Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol
A series of promoted CeO2/Al2O3 catalysts (10Cu-90CeO2/Al2O3, 10Ni-90CeO2/Al2O3, 10Co-90CeO2/Al2O3) were synthesized via method of impregnation and later calcined at 600 ℃. Those catalysts were formerly tested for their physicochemical properties by X-ray diffraction (XRD), H2-temperature programmed...
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| Format: | Article |
| Language: | English English |
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The Malaysian Journal of Analytical Sciences
2024
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| Online Access: | https://eprints.ums.edu.my/id/eprint/40951/1/ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/40951/2/FULL%20TEXT.pdf |
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| author | Norsahida Azri Ramli Irmawati Rudy Hakim Danial Leong Usman Idris Nda-Umar Mohd Izham Saiman Yun Hin Taufiq-Yap G. AbdulKareem-Alsultan |
| author_facet | Norsahida Azri Ramli Irmawati Rudy Hakim Danial Leong Usman Idris Nda-Umar Mohd Izham Saiman Yun Hin Taufiq-Yap G. AbdulKareem-Alsultan |
| author_sort | Norsahida Azri |
| collection | UMS |
| description | A series of promoted CeO2/Al2O3 catalysts (10Cu-90CeO2/Al2O3, 10Ni-90CeO2/Al2O3, 10Co-90CeO2/Al2O3) were synthesized via method of impregnation and later calcined at 600 ℃. Those catalysts were formerly tested for their physicochemical properties by X-ray diffraction (XRD), H2-temperature programmed reduction (H2-TPR), and NH3-temperature programmed desorption (NH3–TPD). After characterized, it was then evaluated in the performance of catalytic glycerol conversion into 1,2-propanediol; propylene glycol (1,2-PDO; PG) via aqueous phase glycerol reforming and hydrogenolysis route under inert N2 flow. Among the examined catalysts, CeO2/Al2O3 with 10wt% Cu loading (10Cu-90CeO2/Al2O3) showed optimum catalytic activity with 88.5% glycerol conversion (GC) and 35.5% PG selectivity at 300 ℃ reaction temperature, 2 h duration test, 30 cc/min of N2 initial pressure, 0.1 g catalyst dosage and 10wt% glycerol concentration. The high catalytic performance of 10Cu90CeO2/Al2O3 was owing to the good copper-cerium-alumina interaction via its good metal reducibility at low temperature along with good acid capacity for the reaction. |
| first_indexed | 2024-09-24T00:52:38Z |
| format | Article |
| id | ums.eprints-40951 |
| institution | Universiti Malaysia Sabah |
| language | English English |
| last_indexed | 2024-09-24T00:52:38Z |
| publishDate | 2024 |
| publisher | The Malaysian Journal of Analytical Sciences |
| record_format | dspace |
| spelling | ums.eprints-409512024-09-02T08:09:40Z https://eprints.ums.edu.my/id/eprint/40951/ Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol Norsahida Azri Ramli Irmawati Rudy Hakim Danial Leong Usman Idris Nda-Umar Mohd Izham Saiman Yun Hin Taufiq-Yap G. AbdulKareem-Alsultan TN400-580 Ore deposits and mining of particular metals TP1-1185 Chemical technology A series of promoted CeO2/Al2O3 catalysts (10Cu-90CeO2/Al2O3, 10Ni-90CeO2/Al2O3, 10Co-90CeO2/Al2O3) were synthesized via method of impregnation and later calcined at 600 ℃. Those catalysts were formerly tested for their physicochemical properties by X-ray diffraction (XRD), H2-temperature programmed reduction (H2-TPR), and NH3-temperature programmed desorption (NH3–TPD). After characterized, it was then evaluated in the performance of catalytic glycerol conversion into 1,2-propanediol; propylene glycol (1,2-PDO; PG) via aqueous phase glycerol reforming and hydrogenolysis route under inert N2 flow. Among the examined catalysts, CeO2/Al2O3 with 10wt% Cu loading (10Cu-90CeO2/Al2O3) showed optimum catalytic activity with 88.5% glycerol conversion (GC) and 35.5% PG selectivity at 300 ℃ reaction temperature, 2 h duration test, 30 cc/min of N2 initial pressure, 0.1 g catalyst dosage and 10wt% glycerol concentration. The high catalytic performance of 10Cu90CeO2/Al2O3 was owing to the good copper-cerium-alumina interaction via its good metal reducibility at low temperature along with good acid capacity for the reaction. The Malaysian Journal of Analytical Sciences 2024 Article NonPeerReviewed text en https://eprints.ums.edu.my/id/eprint/40951/1/ABSTRACT.pdf text en https://eprints.ums.edu.my/id/eprint/40951/2/FULL%20TEXT.pdf Norsahida Azri and Ramli Irmawati and Rudy Hakim Danial Leong and Usman Idris Nda-Umar and Mohd Izham Saiman and Yun Hin Taufiq-Yap and G. AbdulKareem-Alsultan (2024) Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol. Malaysian Journal of Analytical Sciences, 28 (2). pp. 1-8. ISSN 1394-2506 |
| spellingShingle | TN400-580 Ore deposits and mining of particular metals TP1-1185 Chemical technology Norsahida Azri Ramli Irmawati Rudy Hakim Danial Leong Usman Idris Nda-Umar Mohd Izham Saiman Yun Hin Taufiq-Yap G. AbdulKareem-Alsultan Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol |
| title | Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol |
| title_full | Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol |
| title_fullStr | Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol |
| title_full_unstemmed | Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol |
| title_short | Screening of promoted CeO2/Al2O3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1,2-propanediol |
| title_sort | screening of promoted ceo2 al2o3 catalysts in aqueous phase glycerol reforming and hydrogenolysis into 1 2 propanediol |
| topic | TN400-580 Ore deposits and mining of particular metals TP1-1185 Chemical technology |
| url | https://eprints.ums.edu.my/id/eprint/40951/1/ABSTRACT.pdf https://eprints.ums.edu.my/id/eprint/40951/2/FULL%20TEXT.pdf |
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