Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance

The two major global issues; climate change and global energy demand will have been increasing in the future especially in both developing and developed countries. These two major global issues are basically due to the industrial activity and advanced lifestyle in that country. Therefore, the Carbon...

Full description

Bibliographic Details
Main Authors: Huzaikha Awang, Tan, Lling Lling
Format: Proceedings
Language:English
English
Published: Pusat e-pembelajaran, UMS 2021
Subjects:
Online Access:https://eprints.ums.edu.my/id/eprint/41618/1/ABSTRACT.pdf
https://eprints.ums.edu.my/id/eprint/41618/2/FULL%20TEXT.pdf
_version_ 1825715897683148800
author Huzaikha Awang
Tan, Lling Lling
author_facet Huzaikha Awang
Tan, Lling Lling
author_sort Huzaikha Awang
collection UMS
description The two major global issues; climate change and global energy demand will have been increasing in the future especially in both developing and developed countries. These two major global issues are basically due to the industrial activity and advanced lifestyle in that country. Therefore, the Carbon Capture and Conversion (CCC) method had been used in this research work. The CCC method has been used to capture and convert the CO₂ gas into hydrocarbon fuels such as methane gas. The Reduced graphene oxide-Titanium (rGO-TiO₂) sample in this experiment has been used to evaluate two research questions: the effect of synthesis method in sample’s physicochemical properties and the photocatalytic performance. There are three synthesize methods had used to extract the samples; solvothermal method by using a Tetrabutyl Titanate powder (TBT) as raw material, hydrothermal method by using TBT as raw material and hydrothermal method by using anatase P90 TiO₂ powder as a raw material. These three samples were fused at fixed temperature and treatment time with 180oC and 8 hours, respectively. The physicochemical properties of these three samples had been characterized via X-ray Diffractometry (XRD) and UV-Vis spectrophotometer. Furthermore, the Gas Chromatograph (GC) was used to examine the photocatalytic performance at the end of this experiment. The rGO-TiO₂ (H1) sample shows the best photocatalytic performance with 700 nmol/gcat number of methane (CH4) yield within 8 hours which obviously higher than rGO-TiO2 (S) and rGO-Anatase TiO₂ (H2) with only 387 nmol/ gcat and 297 nmol/gcat respectively. It can be concluded that the synthesis method had been affecting the physicochemical properties and the photocatalytic performance in photocatalysts.
first_indexed 2024-12-09T00:53:05Z
format Proceedings
id ums.eprints-41618
institution Universiti Malaysia Sabah
language English
English
last_indexed 2024-12-09T00:53:05Z
publishDate 2021
publisher Pusat e-pembelajaran, UMS
record_format dspace
spelling ums.eprints-416182024-10-25T01:29:20Z https://eprints.ums.edu.my/id/eprint/41618/ Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance Huzaikha Awang Tan, Lling Lling Q1-390 Science (General) TN1-997 Mining engineering. Metallurgy The two major global issues; climate change and global energy demand will have been increasing in the future especially in both developing and developed countries. These two major global issues are basically due to the industrial activity and advanced lifestyle in that country. Therefore, the Carbon Capture and Conversion (CCC) method had been used in this research work. The CCC method has been used to capture and convert the CO₂ gas into hydrocarbon fuels such as methane gas. The Reduced graphene oxide-Titanium (rGO-TiO₂) sample in this experiment has been used to evaluate two research questions: the effect of synthesis method in sample’s physicochemical properties and the photocatalytic performance. There are three synthesize methods had used to extract the samples; solvothermal method by using a Tetrabutyl Titanate powder (TBT) as raw material, hydrothermal method by using TBT as raw material and hydrothermal method by using anatase P90 TiO₂ powder as a raw material. These three samples were fused at fixed temperature and treatment time with 180oC and 8 hours, respectively. The physicochemical properties of these three samples had been characterized via X-ray Diffractometry (XRD) and UV-Vis spectrophotometer. Furthermore, the Gas Chromatograph (GC) was used to examine the photocatalytic performance at the end of this experiment. The rGO-TiO₂ (H1) sample shows the best photocatalytic performance with 700 nmol/gcat number of methane (CH4) yield within 8 hours which obviously higher than rGO-TiO2 (S) and rGO-Anatase TiO₂ (H2) with only 387 nmol/ gcat and 297 nmol/gcat respectively. It can be concluded that the synthesis method had been affecting the physicochemical properties and the photocatalytic performance in photocatalysts. Pusat e-pembelajaran, UMS 2021 Proceedings PeerReviewed text en https://eprints.ums.edu.my/id/eprint/41618/1/ABSTRACT.pdf text en https://eprints.ums.edu.my/id/eprint/41618/2/FULL%20TEXT.pdf Huzaikha Awang and Tan, Lling Lling (2021) Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance. https://oer.ums.edu.my/handle/oer_source_files/1874
spellingShingle Q1-390 Science (General)
TN1-997 Mining engineering. Metallurgy
Huzaikha Awang
Tan, Lling Lling
Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance
title Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance
title_full Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance
title_fullStr Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance
title_full_unstemmed Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance
title_short Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance
title_sort preliminary study of reduced graphene oxide titanium rgo tio₂ photocatalyst for co₂ reduction into methane the physicochemical analysis photocatalyst performance
topic Q1-390 Science (General)
TN1-997 Mining engineering. Metallurgy
url https://eprints.ums.edu.my/id/eprint/41618/1/ABSTRACT.pdf
https://eprints.ums.edu.my/id/eprint/41618/2/FULL%20TEXT.pdf
work_keys_str_mv AT huzaikhaawang preliminarystudyofreducedgrapheneoxidetitaniumrgotio2photocatalystforco2reductionintomethanethephysicochemicalanalysisphotocatalystperformance
AT tanllinglling preliminarystudyofreducedgrapheneoxidetitaniumrgotio2photocatalystforco2reductionintomethanethephysicochemicalanalysisphotocatalystperformance