Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique

The search for hard fats is increasing by the day due to their demand for industrial purposes. Rambutan seed fat (RSF) was fractionated prior to investigate the melting and crystallisation behaviours, triacylglycerols (TAGs), and morphology using different chromatographic and thermal techniques. The...

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Main Authors: Azzatul, Jahurul Haque Akanda, J. Norliza, M.R. Norazlina, Hasmadi Mamat, Shaarani Md. Sharifudin, Patricia @ Patricia Clementina Matanjun, Jau, Shya Lee, A. Shihabul Noorakmar Ab. Wahab
Format: Article
Jezik:English
Izdano: Institute of Food Science & Technology 2020
Online dostop:https://eprints.ums.edu.my/id/eprint/26213/1/Improvement%20of%20melting%20and%20crystallisation%20properties%20of%20rambutan%20seed%20fat%20as%20cocoa%20butter%20improver%20by%20two%E2%80%90stage%20fractionation%20technique.pdf
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author Azzatul
Jahurul Haque Akanda
J. Norliza
M.R. Norazlina
Hasmadi Mamat
Shaarani Md. Sharifudin
Patricia @ Patricia Clementina Matanjun
Jau, Shya Lee
A. Shihabul Noorakmar Ab. Wahab
author_facet Azzatul
Jahurul Haque Akanda
J. Norliza
M.R. Norazlina
Hasmadi Mamat
Shaarani Md. Sharifudin
Patricia @ Patricia Clementina Matanjun
Jau, Shya Lee
A. Shihabul Noorakmar Ab. Wahab
author_sort Azzatul
collection UMS
description The search for hard fats is increasing by the day due to their demand for industrial purposes. Rambutan seed fat (RSF) was fractionated prior to investigate the melting and crystallisation behaviours, triacylglycerols (TAGs), and morphology using different chromatographic and thermal techniques. The increasing trends were observed for high‐melting symmetrical monounsaturated TAGs such as 1,3‐distearoyl‐2‐oleoyl‐glycerol and 1‐palmitoyl‐3‐stearoyl‐2‐oleoyl‐glycerol in both solid fractions upon fractionation. The solid fractions (F1‐S) and (F2‐S) exhibited small peaks towards low melting area and big peaks towards high melting area with the offset temperatures of 35.29–48.75 °C and 43.58–52.70 °C with significantly higher enthalpies (93.49 and 105.13 J g−1) upon fractionation. F2‐S showed the densely packed microstructure compared to that of crude RSF and F1‐S. Based on the thermal behaviours as well as morphology of RSF fractions, cocoa butter improver could be prepared that has the potential to be utilised in chocolate manufacturing in tropical countries.
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spelling ums.eprints-262132020-10-27T10:25:32Z https://eprints.ums.edu.my/id/eprint/26213/ Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique Azzatul Jahurul Haque Akanda J. Norliza M.R. Norazlina Hasmadi Mamat Shaarani Md. Sharifudin Patricia @ Patricia Clementina Matanjun Jau, Shya Lee A. Shihabul Noorakmar Ab. Wahab The search for hard fats is increasing by the day due to their demand for industrial purposes. Rambutan seed fat (RSF) was fractionated prior to investigate the melting and crystallisation behaviours, triacylglycerols (TAGs), and morphology using different chromatographic and thermal techniques. The increasing trends were observed for high‐melting symmetrical monounsaturated TAGs such as 1,3‐distearoyl‐2‐oleoyl‐glycerol and 1‐palmitoyl‐3‐stearoyl‐2‐oleoyl‐glycerol in both solid fractions upon fractionation. The solid fractions (F1‐S) and (F2‐S) exhibited small peaks towards low melting area and big peaks towards high melting area with the offset temperatures of 35.29–48.75 °C and 43.58–52.70 °C with significantly higher enthalpies (93.49 and 105.13 J g−1) upon fractionation. F2‐S showed the densely packed microstructure compared to that of crude RSF and F1‐S. Based on the thermal behaviours as well as morphology of RSF fractions, cocoa butter improver could be prepared that has the potential to be utilised in chocolate manufacturing in tropical countries. Institute of Food Science & Technology 2020 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/26213/1/Improvement%20of%20melting%20and%20crystallisation%20properties%20of%20rambutan%20seed%20fat%20as%20cocoa%20butter%20improver%20by%20two%E2%80%90stage%20fractionation%20technique.pdf Azzatul and Jahurul Haque Akanda and J. Norliza and M.R. Norazlina and Hasmadi Mamat and Shaarani Md. Sharifudin and Patricia @ Patricia Clementina Matanjun and Jau, Shya Lee and A. Shihabul Noorakmar Ab. Wahab (2020) Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique. International Journal of Food Science and Technology. https://doi.org/10.1111/ijfs.14772
spellingShingle Azzatul
Jahurul Haque Akanda
J. Norliza
M.R. Norazlina
Hasmadi Mamat
Shaarani Md. Sharifudin
Patricia @ Patricia Clementina Matanjun
Jau, Shya Lee
A. Shihabul Noorakmar Ab. Wahab
Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_full Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_fullStr Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_full_unstemmed Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_short Improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_sort improvement of melting and crystallization properties of rambutan seed fat as cocoa butter improver by two stage fractionation technique
url https://eprints.ums.edu.my/id/eprint/26213/1/Improvement%20of%20melting%20and%20crystallisation%20properties%20of%20rambutan%20seed%20fat%20as%20cocoa%20butter%20improver%20by%20two%E2%80%90stage%20fractionation%20technique.pdf
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