Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT
Poly[N-9’-heptadecanyl-2,7-carbazole-alt-5,5-(4’,7’-di-2-thienyl-2’,1’,3’-benzothiadiazole)] (PCDTBT) is an attractive material for optoelectronic devices, and has been prevalently prepared by traditional couplings. Despite robust and effective, the traditional methods generally involve the use of t...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
Malaysian Institute of Chemistry
2020
|
| Subjects: | |
| Online Access: | https://eprints.ums.edu.my/id/eprint/27602/1/Direct%20Arylation%20Polymerization%20Toward%20a%20D-A%20Type%20Copolymer%20Based%20on%20Carbazole%20and%20Benzothiadiazole%20Units%20-%20an%20Analogue%20of%20PCDTBT%20abstract.pdf https://eprints.ums.edu.my/id/eprint/27602/2/Direct%20arylation%20polymerization%20toward%20a%20D-A%20type%20copolymer%20based%20on%20carbazole%20and%20benzothiadiazole%20units%20-%20An%20analogue%20of%20PCDTBT%20fulltext.pdf |
| _version_ | 1825714188318670848 |
|---|---|
| author | Mohd Sani Sarjadi Wong, Xin Lin Farah Hannan Anuar Zuhair Jamain Md. Lutfor Rahman |
| author_facet | Mohd Sani Sarjadi Wong, Xin Lin Farah Hannan Anuar Zuhair Jamain Md. Lutfor Rahman |
| author_sort | Mohd Sani Sarjadi |
| collection | UMS |
| description | Poly[N-9’-heptadecanyl-2,7-carbazole-alt-5,5-(4’,7’-di-2-thienyl-2’,1’,3’-benzothiadiazole)] (PCDTBT) is an attractive material for optoelectronic devices, and has been prevalently prepared by traditional couplings. Despite robust and effective, the traditional methods generally involve the use of toxic organometallic reagents. Direct arylation polymerization (DArP), as a simple, green, and cost-effective alternative to traditional coupling, has been utilized in this work to prepare an analogue of PCDTBT, namely poly[(9-hexadecyl-2,7-carbazole)-alt-(4,7-di(thiophen-2-yl)-2,1,3-benzothiadiazole)] (P1). The co-polymer was obtained in 44% yield and satisfactorily characterized by Fourier-transform infrared spectroscopy (FTIR)and Nuclear magnetic resonance (NMR). UV-Vis absorption spectra showed the presence of inter-chain interaction and aggregation in the solid state. The optical band gap of the co-polymer was found to be in the range of 1.77 -1.81 eV, which is slightly lower than that of PCDTBT (1.88 eV). |
| first_indexed | 2024-03-06T03:08:05Z |
| format | Article |
| id | ums.eprints-27602 |
| institution | Universiti Malaysia Sabah |
| language | English English |
| last_indexed | 2024-03-06T03:08:05Z |
| publishDate | 2020 |
| publisher | Malaysian Institute of Chemistry |
| record_format | dspace |
| spelling | ums.eprints-276022021-07-04T13:03:53Z https://eprints.ums.edu.my/id/eprint/27602/ Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT Mohd Sani Sarjadi Wong, Xin Lin Farah Hannan Anuar Zuhair Jamain Md. Lutfor Rahman QC Physics Poly[N-9’-heptadecanyl-2,7-carbazole-alt-5,5-(4’,7’-di-2-thienyl-2’,1’,3’-benzothiadiazole)] (PCDTBT) is an attractive material for optoelectronic devices, and has been prevalently prepared by traditional couplings. Despite robust and effective, the traditional methods generally involve the use of toxic organometallic reagents. Direct arylation polymerization (DArP), as a simple, green, and cost-effective alternative to traditional coupling, has been utilized in this work to prepare an analogue of PCDTBT, namely poly[(9-hexadecyl-2,7-carbazole)-alt-(4,7-di(thiophen-2-yl)-2,1,3-benzothiadiazole)] (P1). The co-polymer was obtained in 44% yield and satisfactorily characterized by Fourier-transform infrared spectroscopy (FTIR)and Nuclear magnetic resonance (NMR). UV-Vis absorption spectra showed the presence of inter-chain interaction and aggregation in the solid state. The optical band gap of the co-polymer was found to be in the range of 1.77 -1.81 eV, which is slightly lower than that of PCDTBT (1.88 eV). Malaysian Institute of Chemistry 2020 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/27602/1/Direct%20Arylation%20Polymerization%20Toward%20a%20D-A%20Type%20Copolymer%20Based%20on%20Carbazole%20and%20Benzothiadiazole%20Units%20-%20an%20Analogue%20of%20PCDTBT%20abstract.pdf text en https://eprints.ums.edu.my/id/eprint/27602/2/Direct%20arylation%20polymerization%20toward%20a%20D-A%20type%20copolymer%20based%20on%20carbazole%20and%20benzothiadiazole%20units%20-%20An%20analogue%20of%20PCDTBT%20fulltext.pdf Mohd Sani Sarjadi and Wong, Xin Lin and Farah Hannan Anuar and Zuhair Jamain and Md. Lutfor Rahman (2020) Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT. Malaysian Journal of Chemistry, 22 (4). pp. 141-149. ISSN 2550-1658 https://ikm.org.my/ojs/index.php/MJChem/article/vi https://ikm.org.my/ojs/index.php/MJChem/article/view/796/357 |
| spellingShingle | QC Physics Mohd Sani Sarjadi Wong, Xin Lin Farah Hannan Anuar Zuhair Jamain Md. Lutfor Rahman Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT |
| title | Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT |
| title_full | Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT |
| title_fullStr | Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT |
| title_full_unstemmed | Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT |
| title_short | Direct arylation polymerization toward a D-A type copolymer based on carbazole and benzothiadiazole units - An analogue of PCDTBT |
| title_sort | direct arylation polymerization toward a d a type copolymer based on carbazole and benzothiadiazole units an analogue of pcdtbt |
| topic | QC Physics |
| url | https://eprints.ums.edu.my/id/eprint/27602/1/Direct%20Arylation%20Polymerization%20Toward%20a%20D-A%20Type%20Copolymer%20Based%20on%20Carbazole%20and%20Benzothiadiazole%20Units%20-%20an%20Analogue%20of%20PCDTBT%20abstract.pdf https://eprints.ums.edu.my/id/eprint/27602/2/Direct%20arylation%20polymerization%20toward%20a%20D-A%20type%20copolymer%20based%20on%20carbazole%20and%20benzothiadiazole%20units%20-%20An%20analogue%20of%20PCDTBT%20fulltext.pdf |
| work_keys_str_mv | AT mohdsanisarjadi directarylationpolymerizationtowardadatypecopolymerbasedoncarbazoleandbenzothiadiazoleunitsananalogueofpcdtbt AT wongxinlin directarylationpolymerizationtowardadatypecopolymerbasedoncarbazoleandbenzothiadiazoleunitsananalogueofpcdtbt AT farahhannananuar directarylationpolymerizationtowardadatypecopolymerbasedoncarbazoleandbenzothiadiazoleunitsananalogueofpcdtbt AT zuhairjamain directarylationpolymerizationtowardadatypecopolymerbasedoncarbazoleandbenzothiadiazoleunitsananalogueofpcdtbt AT mdlutforrahman directarylationpolymerizationtowardadatypecopolymerbasedoncarbazoleandbenzothiadiazoleunitsananalogueofpcdtbt |