Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst
Low cost and environment friendly sulfonated carbon catalyst was prepared from glycerol and concentrated sulfuric acid via in situ carbonization and sulfonation. The physico-chemical properties of catalyst were determined using various techniques. The textural properties of glycerol derived sulfonat...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English English |
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Elsevier Ltd
2020
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| Online Access: | https://eprints.ums.edu.my/id/eprint/31829/1/Production%20of%20methyl%20esters%20from%20waste%20cooking%20oil%20and%20chicken%20fat%20oil%20via%20simultaneous%20esterification%20and%20transesterification%20using%20acid%20catalyst.ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/31829/2/Production%20of%20methyl%20esters%20from%20waste%20cooking%20oil%20and%20chicken%20fat%20oil%20via.pdf |
| _version_ | 1796911109420089344 |
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| author | Shatesh Kumar Mohd Razali Shamsuddin M.S Ahmad Farabi Mohd Izham Saiman Zulkarnain Zainal Yap, Taufiq Yun Hin |
| author_facet | Shatesh Kumar Mohd Razali Shamsuddin M.S Ahmad Farabi Mohd Izham Saiman Zulkarnain Zainal Yap, Taufiq Yun Hin |
| author_sort | Shatesh Kumar |
| collection | UMS |
| description | Low cost and environment friendly sulfonated carbon catalyst was prepared from glycerol and concentrated sulfuric acid via in situ carbonization and sulfonation. The physico-chemical properties of catalyst were determined using various techniques. The textural properties of glycerol derived sulfonated carbon catalyst (SCG) revealed amorphous structure with low surface area and pore volume. The total acid density of catalyst is found to be 35117.14 μmol/g. SCG catalyst showed remarkable catalytic performances for simultaneous esterification and transesterification using waste cooking oil (WCO) and chicken fat oil (CFO). By using WCO, the highest FAME yield achieved was 92.3% at an optimum conditions of 5 wt% catalyst loading with 22:1 methanol to WCO molar ratio and 100 °C reaction temperature for 3 h. The SCG catalyst also maintained FAME yield >90% for two consecutive cycle for reusability. Meanwhile, using CFO, the highest FAME yield obtained was 90.8% at an optimised condition of 5 wt% catalyst loading with 18:1 methanol to CFO molar ratio and 70 °C reaction temperature for 1 h. The quality assessment of WCO methyl ester met both international standards (EN14214 and ASTM D675). The amount of sulfur in biodiesel is lower than the maximum limit of ASTM D6751. |
| first_indexed | 2024-03-06T03:13:56Z |
| format | Article |
| id | ums.eprints-31829 |
| institution | Universiti Malaysia Sabah |
| language | English English |
| last_indexed | 2024-03-06T03:13:56Z |
| publishDate | 2020 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | ums.eprints-318292022-03-04T07:49:20Z https://eprints.ums.edu.my/id/eprint/31829/ Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst Shatesh Kumar Mohd Razali Shamsuddin M.S Ahmad Farabi Mohd Izham Saiman Zulkarnain Zainal Yap, Taufiq Yun Hin TD783-812.5 Municipal refuse. Solid wastes TP200-248 Chemicals: Manufacture, use, etc. Low cost and environment friendly sulfonated carbon catalyst was prepared from glycerol and concentrated sulfuric acid via in situ carbonization and sulfonation. The physico-chemical properties of catalyst were determined using various techniques. The textural properties of glycerol derived sulfonated carbon catalyst (SCG) revealed amorphous structure with low surface area and pore volume. The total acid density of catalyst is found to be 35117.14 μmol/g. SCG catalyst showed remarkable catalytic performances for simultaneous esterification and transesterification using waste cooking oil (WCO) and chicken fat oil (CFO). By using WCO, the highest FAME yield achieved was 92.3% at an optimum conditions of 5 wt% catalyst loading with 22:1 methanol to WCO molar ratio and 100 °C reaction temperature for 3 h. The SCG catalyst also maintained FAME yield >90% for two consecutive cycle for reusability. Meanwhile, using CFO, the highest FAME yield obtained was 90.8% at an optimised condition of 5 wt% catalyst loading with 18:1 methanol to CFO molar ratio and 70 °C reaction temperature for 1 h. The quality assessment of WCO methyl ester met both international standards (EN14214 and ASTM D675). The amount of sulfur in biodiesel is lower than the maximum limit of ASTM D6751. Elsevier Ltd 2020-12-15 Article PeerReviewed text en https://eprints.ums.edu.my/id/eprint/31829/1/Production%20of%20methyl%20esters%20from%20waste%20cooking%20oil%20and%20chicken%20fat%20oil%20via%20simultaneous%20esterification%20and%20transesterification%20using%20acid%20catalyst.ABSTRACT.pdf text en https://eprints.ums.edu.my/id/eprint/31829/2/Production%20of%20methyl%20esters%20from%20waste%20cooking%20oil%20and%20chicken%20fat%20oil%20via.pdf Shatesh Kumar and Mohd Razali Shamsuddin and M.S Ahmad Farabi and Mohd Izham Saiman and Zulkarnain Zainal and Yap, Taufiq Yun Hin (2020) Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst. Energy Conversion and Management, 226. ISSN 0196-8904 https://www.sciencedirect.com/science/article/abs/pii/S0196890420309031 https://doi.org/10.1016/j.enconman.2020.113366 https://doi.org/10.1016/j.enconman.2020.113366 |
| spellingShingle | TD783-812.5 Municipal refuse. Solid wastes TP200-248 Chemicals: Manufacture, use, etc. Shatesh Kumar Mohd Razali Shamsuddin M.S Ahmad Farabi Mohd Izham Saiman Zulkarnain Zainal Yap, Taufiq Yun Hin Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst |
| title | Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst |
| title_full | Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst |
| title_fullStr | Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst |
| title_full_unstemmed | Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst |
| title_short | Production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst |
| title_sort | production of methyl esters from waste cooking oil and chicken fat oil via simultaneous esterification and transesterification using acid catalyst |
| topic | TD783-812.5 Municipal refuse. Solid wastes TP200-248 Chemicals: Manufacture, use, etc. |
| url | https://eprints.ums.edu.my/id/eprint/31829/1/Production%20of%20methyl%20esters%20from%20waste%20cooking%20oil%20and%20chicken%20fat%20oil%20via%20simultaneous%20esterification%20and%20transesterification%20using%20acid%20catalyst.ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/31829/2/Production%20of%20methyl%20esters%20from%20waste%20cooking%20oil%20and%20chicken%20fat%20oil%20via.pdf |
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