Effect of thermal treatment on physical properties of Malaysian dolomitic limestone

Thermal treatment of dolomite powder from Kangar (northern region of Malaysia) was carried out at temperatures ranging from 400–800 °C. The modifications that dolomite undergoes during thermal treatment have been investigated using X-ray diffraction patterns (XRD). Additionally, Fourier Transform In...

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Main Authors: Che Abdullah, Che Azurahanim, Albert, Emmellie Laura, Gee, Een Lau, Mohd Yusoff, Mohd Zaki, Abu Zarin, Mazni
Format: Article
Published: Electroactive Materials Society 2022
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author Che Abdullah, Che Azurahanim
Albert, Emmellie Laura
Gee, Een Lau
Mohd Yusoff, Mohd Zaki
Abu Zarin, Mazni
author_facet Che Abdullah, Che Azurahanim
Albert, Emmellie Laura
Gee, Een Lau
Mohd Yusoff, Mohd Zaki
Abu Zarin, Mazni
author_sort Che Abdullah, Che Azurahanim
collection UPM
description Thermal treatment of dolomite powder from Kangar (northern region of Malaysia) was carried out at temperatures ranging from 400–800 °C. The modifications that dolomite undergoes during thermal treatment have been investigated using X-ray diffraction patterns (XRD). Additionally, Fourier Transform Infrared (FTIR) spectroscopy and Field Emission Scanning Electron Microscopy were used to discuss the results (FESEM). The XRD data, analysed using the X’Pert Highscore Plus application, revealed that as the heat treatment temperature was increased, the crystallinity degree and crystallite size decreased progressively. XRD analysis revealed that the samples are highly crystalline, consisting of two major phases: dolomite and calcium carbonate. After thermal treatment at 800 °C, the major phase of dolomite vanished, revealing a higher Ca(OH)2 content. FTIR spectral analysis determined that the primary component of dolomite is a carbonate mineral and that the primary characteristic bands of dolomite are located between 872 and 876 cm-1. FESEM analysis revealed the presence of discrete grains with preferential orientation, whereas post-thermal treatment completely destroyed the dolomite's original particle shape, resulting in the formation of smaller spherical particles consistent with the XRD data. The findings may pave the way for a better understanding of the phenomena that occur during dolomite thermal treatment, the changes in their physical properties, and their potential applications in a variety of bio-related commercial industries.
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spelling upm.eprints-1011482023-05-23T07:15:27Z http://psasir.upm.edu.my/id/eprint/101148/ Effect of thermal treatment on physical properties of Malaysian dolomitic limestone Che Abdullah, Che Azurahanim Albert, Emmellie Laura Gee, Een Lau Mohd Yusoff, Mohd Zaki Abu Zarin, Mazni Thermal treatment of dolomite powder from Kangar (northern region of Malaysia) was carried out at temperatures ranging from 400–800 °C. The modifications that dolomite undergoes during thermal treatment have been investigated using X-ray diffraction patterns (XRD). Additionally, Fourier Transform Infrared (FTIR) spectroscopy and Field Emission Scanning Electron Microscopy were used to discuss the results (FESEM). The XRD data, analysed using the X’Pert Highscore Plus application, revealed that as the heat treatment temperature was increased, the crystallinity degree and crystallite size decreased progressively. XRD analysis revealed that the samples are highly crystalline, consisting of two major phases: dolomite and calcium carbonate. After thermal treatment at 800 °C, the major phase of dolomite vanished, revealing a higher Ca(OH)2 content. FTIR spectral analysis determined that the primary component of dolomite is a carbonate mineral and that the primary characteristic bands of dolomite are located between 872 and 876 cm-1. FESEM analysis revealed the presence of discrete grains with preferential orientation, whereas post-thermal treatment completely destroyed the dolomite's original particle shape, resulting in the formation of smaller spherical particles consistent with the XRD data. The findings may pave the way for a better understanding of the phenomena that occur during dolomite thermal treatment, the changes in their physical properties, and their potential applications in a variety of bio-related commercial industries. Electroactive Materials Society 2022-03-11 Article PeerReviewed Che Abdullah, Che Azurahanim and Albert, Emmellie Laura and Gee, Een Lau and Mohd Yusoff, Mohd Zaki and Abu Zarin, Mazni (2022) Effect of thermal treatment on physical properties of Malaysian dolomitic limestone. International Journal of Electroactive Materials, 10 (1). 18 - 23. ISSN 2289-8360 https://www.electroactmater.com/index.php/volume-10-2022?id=60&subid=428
spellingShingle Che Abdullah, Che Azurahanim
Albert, Emmellie Laura
Gee, Een Lau
Mohd Yusoff, Mohd Zaki
Abu Zarin, Mazni
Effect of thermal treatment on physical properties of Malaysian dolomitic limestone
title Effect of thermal treatment on physical properties of Malaysian dolomitic limestone
title_full Effect of thermal treatment on physical properties of Malaysian dolomitic limestone
title_fullStr Effect of thermal treatment on physical properties of Malaysian dolomitic limestone
title_full_unstemmed Effect of thermal treatment on physical properties of Malaysian dolomitic limestone
title_short Effect of thermal treatment on physical properties of Malaysian dolomitic limestone
title_sort effect of thermal treatment on physical properties of malaysian dolomitic limestone
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