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide |
| title_full | N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide |
| title_fullStr | N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide |
| title_full_unstemmed | N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide |
| title_short | N '- (Biphenyl-4-yl)methylene -2- (3,5-di-tert-butyl-4-hydroxybenzyl)sulfa nyl acetohydrazide |
| title_sort | n biphenyl 4 yl methylene 2 3 5 di tert butyl 4 hydroxybenzyl sulfa nyl acetohydrazide |
| topic | QD Chemistry |
| url | http://eprints.um.edu.my/8091/1/Yehye-2010-N_%27-_%28Biphenyl-4-yl%29.pdf |
| work_keys_str_mv | AT ariffinazhar nbiphenyl4ylmethylene235ditertbutyl4hydroxybenzylsulfanylacetohydrazide AT ngsw nbiphenyl4ylmethylene235ditertbutyl4hydroxybenzylsulfanylacetohydrazide AT yehyewa nbiphenyl4ylmethylene235ditertbutyl4hydroxybenzylsulfanylacetohydrazide AT rahmanna nbiphenyl4ylmethylene235ditertbutyl4hydroxybenzylsulfanylacetohydrazide |