Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction
In this study aliphatic polyacids were synthesized using palm acid oil (PAO) and sunflower oil (SFO) via addition reaction technique. The synthesized materials were characterized using Fourier-transform infra-red (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, matrix-assisted las...
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| Format: | Article |
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Elsevier
2013
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| _version_ | 1796945765761810432 |
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| author | Zeimaran, E. Kadir, M.R. Nor, H.M. Kamarul, Tunku Djordjevic, I. |
| author_facet | Zeimaran, E. Kadir, M.R. Nor, H.M. Kamarul, Tunku Djordjevic, I. |
| author_sort | Zeimaran, E. |
| collection | UM |
| description | In this study aliphatic polyacids were synthesized using palm acid oil (PAO) and sunflower oil (SFO) via addition reaction technique. The synthesized materials were characterized using Fourier-transform infra-red (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-ToF-MS) and thermo-gravimetric analysis (TGA). Mixing formic acid and hydrogen peroxide with PAO or SFO at the ratio 3:10:1 produced the lowest iodine value of 10.57 and 9.24 respectively, indicating the increase in epoxidization of both oils. Adding adipic acid to the epoxidized oils at a ratio of 1:10 increases the acid values of SFO and PAO to 11.22 and 6.73 respectively. The existence of multi-acid groups present in synthesized polyacid was confirmed by MALD-ToF-MS. This feature indicates a possible value to the biomaterials development. |
| first_indexed | 2024-03-06T05:21:34Z |
| format | Article |
| id | um.eprints-8583 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:21:34Z |
| publishDate | 2013 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | um.eprints-85832018-10-10T08:48:39Z http://eprints.um.edu.my/8583/ Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction Zeimaran, E. Kadir, M.R. Nor, H.M. Kamarul, Tunku Djordjevic, I. R Medicine In this study aliphatic polyacids were synthesized using palm acid oil (PAO) and sunflower oil (SFO) via addition reaction technique. The synthesized materials were characterized using Fourier-transform infra-red (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-ToF-MS) and thermo-gravimetric analysis (TGA). Mixing formic acid and hydrogen peroxide with PAO or SFO at the ratio 3:10:1 produced the lowest iodine value of 10.57 and 9.24 respectively, indicating the increase in epoxidization of both oils. Adding adipic acid to the epoxidized oils at a ratio of 1:10 increases the acid values of SFO and PAO to 11.22 and 6.73 respectively. The existence of multi-acid groups present in synthesized polyacid was confirmed by MALD-ToF-MS. This feature indicates a possible value to the biomaterials development. Elsevier 2013 Article PeerReviewed Zeimaran, E. and Kadir, M.R. and Nor, H.M. and Kamarul, Tunku and Djordjevic, I. (2013) Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction. Bioorganic & Medicinal Chemistry Letters, 23 (24). pp. 6616-6619. ISSN 0960-894X, DOI PMID: 24215893. https://doi.org/10.1016/j.bmcl.2013.10.053 PMID: 24215893 |
| spellingShingle | R Medicine Zeimaran, E. Kadir, M.R. Nor, H.M. Kamarul, Tunku Djordjevic, I. Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction |
| title | Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction |
| title_full | Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction |
| title_fullStr | Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction |
| title_full_unstemmed | Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction |
| title_short | Synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction |
| title_sort | synthesis and characterization of polyacids from palm acid oil and sunflower oil via addition reaction |
| topic | R Medicine |
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