Effects of pure Acoh and mixed AcOH-CS (CS = CH3CN And THF) solvents on the rate of cleavage of Phthalic Anhydride (PAn)
The values of pseudo-first-order rate constants (k (obs)) for the acetolysis of phthalic anhydride (PAn) increase from 6.60 x 10(-7) to 31.5 x 10(-7) s(-1) with the increase in temperature from 30 to 50 A degrees C. These values of k (obs) give activation parameters a dagger H* and a dagger S* as 14...
Main Authors: | Ariffin, Azhar, Khan, M.N., Damit, E.F., Yusof, N.S.M. |
---|---|
Format: | Article |
Published: |
2012
|
Subjects: |
Similar Items
-
Kinetics and mechanism of the cleavage of Phthalic Anhydride in Glacial Acetic Acid Solvent containing Aniline
by: Ariffin, Azhar, et al.
Published: (2008) -
Unusual formation of imidazooxazolone in the reaction of
1-[(2-acetylamino)ethyl]imidazolone with KSCN in the presence of AcOH
by: Vladimir V. Baranov, et al.
Published: (2017-03-01) -
Microwave Assisted Rapid, Efficient and Chemoselective Deoxygenation of Sulfoxides to Thioethers Using Zn / AcOH on Silica Gel
by: Abbas Shockravi, et al.
Published: (2008-06-01) -
Unexpected rate retardation in the formation of phthalic anhydride from N-Methylphthalamic Acid in acidic H2O-CH3CN medium
by: Ariffin, Azhar, et al.
Published: (2005) -
TLR4 as a Potential Target of Me-PFOSA-AcOH Leading to Cardiovascular Diseases: Evidence from NHANES 2013–2018 and Molecular Docking
by: Zhilei Mao, et al.
Published: (2024-09-01)