In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil
Deoxygenation is a highly significant means of generating oxygen-free hydrocarbon fuels from liquid biomass. This study will deoxygenate sludge palm oil (FFA % = 42.35%) in an H2-free atmosphere through a series of Mn-Co supported AC catalysts (MnO0.5CoO0.5/AC, Mn0.5Co0.5S/AC and Mn0.5Co0.5P/AC). Th...
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| Format: | Article |
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Elsevier
2022
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| _version_ | 1825938616980865024 |
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| author | Alsultan, G. Abdulkareem Mijan, N. Asikin Obeas, Laith K. Yunus, Robiah Razali, Siti Zulaika Islam, Aminul Yap, Taufiq Yun Hin |
| author_facet | Alsultan, G. Abdulkareem Mijan, N. Asikin Obeas, Laith K. Yunus, Robiah Razali, Siti Zulaika Islam, Aminul Yap, Taufiq Yun Hin |
| author_sort | Alsultan, G. Abdulkareem |
| collection | UPM |
| description | Deoxygenation is a highly significant means of generating oxygen-free hydrocarbon fuels from liquid biomass. This study will deoxygenate sludge palm oil (FFA % = 42.35%) in an H2-free atmosphere through a series of Mn-Co supported AC catalysts (MnO0.5CoO0.5/AC, Mn0.5Co0.5S/AC and Mn0.5Co0.5P/AC). The XAS in-situ results confirm that the preparation method of formation the catalyst structure was successful. The catalytic results show that by oligomerizing unsaturated fatty acids produced during Diels-Alder reactions or radical additions, the MnO0.5)CoO0.5/AC can largely enhance the production of heavy products. It is a straightforward process to transform these heavy products into coke species, which enables the rapid deactivation of the catalyst. This study additionally showed that AC-supported sulphide and phosphide Mn-Co catalysts are hugely beneficial for steadily and reliably acquiring an above-average yield of diesel-range hydrocarbons at substantially reduced temperatures whilst simultaneously effectively impeding catalyst deactivation during deoxygenation. The deactivation kinetic study conform that the deactivation happens by the coke formation and flow the second order deactivation. |
| first_indexed | 2024-03-06T11:16:14Z |
| format | Article |
| id | upm.eprints-101938 |
| institution | Universiti Putra Malaysia |
| last_indexed | 2024-03-06T11:16:14Z |
| publishDate | 2022 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | upm.eprints-1019382023-07-10T00:38:40Z http://psasir.upm.edu.my/id/eprint/101938/ In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil Alsultan, G. Abdulkareem Mijan, N. Asikin Obeas, Laith K. Yunus, Robiah Razali, Siti Zulaika Islam, Aminul Yap, Taufiq Yun Hin Deoxygenation is a highly significant means of generating oxygen-free hydrocarbon fuels from liquid biomass. This study will deoxygenate sludge palm oil (FFA % = 42.35%) in an H2-free atmosphere through a series of Mn-Co supported AC catalysts (MnO0.5CoO0.5/AC, Mn0.5Co0.5S/AC and Mn0.5Co0.5P/AC). The XAS in-situ results confirm that the preparation method of formation the catalyst structure was successful. The catalytic results show that by oligomerizing unsaturated fatty acids produced during Diels-Alder reactions or radical additions, the MnO0.5)CoO0.5/AC can largely enhance the production of heavy products. It is a straightforward process to transform these heavy products into coke species, which enables the rapid deactivation of the catalyst. This study additionally showed that AC-supported sulphide and phosphide Mn-Co catalysts are hugely beneficial for steadily and reliably acquiring an above-average yield of diesel-range hydrocarbons at substantially reduced temperatures whilst simultaneously effectively impeding catalyst deactivation during deoxygenation. The deactivation kinetic study conform that the deactivation happens by the coke formation and flow the second order deactivation. Elsevier 2022 Article PeerReviewed Alsultan, G. Abdulkareem and Mijan, N. Asikin and Obeas, Laith K. and Yunus, Robiah and Razali, Siti Zulaika and Islam, Aminul and Yap, Taufiq Yun Hin (2022) In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil. Chemical Engineering Journal, 429. art. no. 132206. pp. 1-15. ISSN 1385-8947; ESSN: 1873-3212 https://www.sciencedirect.com/science/article/pii/S1385894721037852 10.1016/j.cej.2021.132206 |
| spellingShingle | Alsultan, G. Abdulkareem Mijan, N. Asikin Obeas, Laith K. Yunus, Robiah Razali, Siti Zulaika Islam, Aminul Yap, Taufiq Yun Hin In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil |
| title | In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil |
| title_full | In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil |
| title_fullStr | In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil |
| title_full_unstemmed | In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil |
| title_short | In-situ operando and ex-situ study on light hydrocarbon-like-diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil |
| title_sort | in situ operando and ex situ study on light hydrocarbon like diesel and catalyst deactivation kinetic and mechanism study during deoxygenation of sludge oil |
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