Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application

Porous carbon is prepared from the cornstarch biopolymer by simple carbonization process initially at 800 °C. This carbon sample has been activated by gasification with the help of oxidizing gas and by reaction with certain chemicals for its pore development. The final product of activated carbon is...

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Main Authors: Nath, Gaurav, Singh, Pramod K., Dhapola, Pawan Singh, Dohare, Sushil, Noor, I. M., Sharma, Tejas, Singh, Abhimanyu
Format: Article
Published: Springer 2022
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author Nath, Gaurav
Singh, Pramod K.
Dhapola, Pawan Singh
Dohare, Sushil
Noor, I. M.
Sharma, Tejas
Singh, Abhimanyu
author_facet Nath, Gaurav
Singh, Pramod K.
Dhapola, Pawan Singh
Dohare, Sushil
Noor, I. M.
Sharma, Tejas
Singh, Abhimanyu
author_sort Nath, Gaurav
collection UPM
description Porous carbon is prepared from the cornstarch biopolymer by simple carbonization process initially at 800 °C. This carbon sample has been activated by gasification with the help of oxidizing gas and by reaction with certain chemicals for its pore development. The final product of activated carbon is then characterized by techniques like XRD, RAMAN, BET, TGA, FESEM, and EDX to study all its behavior. The results of these characterizations have been thoroughly studied in the Sect. 3. The carbon is used as an electrode material to decorate the supercapacitor electrode by 1 mg of coating. Polymer electrolyte film of PVDF-HFP doped with 300 wt% of 1-ethyl-3-methylimidazolium tricyanomethanide (TCM) (optimized for better conductivity) ionic liquid is used as a separator. A supercapacitor device is then fabricated at laboratory scale with the prepared porous carbon electrodes sandwiched with the electrolyte film which yield a specific capacitance of 188.4 F/gm at 10 mHz confirmed from the electrochemical low-frequency impedance spectroscopy plot. Cyclic voltammetry results were also measured, yielding a high specific capacitance of 184.8 F/gm at 5 mV/s.
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spelling upm.eprints-1014512023-09-22T23:43:36Z http://psasir.upm.edu.my/id/eprint/101451/ Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application Nath, Gaurav Singh, Pramod K. Dhapola, Pawan Singh Dohare, Sushil Noor, I. M. Sharma, Tejas Singh, Abhimanyu Porous carbon is prepared from the cornstarch biopolymer by simple carbonization process initially at 800 °C. This carbon sample has been activated by gasification with the help of oxidizing gas and by reaction with certain chemicals for its pore development. The final product of activated carbon is then characterized by techniques like XRD, RAMAN, BET, TGA, FESEM, and EDX to study all its behavior. The results of these characterizations have been thoroughly studied in the Sect. 3. The carbon is used as an electrode material to decorate the supercapacitor electrode by 1 mg of coating. Polymer electrolyte film of PVDF-HFP doped with 300 wt% of 1-ethyl-3-methylimidazolium tricyanomethanide (TCM) (optimized for better conductivity) ionic liquid is used as a separator. A supercapacitor device is then fabricated at laboratory scale with the prepared porous carbon electrodes sandwiched with the electrolyte film which yield a specific capacitance of 188.4 F/gm at 10 mHz confirmed from the electrochemical low-frequency impedance spectroscopy plot. Cyclic voltammetry results were also measured, yielding a high specific capacitance of 184.8 F/gm at 5 mV/s. Springer 2022-04-14 Article PeerReviewed Nath, Gaurav and Singh, Pramod K. and Dhapola, Pawan Singh and Dohare, Sushil and Noor, I. M. and Sharma, Tejas and Singh, Abhimanyu (2022) Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application. Biomass Conversion and Biorefinery. pp. 1-8. ISSN 2190-6815; ESSN: 2190-6823 https://link.springer.com/article/10.1007/s13399-022-02656-1 10.1007/s13399-022-02656-1
spellingShingle Nath, Gaurav
Singh, Pramod K.
Dhapola, Pawan Singh
Dohare, Sushil
Noor, I. M.
Sharma, Tejas
Singh, Abhimanyu
Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application
title Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application
title_full Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application
title_fullStr Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application
title_full_unstemmed Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application
title_short Fabrication of cornstarch biopolymer-derived nano porous carbon as electrode material for supercapacitor application
title_sort fabrication of cornstarch biopolymer derived nano porous carbon as electrode material for supercapacitor application
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