Preloading hydrous ferric oxide into granular activated carbon for arsenic removal

Arsenic is of concern in water treatment because of its health effects. This research focused on incorporating hydrous ferric oxide (HFO) into granular activated carbon (GAC) for the purpose of arsenic removal. Iron was incorporated into GAC via incipient wetness impregnation and cured at temperatur...

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Main Authors: Jang, M., Chen, W., Cannon, F.S.
Format: Article
Language:English
Published: 2008
Subjects:
Online Access:http://eprints.um.edu.my/9195/1/Preloading_Hydrous_Ferric_Oxide_into_Granular_Activated_Carbon_for_Arsenic_Removal.pdf
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author Jang, M.
Chen, W.
Cannon, F.S.
author_facet Jang, M.
Chen, W.
Cannon, F.S.
author_sort Jang, M.
collection UM
description Arsenic is of concern in water treatment because of its health effects. This research focused on incorporating hydrous ferric oxide (HFO) into granular activated carbon (GAC) for the purpose of arsenic removal. Iron was incorporated into GAC via incipient wetness impregnation and cured at temperatures ranging from 60 to 90 °C. X-ray diffractions and arsenic sorption as a function of pH were conducted to investigate the effect of temperature on final iron oxide (hydroxide) and their arsenic removal capabilities. Results revealed that when curing at 60 °C, the procedure successfully created HFO in the pores of GAC, whereas at temperatures of 80 and 90 °C, the impregnated iron oxide manifested a more crystalline form. In the column tests using synthetic water, the HFO-loaded GAC prepared at 60 °C also showed higher sorption capacities than media cured at higher temperatures. These results indicated that the adsorption capacity for arsenic was closely related to the form of iron (hydr)oxide for a given iron content. For the column test using a natural groundwater, HFO-loaded GAC (Fe, 11.7) showed an arsenic sorption capacity of 26 mg As/g when the influent contained 300/μg/L As. Thus, the preloading of HFO into a stable GAC media offered the opportunity to employ fixed carbon bed reactors in water treatment plants or point-of-use filters for arsenic removal. © 2008 American Chemical Society.
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spelling um.eprints-91952014-02-04T03:34:42Z http://eprints.um.edu.my/9195/ Preloading hydrous ferric oxide into granular activated carbon for arsenic removal Jang, M. Chen, W. Cannon, F.S. TA Engineering (General). Civil engineering (General) Arsenic is of concern in water treatment because of its health effects. This research focused on incorporating hydrous ferric oxide (HFO) into granular activated carbon (GAC) for the purpose of arsenic removal. Iron was incorporated into GAC via incipient wetness impregnation and cured at temperatures ranging from 60 to 90 °C. X-ray diffractions and arsenic sorption as a function of pH were conducted to investigate the effect of temperature on final iron oxide (hydroxide) and their arsenic removal capabilities. Results revealed that when curing at 60 °C, the procedure successfully created HFO in the pores of GAC, whereas at temperatures of 80 and 90 °C, the impregnated iron oxide manifested a more crystalline form. In the column tests using synthetic water, the HFO-loaded GAC prepared at 60 °C also showed higher sorption capacities than media cured at higher temperatures. These results indicated that the adsorption capacity for arsenic was closely related to the form of iron (hydr)oxide for a given iron content. For the column test using a natural groundwater, HFO-loaded GAC (Fe, 11.7) showed an arsenic sorption capacity of 26 mg As/g when the influent contained 300/μg/L As. Thus, the preloading of HFO into a stable GAC media offered the opportunity to employ fixed carbon bed reactors in water treatment plants or point-of-use filters for arsenic removal. © 2008 American Chemical Society. 2008 Article PeerReviewed application/pdf en http://eprints.um.edu.my/9195/1/Preloading_Hydrous_Ferric_Oxide_into_Granular_Activated_Carbon_for_Arsenic_Removal.pdf Jang, M. and Chen, W. and Cannon, F.S. (2008) Preloading hydrous ferric oxide into granular activated carbon for arsenic removal. Environmental Science and Technology, 42 (9). pp. 3369-3374. ISSN 0013936X, DOI https://doi.org/10.1021/es7025399 <https://doi.org/10.1021/es7025399>. http://www.scopus.com/inward/record.url?eid=2-s2.0-52049104481&partnerID=40&md5=2e839d1a7d708c429ebc4da360c645df http://pubs.acs.org/doi/abs/10.1021/es7025399 10.1021/es7025399
spellingShingle TA Engineering (General). Civil engineering (General)
Jang, M.
Chen, W.
Cannon, F.S.
Preloading hydrous ferric oxide into granular activated carbon for arsenic removal
title Preloading hydrous ferric oxide into granular activated carbon for arsenic removal
title_full Preloading hydrous ferric oxide into granular activated carbon for arsenic removal
title_fullStr Preloading hydrous ferric oxide into granular activated carbon for arsenic removal
title_full_unstemmed Preloading hydrous ferric oxide into granular activated carbon for arsenic removal
title_short Preloading hydrous ferric oxide into granular activated carbon for arsenic removal
title_sort preloading hydrous ferric oxide into granular activated carbon for arsenic removal
topic TA Engineering (General). Civil engineering (General)
url http://eprints.um.edu.my/9195/1/Preloading_Hydrous_Ferric_Oxide_into_Granular_Activated_Carbon_for_Arsenic_Removal.pdf
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AT chenw preloadinghydrousferricoxideintogranularactivatedcarbonforarsenicremoval
AT cannonfs preloadinghydrousferricoxideintogranularactivatedcarbonforarsenicremoval