Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV).
In the title salt, [Ag(C(26)H(24)P(2))(2)][Sn(C(2)ClF(2)O(2))(2)(C(6)H(5))(2)(C(6)H(4)Cl)], the Ag(I) atom has a tetra-hedral and the Sn(IV) atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two...
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| Format: | Article |
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International Union of Crystallography
2008
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| _version_ | 1825718489874169856 |
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| author | Teo, Y.Y. Lo, K.M. Ng, Seik Weng |
| author_facet | Teo, Y.Y. Lo, K.M. Ng, Seik Weng |
| author_sort | Teo, Y.Y. |
| collection | UM |
| description | In the title salt, [Ag(C(26)H(24)P(2))(2)][Sn(C(2)ClF(2)O(2))(2)(C(6)H(5))(2)(C(6)H(4)Cl)], the Ag(I) atom has a tetra-hedral and the Sn(IV) atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chloro-difluoro-methyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30). |
| first_indexed | 2024-03-06T05:05:20Z |
| format | Article |
| id | um.eprints-891 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:05:20Z |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-8912019-01-31T02:04:50Z http://eprints.um.edu.my/891/ Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). Teo, Y.Y. Lo, K.M. Ng, Seik Weng QD Chemistry In the title salt, [Ag(C(26)H(24)P(2))(2)][Sn(C(2)ClF(2)O(2))(2)(C(6)H(5))(2)(C(6)H(4)Cl)], the Ag(I) atom has a tetra-hedral and the Sn(IV) atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chloro-difluoro-methyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30). International Union of Crystallography 2008 Article PeerReviewed Teo, Y.Y. and Lo, K.M. and Ng, Seik Weng (2008) Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). Acta Crystallographica Section E: Structure Reports Online, 64 (Pt 6). m819. ISSN 1600-5368, DOI 21202502. http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2961517/ 21202502 |
| spellingShingle | QD Chemistry Teo, Y.Y. Lo, K.M. Ng, Seik Weng Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). |
| title | Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). |
| title_full | Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). |
| title_fullStr | Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). |
| title_full_unstemmed | Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). |
| title_short | Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV). |
| title_sort | bis 1 2 bis diphenyl phosphino ethane κp p silver i bis chloro difluoro acetato κo 4 chloro phen yl diphenyl stannate iv |
| topic | QD Chemistry |
| work_keys_str_mv | AT teoyy bis12bisdiphenylphosphinoethanekppsilveribischlorodifluoroacetatoko4chlorophenyldiphenylstannateiv AT lokm bis12bisdiphenylphosphinoethanekppsilveribischlorodifluoroacetatoko4chlorophenyldiphenylstannateiv AT ngseikweng bis12bisdiphenylphosphinoethanekppsilveribischlorodifluoroacetatoko4chlorophenyldiphenylstannateiv |