Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects

The adsorption process combined with electrocoagulation is a highly effective technique for dye removal. Calcinized and non-calcinized composites based on bentonite and sodium zeolite were prepared for adsorptive removal of Foron EBL blue, Terasil brown 2RFL, Torque blue PG, and Orange P3R dyes. Fac...

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Main Authors: Javed, Ifrah, Hanif, Muhammad Asif, Rashid, Umer, Nadeem, Farwa, Alharthi, Fahad A., Kazerooni, Elham Ahmed
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2022
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author Javed, Ifrah
Hanif, Muhammad Asif
Rashid, Umer
Nadeem, Farwa
Alharthi, Fahad A.
Kazerooni, Elham Ahmed
author_facet Javed, Ifrah
Hanif, Muhammad Asif
Rashid, Umer
Nadeem, Farwa
Alharthi, Fahad A.
Kazerooni, Elham Ahmed
author_sort Javed, Ifrah
collection UPM
description The adsorption process combined with electrocoagulation is a highly effective technique for dye removal. Calcinized and non-calcinized composites based on bentonite and sodium zeolite were prepared for adsorptive removal of Foron EBL blue, Terasil brown 2RFL, Torque blue PG, and Orange P3R dyes. Factors affecting the adsorption process, such as contact time, initial dye concentration, and temperature, were also explored in this study. Equilibrium data of natural clay composites was explained by Freundlich, Langmuir, Dubinin Radushkevich isotherm, Harkin Jura, and Temkin isothermal models. Harkin Jura isotherm model best fitted on the adsorption mechanism compared to Langmuir and Temkin isotherm model. Morphology of clay-based adsorbents and functional group arrangement were investigated by scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The calcinized nano-composite material exhibited better adsorption capacity than non-calcinized nano-composite and could be employed as a low-cost alternative for dye removal.
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spelling upm.eprints-1012722023-08-18T23:39:06Z http://psasir.upm.edu.my/id/eprint/101272/ Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects Javed, Ifrah Hanif, Muhammad Asif Rashid, Umer Nadeem, Farwa Alharthi, Fahad A. Kazerooni, Elham Ahmed The adsorption process combined with electrocoagulation is a highly effective technique for dye removal. Calcinized and non-calcinized composites based on bentonite and sodium zeolite were prepared for adsorptive removal of Foron EBL blue, Terasil brown 2RFL, Torque blue PG, and Orange P3R dyes. Factors affecting the adsorption process, such as contact time, initial dye concentration, and temperature, were also explored in this study. Equilibrium data of natural clay composites was explained by Freundlich, Langmuir, Dubinin Radushkevich isotherm, Harkin Jura, and Temkin isothermal models. Harkin Jura isotherm model best fitted on the adsorption mechanism compared to Langmuir and Temkin isotherm model. Morphology of clay-based adsorbents and functional group arrangement were investigated by scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The calcinized nano-composite material exhibited better adsorption capacity than non-calcinized nano-composite and could be employed as a low-cost alternative for dye removal. Multidisciplinary Digital Publishing Institute 2022-08-24 Article PeerReviewed Javed, Ifrah and Hanif, Muhammad Asif and Rashid, Umer and Nadeem, Farwa and Alharthi, Fahad A. and Kazerooni, Elham Ahmed (2022) Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects. Water, 14 (17). art. no. 2600. pp. 1-19. ISSN 2073-4441 https://www.mdpi.com/2073-4441/14/17/2600 10.3390/w14172600
spellingShingle Javed, Ifrah
Hanif, Muhammad Asif
Rashid, Umer
Nadeem, Farwa
Alharthi, Fahad A.
Kazerooni, Elham Ahmed
Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects
title Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects
title_full Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects
title_fullStr Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects
title_full_unstemmed Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects
title_short Enhancing functionalities in nanocomposites for effective dye removal from wastewater: isothermal, kinetic and thermodynamic aspects
title_sort enhancing functionalities in nanocomposites for effective dye removal from wastewater isothermal kinetic and thermodynamic aspects
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