Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique

The search for hard fats is increasing by the day due to their demand for industrial purposes. Rambutan seed fat (RSF) was fractionated prior to investigate the melting and crystallisation behaviours, triacylglycerols (TAGs), and morphology using different chromatographic and thermal techniques. The...

Full description

Bibliographic Details
Main Authors: Azzatul F., Md. Jahurul Haque Akanda e, Norliza Julmohammad, Norazlina M. R., Hasmadi Mamat, Sharifudin Md Shaarani, Patricia @ Patricia Clementina Matanjun, Lee Jau Shya, A. Shihabul, Noorakmar Ab. Wahab
Format: Article
Language:English
Published: Institute of Food Science & Technology 2020
Subjects:
Online Access:https://eprints.ums.edu.my/id/eprint/30774/1/Improvement%20of%20melting%20and%20crystallisation%20properties%20of%20rambutan%20seed%20fat%20as%20cocoa%20butter%20improver%20by%20two-stage%20fractionation%20technique-ABSTRACT.pdf
_version_ 1825714409191768064
author Azzatul F.
Md. Jahurul Haque Akanda e
Norliza Julmohammad
Norazlina M. R.
Hasmadi Mamat
Sharifudin Md Shaarani
Patricia @ Patricia Clementina Matanjun
Lee Jau Shya
A. Shihabul
Noorakmar Ab. Wahab
author_facet Azzatul F.
Md. Jahurul Haque Akanda e
Norliza Julmohammad
Norazlina M. R.
Hasmadi Mamat
Sharifudin Md Shaarani
Patricia @ Patricia Clementina Matanjun
Lee Jau Shya
A. Shihabul
Noorakmar Ab. Wahab
author_sort Azzatul F.
collection UMS
description The search for hard fats is increasing by the day due to their demand for industrial purposes. Rambutan seed fat (RSF) was fractionated prior to investigate the melting and crystallisation behaviours, triacylglycerols (TAGs), and morphology using different chromatographic and thermal techniques. The increasing trends were observed for high-melting symmetrical monounsaturated TAGs such as 1,3-distearoyl-2-oleoyl-glycerol and 1-palmitoyl-3-stearoyl-2-oleoyl-glycerol in both solid fractions upon fractionation. The solid fractions (F1-S) and (F2-S) exhibited small peaks towards low melting area and big peaks towards high melting area with the offset temperatures of 35.29–48.75 °C and 43.58–52.70 °C with significantly higher enthalpies (93.49 and 105.13 J g−1) upon fractionation. F2-S showed the densely packed microstructure compared to that of crude RSF and F1-S. Based on the thermal behaviours as well as morphology of RSF fractions, cocoa butter improver could be prepared that has the potential to be utilised in chocolate manufacturing in tropical countries.
first_indexed 2024-03-06T03:11:23Z
format Article
id ums.eprints-30774
institution Universiti Malaysia Sabah
language English
last_indexed 2024-03-06T03:11:23Z
publishDate 2020
publisher Institute of Food Science & Technology
record_format dspace
spelling ums.eprints-307742021-10-26T11:46:34Z https://eprints.ums.edu.my/id/eprint/30774/ Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique Azzatul F. Md. Jahurul Haque Akanda e Norliza Julmohammad Norazlina M. R. Hasmadi Mamat Sharifudin Md Shaarani Patricia @ Patricia Clementina Matanjun Lee Jau Shya A. Shihabul Noorakmar Ab. Wahab QK710-899 Plant physiology TP500-660 Fermentation industries. Beverages. Alcohol The search for hard fats is increasing by the day due to their demand for industrial purposes. Rambutan seed fat (RSF) was fractionated prior to investigate the melting and crystallisation behaviours, triacylglycerols (TAGs), and morphology using different chromatographic and thermal techniques. The increasing trends were observed for high-melting symmetrical monounsaturated TAGs such as 1,3-distearoyl-2-oleoyl-glycerol and 1-palmitoyl-3-stearoyl-2-oleoyl-glycerol in both solid fractions upon fractionation. The solid fractions (F1-S) and (F2-S) exhibited small peaks towards low melting area and big peaks towards high melting area with the offset temperatures of 35.29–48.75 °C and 43.58–52.70 °C with significantly higher enthalpies (93.49 and 105.13 J g−1) upon fractionation. F2-S showed the densely packed microstructure compared to that of crude RSF and F1-S. Based on the thermal behaviours as well as morphology of RSF fractions, cocoa butter improver could be prepared that has the potential to be utilised in chocolate manufacturing in tropical countries. Institute of Food Science & Technology 2020-08-11 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/30774/1/Improvement%20of%20melting%20and%20crystallisation%20properties%20of%20rambutan%20seed%20fat%20as%20cocoa%20butter%20improver%20by%20two-stage%20fractionation%20technique-ABSTRACT.pdf Azzatul F. and Md. Jahurul Haque Akanda e and Norliza Julmohammad and Norazlina M. R. and Hasmadi Mamat and Sharifudin Md Shaarani and Patricia @ Patricia Clementina Matanjun and Lee Jau Shya and A. Shihabul and Noorakmar Ab. Wahab (2020) Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique. International Journal of Food Science and Technology, 56. pp. 1574-1581. ISSN 2356-7015 (P-ISSN) , 2314-5765 (E-ISSN) https://ifst.onlinelibrary.wiley.com/doi/10.1111/ijfs.14772 https://doi.org/10.1111/ijfs.14772 https://doi.org/10.1111/ijfs.14772
spellingShingle QK710-899 Plant physiology
TP500-660 Fermentation industries. Beverages. Alcohol
Azzatul F.
Md. Jahurul Haque Akanda e
Norliza Julmohammad
Norazlina M. R.
Hasmadi Mamat
Sharifudin Md Shaarani
Patricia @ Patricia Clementina Matanjun
Lee Jau Shya
A. Shihabul
Noorakmar Ab. Wahab
Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_full Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_fullStr Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_full_unstemmed Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_short Improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two-stage fractionation technique
title_sort improvement of melting and crystallisation properties of rambutan seed fat as cocoa butter improver by two stage fractionation technique
topic QK710-899 Plant physiology
TP500-660 Fermentation industries. Beverages. Alcohol
url https://eprints.ums.edu.my/id/eprint/30774/1/Improvement%20of%20melting%20and%20crystallisation%20properties%20of%20rambutan%20seed%20fat%20as%20cocoa%20butter%20improver%20by%20two-stage%20fractionation%20technique-ABSTRACT.pdf
work_keys_str_mv AT azzatulf improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT mdjahurulhaqueakandae improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT norlizajulmohammad improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT norazlinamr improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT hasmadimamat improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT sharifudinmdshaarani improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT patriciapatriciaclementinamatanjun improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT leejaushya improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT ashihabul improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique
AT noorakmarabwahab improvementofmeltingandcrystallisationpropertiesoframbutanseedfatascocoabutterimproverbytwostagefractionationtechnique