Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties
Increasing environmental awareness and concern have shifted the focus of research and development towards biodegradable materials development. In the current study, Cymbopogan citratus fibre (CCF) were incorporated into thermoplastic cassava starch (TPCS) with various content of CCF (10, 20, 30, 40,...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English English |
Published: |
MDPI
2022
|
Subjects: | |
Online Access: | https://eprints.ums.edu.my/id/eprint/33411/2/Biocomposite%20of%20cassava%20starch-cymbopogan%20citratus%20fibre%2C%20Mechanical%2C%20thermal%20and%20biodegradation%20properties.ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/33411/1/Biocomposite%20of%20Cassava%20Starch-Cymbopogan%20Citratus%20Fibre%2C%20Mechanical%2C%20Thermal%20and%20Biodegradation%20Properties.pdf |
_version_ | 1796911399155269632 |
---|---|
author | Zatil Hafila Kamaruddin Ridhwan Jumaidin Rushdan Ahmad Ilyas Mohd Zulkefli Selamat Roziela Hanim Alamjuri Fahmi Asyadi Md Yusof |
author_facet | Zatil Hafila Kamaruddin Ridhwan Jumaidin Rushdan Ahmad Ilyas Mohd Zulkefli Selamat Roziela Hanim Alamjuri Fahmi Asyadi Md Yusof |
author_sort | Zatil Hafila Kamaruddin |
collection | UMS |
description | Increasing environmental awareness and concern have shifted the focus of research and development towards biodegradable materials development. In the current study, Cymbopogan citratus fibre (CCF) were incorporated into thermoplastic cassava starch (TPCS) with various content of CCF (10, 20, 30, 40, 50, 60 wt.%) via compression moulding. The determination of fundamental characteristics of TPCS/CCF biopolymer composites was conducted to assess their potential as biodegradable reinforcements. Characterization of the samples was conducted via Fourier-transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM), as well as mechanical, moisture absorption, and soil burial testings. The findings showed that the improved tensile and flexural features of the TPCS composites with CCF incorporation, with 50 wt.% CCF content yielded the maximum modulus and strength. The thermal properties of the biocomposite demonstrated that CCF addition improved the material’s thermal stability, as shown by a higher-onset decomposition temperature and ash content. Meanwhile, the CCF incorporation into TPCS slowed down the biodegradation of the composites. In term of morphological, homoge-neous fibres and matrix dispersion with excellent adhesion was observed in morphological analyses using scanning electron microscopy (SEM), which is crucial for the enhancement of the mechanical performance of biocomposites. |
first_indexed | 2024-03-06T03:18:13Z |
format | Article |
id | ums.eprints-33411 |
institution | Universiti Malaysia Sabah |
language | English English |
last_indexed | 2024-03-06T03:18:13Z |
publishDate | 2022 |
publisher | MDPI |
record_format | dspace |
spelling | ums.eprints-334112022-07-21T01:03:36Z https://eprints.ums.edu.my/id/eprint/33411/ Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties Zatil Hafila Kamaruddin Ridhwan Jumaidin Rushdan Ahmad Ilyas Mohd Zulkefli Selamat Roziela Hanim Alamjuri Fahmi Asyadi Md Yusof TP200-248 Chemicals: Manufacture, use, etc. Increasing environmental awareness and concern have shifted the focus of research and development towards biodegradable materials development. In the current study, Cymbopogan citratus fibre (CCF) were incorporated into thermoplastic cassava starch (TPCS) with various content of CCF (10, 20, 30, 40, 50, 60 wt.%) via compression moulding. The determination of fundamental characteristics of TPCS/CCF biopolymer composites was conducted to assess their potential as biodegradable reinforcements. Characterization of the samples was conducted via Fourier-transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM), as well as mechanical, moisture absorption, and soil burial testings. The findings showed that the improved tensile and flexural features of the TPCS composites with CCF incorporation, with 50 wt.% CCF content yielded the maximum modulus and strength. The thermal properties of the biocomposite demonstrated that CCF addition improved the material’s thermal stability, as shown by a higher-onset decomposition temperature and ash content. Meanwhile, the CCF incorporation into TPCS slowed down the biodegradation of the composites. In term of morphological, homoge-neous fibres and matrix dispersion with excellent adhesion was observed in morphological analyses using scanning electron microscopy (SEM), which is crucial for the enhancement of the mechanical performance of biocomposites. MDPI 2022-01-27 Article NonPeerReviewed text en https://eprints.ums.edu.my/id/eprint/33411/2/Biocomposite%20of%20cassava%20starch-cymbopogan%20citratus%20fibre%2C%20Mechanical%2C%20thermal%20and%20biodegradation%20properties.ABSTRACT.pdf text en https://eprints.ums.edu.my/id/eprint/33411/1/Biocomposite%20of%20Cassava%20Starch-Cymbopogan%20Citratus%20Fibre%2C%20Mechanical%2C%20Thermal%20and%20Biodegradation%20Properties.pdf Zatil Hafila Kamaruddin and Ridhwan Jumaidin and Rushdan Ahmad Ilyas and Mohd Zulkefli Selamat and Roziela Hanim Alamjuri and Fahmi Asyadi Md Yusof (2022) Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties. Polymers, 14. pp. 1-19. ISSN 2073-4360 https://www.mdpi.com/2073-4360/14/3/514/pdf https://doi.10.3390/polym14030514 https://doi.10.3390/polym14030514 |
spellingShingle | TP200-248 Chemicals: Manufacture, use, etc. Zatil Hafila Kamaruddin Ridhwan Jumaidin Rushdan Ahmad Ilyas Mohd Zulkefli Selamat Roziela Hanim Alamjuri Fahmi Asyadi Md Yusof Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties |
title | Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties |
title_full | Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties |
title_fullStr | Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties |
title_full_unstemmed | Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties |
title_short | Biocomposite of cassava starch-cymbopogan citratus fibre: Mechanical, thermal and biodegradation properties |
title_sort | biocomposite of cassava starch cymbopogan citratus fibre mechanical thermal and biodegradation properties |
topic | TP200-248 Chemicals: Manufacture, use, etc. |
url | https://eprints.ums.edu.my/id/eprint/33411/2/Biocomposite%20of%20cassava%20starch-cymbopogan%20citratus%20fibre%2C%20Mechanical%2C%20thermal%20and%20biodegradation%20properties.ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/33411/1/Biocomposite%20of%20Cassava%20Starch-Cymbopogan%20Citratus%20Fibre%2C%20Mechanical%2C%20Thermal%20and%20Biodegradation%20Properties.pdf |
work_keys_str_mv | AT zatilhafilakamaruddin biocompositeofcassavastarchcymbopogancitratusfibremechanicalthermalandbiodegradationproperties AT ridhwanjumaidin biocompositeofcassavastarchcymbopogancitratusfibremechanicalthermalandbiodegradationproperties AT rushdanahmadilyas biocompositeofcassavastarchcymbopogancitratusfibremechanicalthermalandbiodegradationproperties AT mohdzulkefliselamat biocompositeofcassavastarchcymbopogancitratusfibremechanicalthermalandbiodegradationproperties AT rozielahanimalamjuri biocompositeofcassavastarchcymbopogancitratusfibremechanicalthermalandbiodegradationproperties AT fahmiasyadimdyusof biocompositeofcassavastarchcymbopogancitratusfibremechanicalthermalandbiodegradationproperties |