Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions
Azobenzene based metal ion-imprinted polymers (IIPs) were synthesized for selective separation of Co (II) and Cu (II) ions from the mixture of metal ions. After polymerization, cavities for the Co2+ and Cu2+ ions were created in the polymer materials by leaching with hydrochloric acid solution. The...
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| Format: | Article |
| Language: | English English |
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Ion-Imprinted Polymers
2020
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| Online Access: | https://eprints.ums.edu.my/id/eprint/30161/1/Synthesis%20of%20azobenzene-based%20ion-imprinted%20polymers%20for%20selective%20removal%20of%20cobalt%20and%20copper%20ions%20from%20a%20mixture%20of%20metal%20ions%20.pdf https://eprints.ums.edu.my/id/eprint/30161/2/Synthesis%20of%20azobenzene-based%20ion-imprinted%20polymers%20for%20selective%20removal%20of%20cobalt%20and%20copper%20ions%20from%20a%20mixture%20of%20metal%20ions%201.pdf |
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| author | Tapan Kumar Biswas Mashitah Mohd Yusoff Mohd Sani Sarjadi Sazmal Effendi Arshad Baba Musta Md Lutfor Rahman |
| author_facet | Tapan Kumar Biswas Mashitah Mohd Yusoff Mohd Sani Sarjadi Sazmal Effendi Arshad Baba Musta Md Lutfor Rahman |
| author_sort | Tapan Kumar Biswas |
| collection | UMS |
| description | Azobenzene based metal ion-imprinted polymers (IIPs) were synthesized for selective separation of Co (II) and Cu (II) ions from the mixture of metal ions. After polymerization, cavities for the Co2+ and Cu2+ ions were created in the polymer materials by leaching with hydrochloric acid solution. The synthesized IIPs were characterized by FT-IR, 1 H NMR and elemental analysis. The competitive sorption studies were carried out to evaluate the selectivity of the target metal ions. Interestingly, the observed sorption capacity was pH dependent and maximum sorption was found to be 95.4 and 103.0 mg·g−1 for Co-IIPs and Cu-IIPs at pH 5, respectively. It was observed that the IIPs showed good selectivity to Co (II) and Cu (II) ions in the presence of other bi and trivalent metal ions in solution. Reused capacity was also checked for six times without a significant decrease in binding affinity for IIPs. |
| first_indexed | 2024-03-06T03:09:51Z |
| format | Article |
| id | ums.eprints-30161 |
| institution | Universiti Malaysia Sabah |
| language | English English |
| last_indexed | 2024-03-06T03:09:51Z |
| publishDate | 2020 |
| publisher | Ion-Imprinted Polymers |
| record_format | dspace |
| spelling | ums.eprints-301612021-07-31T01:21:30Z https://eprints.ums.edu.my/id/eprint/30161/ Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions Tapan Kumar Biswas Mashitah Mohd Yusoff Mohd Sani Sarjadi Sazmal Effendi Arshad Baba Musta Md Lutfor Rahman Q Science (General) QD Chemistry Azobenzene based metal ion-imprinted polymers (IIPs) were synthesized for selective separation of Co (II) and Cu (II) ions from the mixture of metal ions. After polymerization, cavities for the Co2+ and Cu2+ ions were created in the polymer materials by leaching with hydrochloric acid solution. The synthesized IIPs were characterized by FT-IR, 1 H NMR and elemental analysis. The competitive sorption studies were carried out to evaluate the selectivity of the target metal ions. Interestingly, the observed sorption capacity was pH dependent and maximum sorption was found to be 95.4 and 103.0 mg·g−1 for Co-IIPs and Cu-IIPs at pH 5, respectively. It was observed that the IIPs showed good selectivity to Co (II) and Cu (II) ions in the presence of other bi and trivalent metal ions in solution. Reused capacity was also checked for six times without a significant decrease in binding affinity for IIPs. Ion-Imprinted Polymers 2020 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/30161/1/Synthesis%20of%20azobenzene-based%20ion-imprinted%20polymers%20for%20selective%20removal%20of%20cobalt%20and%20copper%20ions%20from%20a%20mixture%20of%20metal%20ions%20.pdf text en https://eprints.ums.edu.my/id/eprint/30161/2/Synthesis%20of%20azobenzene-based%20ion-imprinted%20polymers%20for%20selective%20removal%20of%20cobalt%20and%20copper%20ions%20from%20a%20mixture%20of%20metal%20ions%201.pdf Tapan Kumar Biswas and Mashitah Mohd Yusoff and Mohd Sani Sarjadi and Sazmal Effendi Arshad and Baba Musta and Md Lutfor Rahman (2020) Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions. General Chemistry, 6 (19000). pp. 1-7. ISSN 2414-3421 http://www.genchemistry.org/EN/10.21127/yaoyigc20190009 https://doi.org/10.21127/yaoyigc20190009 https://doi.org/10.21127/yaoyigc20190009 |
| spellingShingle | Q Science (General) QD Chemistry Tapan Kumar Biswas Mashitah Mohd Yusoff Mohd Sani Sarjadi Sazmal Effendi Arshad Baba Musta Md Lutfor Rahman Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions |
| title | Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions |
| title_full | Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions |
| title_fullStr | Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions |
| title_full_unstemmed | Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions |
| title_short | Synthesis of azobenzene-based ion-imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions |
| title_sort | synthesis of azobenzene based ion imprinted polymers for selective removal of cobalt and copper ions from a mixture of metal ions |
| topic | Q Science (General) QD Chemistry |
| url | https://eprints.ums.edu.my/id/eprint/30161/1/Synthesis%20of%20azobenzene-based%20ion-imprinted%20polymers%20for%20selective%20removal%20of%20cobalt%20and%20copper%20ions%20from%20a%20mixture%20of%20metal%20ions%20.pdf https://eprints.ums.edu.my/id/eprint/30161/2/Synthesis%20of%20azobenzene-based%20ion-imprinted%20polymers%20for%20selective%20removal%20of%20cobalt%20and%20copper%20ions%20from%20a%20mixture%20of%20metal%20ions%201.pdf |
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