Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater
A waste material known as palm oil empty fruit bunch (EFB) is used as a source of cellulose for the development of polymeric materials for the removal of metal ions from industrial wastewater. A poly(acrylonitrile)-grafted palm cellulose copolymer was synthesized by a conventional free radical initi...
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| Format: | Article |
| Language: | English English |
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Springer-Verlag GmbH Germany, part of Springer Nature 2020
2020
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| Online Access: | https://eprints.ums.edu.my/id/eprint/26014/1/Poly%28amidoxime%29%20ligand%20derived%20from%20waste%20palm%20fiber%20for%20the%20removal%20of%20heavy%20metals%20from%20electroplating%20wastewater.pdf https://eprints.ums.edu.my/id/eprint/26014/2/Poly%28amidoxime%29%20ligand%20derived%20from%20waste%20palm%20fiber%20for%20the%20removal%20of%20heavy%20metals%20from%20electroplating%20wastewater1.pdf |
| _version_ | 1825713959959789568 |
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| author | Md Lutfor Rahman Choong Jian Fui Mohd Sani Sarjadi Sazmal E. Arshad Baba Musta Mohd Harun Abdullah Shaheen M. Sarkar Emmet J. O’Reilly |
| author_facet | Md Lutfor Rahman Choong Jian Fui Mohd Sani Sarjadi Sazmal E. Arshad Baba Musta Mohd Harun Abdullah Shaheen M. Sarkar Emmet J. O’Reilly |
| author_sort | Md Lutfor Rahman |
| collection | UMS |
| description | A waste material known as palm oil empty fruit bunch (EFB) is used as a source of cellulose for the development of polymeric materials for the removal of metal ions from industrial wastewater. A poly(acrylonitrile)-grafted palm cellulose copolymer was synthesized by a conventional free radical initiating process followed by synthesis of a poly(amidoxime) ligand by oximation reaction. The resulting products were characterized by FT-IR, FE-SEM, EDX, TGA, DSC, and XPS. The poly(amidoxime) ligand was used to coordinate with and extract a series of transition metal ions from water samples. The binding capacity (qe) of the ligand with the metal ions such as copper, iron, cobalt, nickel, and lead were 260, 210, 168, 172, and 272 mg g−1 , respectively at pH 6. The adsorption process followed the pseudo-first-order kinetic model (R2 > 0.99) and as well as the Freundlich isotherm model (R2 > 0.99) indicating the occurrence of a multi-layer adsorption process in the amidoxime ligand adsorbent. Results from reusability studies show that the ligand can be recycled for at least 10 cycles without any significant losses to its initial adsorption capacity. The synthesized polymeric ligand was shown to absorb heavy metals from electroplating wastewater with up to 95% efficiency. |
| first_indexed | 2024-03-06T03:04:39Z |
| format | Article |
| id | ums.eprints-26014 |
| institution | Universiti Malaysia Sabah |
| language | English English |
| last_indexed | 2024-03-06T03:04:39Z |
| publishDate | 2020 |
| publisher | Springer-Verlag GmbH Germany, part of Springer Nature 2020 |
| record_format | dspace |
| spelling | ums.eprints-260142021-04-15T15:27:41Z https://eprints.ums.edu.my/id/eprint/26014/ Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater Md Lutfor Rahman Choong Jian Fui Mohd Sani Sarjadi Sazmal E. Arshad Baba Musta Mohd Harun Abdullah Shaheen M. Sarkar Emmet J. O’Reilly Q Science (General) QE Geology A waste material known as palm oil empty fruit bunch (EFB) is used as a source of cellulose for the development of polymeric materials for the removal of metal ions from industrial wastewater. A poly(acrylonitrile)-grafted palm cellulose copolymer was synthesized by a conventional free radical initiating process followed by synthesis of a poly(amidoxime) ligand by oximation reaction. The resulting products were characterized by FT-IR, FE-SEM, EDX, TGA, DSC, and XPS. The poly(amidoxime) ligand was used to coordinate with and extract a series of transition metal ions from water samples. The binding capacity (qe) of the ligand with the metal ions such as copper, iron, cobalt, nickel, and lead were 260, 210, 168, 172, and 272 mg g−1 , respectively at pH 6. The adsorption process followed the pseudo-first-order kinetic model (R2 > 0.99) and as well as the Freundlich isotherm model (R2 > 0.99) indicating the occurrence of a multi-layer adsorption process in the amidoxime ligand adsorbent. Results from reusability studies show that the ligand can be recycled for at least 10 cycles without any significant losses to its initial adsorption capacity. The synthesized polymeric ligand was shown to absorb heavy metals from electroplating wastewater with up to 95% efficiency. Springer-Verlag GmbH Germany, part of Springer Nature 2020 2020 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/26014/1/Poly%28amidoxime%29%20ligand%20derived%20from%20waste%20palm%20fiber%20for%20the%20removal%20of%20heavy%20metals%20from%20electroplating%20wastewater.pdf text en https://eprints.ums.edu.my/id/eprint/26014/2/Poly%28amidoxime%29%20ligand%20derived%20from%20waste%20palm%20fiber%20for%20the%20removal%20of%20heavy%20metals%20from%20electroplating%20wastewater1.pdf Md Lutfor Rahman and Choong Jian Fui and Mohd Sani Sarjadi and Sazmal E. Arshad and Baba Musta and Mohd Harun Abdullah and Shaheen M. Sarkar and Emmet J. O’Reilly (2020) Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater. Environmental Science and Pollution Research, 27. pp. 34541-34556. https://doi.org/10.1007/s11356-020-09462-0 |
| spellingShingle | Q Science (General) QE Geology Md Lutfor Rahman Choong Jian Fui Mohd Sani Sarjadi Sazmal E. Arshad Baba Musta Mohd Harun Abdullah Shaheen M. Sarkar Emmet J. O’Reilly Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater |
| title | Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater |
| title_full | Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater |
| title_fullStr | Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater |
| title_full_unstemmed | Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater |
| title_short | Poly(amidoxime) ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater |
| title_sort | poly amidoxime ligand derived from waste palm fiber for the removal of heavy metals from electroplating wastewater |
| topic | Q Science (General) QE Geology |
| url | https://eprints.ums.edu.my/id/eprint/26014/1/Poly%28amidoxime%29%20ligand%20derived%20from%20waste%20palm%20fiber%20for%20the%20removal%20of%20heavy%20metals%20from%20electroplating%20wastewater.pdf https://eprints.ums.edu.my/id/eprint/26014/2/Poly%28amidoxime%29%20ligand%20derived%20from%20waste%20palm%20fiber%20for%20the%20removal%20of%20heavy%20metals%20from%20electroplating%20wastewater1.pdf |
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