One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels
In this work, green diesel was generated via one-pot decarboxylation/decarbonylation (deoxygenation) reactions over a series of Ni20Znx/AC (X: 5–20 wt%) catalysts. The Ni20Zn10/AC catalyst exhibited superior deoxygenation reaction by yielding 86% hydrocarbons and 79% of n-(C15 + C17) selectivity, wi...
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| Format: | Article |
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Elsevier BV
2022
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| _version_ | 1825938697124577280 |
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| author | Wan Khalit, Wan Nor Adira Mijan, N. Asikin Tengku Sharifah Marliza Gamal, M. Safa Shamsuddin, Mohd Razali I., Nur Azreena Saiman, Mohd Izham Y. H., Taufiq Yap |
| author_facet | Wan Khalit, Wan Nor Adira Mijan, N. Asikin Tengku Sharifah Marliza Gamal, M. Safa Shamsuddin, Mohd Razali I., Nur Azreena Saiman, Mohd Izham Y. H., Taufiq Yap |
| author_sort | Wan Khalit, Wan Nor Adira |
| collection | UPM |
| description | In this work, green diesel was generated via one-pot decarboxylation/decarbonylation (deoxygenation) reactions over a series of Ni20Znx/AC (X: 5–20 wt%) catalysts. The Ni20Zn10/AC catalyst exhibited superior deoxygenation reaction by yielding 86% hydrocarbons and 79% of n-(C15 + C17) selectivity, with the activity tending to undergo the decarbonylation pathway. Indeed, high deoxygenation activity is correlated with a higher acidity and basicity strength of the catalyst, and the removal of the oxygenates species occurred via decarbonylation pathways. The Ni20Zn10/AC catalyst showed a promising catalytic longevity and recyclability up until four runs, with a hydrocarbon yield of 78–87% and n-(C15 + C17) selectivity within the range of 43–70%. The decrease in the n-(C15 + C17) selectivity at the fourth cycle was due to leaching of active metal and the coking activity. The fuel properties of the green diesel (G100) were investigated, and it was revealed that the green diesel almost exhibited outstanding fuel properties (acid value, kinematic viscosity, flash point, cetane index, and calorific value) in comparison with ultra-low sulfur diesel (ULSD), suggesting that G100 can be used in vehicle engines without modification and has great potential for commercialization. |
| first_indexed | 2024-03-06T11:17:17Z |
| format | Article |
| id | upm.eprints-102373 |
| institution | Universiti Putra Malaysia |
| last_indexed | 2024-03-06T11:17:17Z |
| publishDate | 2022 |
| publisher | Elsevier BV |
| record_format | dspace |
| spelling | upm.eprints-1023732023-06-07T08:41:20Z http://psasir.upm.edu.my/id/eprint/102373/ One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels Wan Khalit, Wan Nor Adira Mijan, N. Asikin Tengku Sharifah Marliza Gamal, M. Safa Shamsuddin, Mohd Razali I., Nur Azreena Saiman, Mohd Izham Y. H., Taufiq Yap In this work, green diesel was generated via one-pot decarboxylation/decarbonylation (deoxygenation) reactions over a series of Ni20Znx/AC (X: 5–20 wt%) catalysts. The Ni20Zn10/AC catalyst exhibited superior deoxygenation reaction by yielding 86% hydrocarbons and 79% of n-(C15 + C17) selectivity, with the activity tending to undergo the decarbonylation pathway. Indeed, high deoxygenation activity is correlated with a higher acidity and basicity strength of the catalyst, and the removal of the oxygenates species occurred via decarbonylation pathways. The Ni20Zn10/AC catalyst showed a promising catalytic longevity and recyclability up until four runs, with a hydrocarbon yield of 78–87% and n-(C15 + C17) selectivity within the range of 43–70%. The decrease in the n-(C15 + C17) selectivity at the fourth cycle was due to leaching of active metal and the coking activity. The fuel properties of the green diesel (G100) were investigated, and it was revealed that the green diesel almost exhibited outstanding fuel properties (acid value, kinematic viscosity, flash point, cetane index, and calorific value) in comparison with ultra-low sulfur diesel (ULSD), suggesting that G100 can be used in vehicle engines without modification and has great potential for commercialization. Elsevier BV 2022 Article PeerReviewed Wan Khalit, Wan Nor Adira and Mijan, N. Asikin and Tengku Sharifah Marliza and Gamal, M. Safa and Shamsuddin, Mohd Razali and I., Nur Azreena and Saiman, Mohd Izham and Y. H., Taufiq Yap (2022) One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels. Journal of Analytical and Applied, 164. pp. 1-15. ISSN 0165-2370; ESSN: 1873-250X https://www.sciencedirect.com/science/article/pii/S0165237022000754 10.1016/j.jaap.2022.105505 |
| spellingShingle | Wan Khalit, Wan Nor Adira Mijan, N. Asikin Tengku Sharifah Marliza Gamal, M. Safa Shamsuddin, Mohd Razali I., Nur Azreena Saiman, Mohd Izham Y. H., Taufiq Yap One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels |
| title | One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels |
| title_full | One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels |
| title_fullStr | One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels |
| title_full_unstemmed | One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels |
| title_short | One-pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel-zinc catalyst into diesel-like fuels |
| title_sort | one pot decarboxylation and decarbonylation reaction of waste cooking oil over activated carbon supported nickel zinc catalyst into diesel like fuels |
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