Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass

Samarium (III) oxide doped zinc-borosilicate glasses were successfully fabricated using the melt-quenching method by using SLS glass as a source of SiO2. With the progression of Sm3+ concentration, the density of the sample improved from 3.423 g/cm3 to 3.495 g/cm3, while the molar volume raised from...

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Main Authors: Cheong, Wei Mun, Mohd Zaid, Mohd Hafiz, Matori, Khamirul Amin, Fen, Yap Wing, Tee, Tan Sin, Loh, Zhi Wei, Schmid, Siegbert
Format: Article
Published: Elsevier 2022
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author Cheong, Wei Mun
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Fen, Yap Wing
Tee, Tan Sin
Loh, Zhi Wei
Schmid, Siegbert
author_facet Cheong, Wei Mun
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Fen, Yap Wing
Tee, Tan Sin
Loh, Zhi Wei
Schmid, Siegbert
author_sort Cheong, Wei Mun
collection UPM
description Samarium (III) oxide doped zinc-borosilicate glasses were successfully fabricated using the melt-quenching method by using SLS glass as a source of SiO2. With the progression of Sm3+ concentration, the density of the sample improved from 3.423 g/cm3 to 3.495 g/cm3, while the molar volume raised from 21.760 cm3/mol to 23.665 cm3/mol. The XRD analysis verified the samples’ amorphous nature. Besides, the longitudinal and shear velocity range between 5265.15 and 5706.244 m/s and 2900.247–3039.522 m/s, respectively. The elastic moduli for longitudinal, shear, bulk, and Young’s modulus range between 96.389–111.457 GPa, 29.247–31.624 GPa, 56.493–69.292 GPa, and 75.000–82.345, respectively. Furthermore, with the increment of Sm3+ concentration, the sample’s Poisson’s ratio reduces from 0.302 to 0.270, indicating a progressive rise in cross-link density due to increased glass ionicity. Moreover, the fractal bond connectivity and fugacity rise from 1.826 to 2.170 and 0.060 to 0.083, respectively, with the progression of Sm3+ concentration. The findings imply that the Sm3+ dopant acts as a glass modifier, impacting the elastic performance of the zinc-borosilicate glasses.
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spelling upm.eprints-1033172023-06-26T07:41:36Z http://psasir.upm.edu.my/id/eprint/103317/ Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass Cheong, Wei Mun Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Fen, Yap Wing Tee, Tan Sin Loh, Zhi Wei Schmid, Siegbert Samarium (III) oxide doped zinc-borosilicate glasses were successfully fabricated using the melt-quenching method by using SLS glass as a source of SiO2. With the progression of Sm3+ concentration, the density of the sample improved from 3.423 g/cm3 to 3.495 g/cm3, while the molar volume raised from 21.760 cm3/mol to 23.665 cm3/mol. The XRD analysis verified the samples’ amorphous nature. Besides, the longitudinal and shear velocity range between 5265.15 and 5706.244 m/s and 2900.247–3039.522 m/s, respectively. The elastic moduli for longitudinal, shear, bulk, and Young’s modulus range between 96.389–111.457 GPa, 29.247–31.624 GPa, 56.493–69.292 GPa, and 75.000–82.345, respectively. Furthermore, with the increment of Sm3+ concentration, the sample’s Poisson’s ratio reduces from 0.302 to 0.270, indicating a progressive rise in cross-link density due to increased glass ionicity. Moreover, the fractal bond connectivity and fugacity rise from 1.826 to 2.170 and 0.060 to 0.083, respectively, with the progression of Sm3+ concentration. The findings imply that the Sm3+ dopant acts as a glass modifier, impacting the elastic performance of the zinc-borosilicate glasses. Elsevier 2022 Article PeerReviewed Cheong, Wei Mun and Mohd Zaid, Mohd Hafiz and Matori, Khamirul Amin and Fen, Yap Wing and Tee, Tan Sin and Loh, Zhi Wei and Schmid, Siegbert (2022) Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass. Optik, 267. art. no. 169658. pp. 1-10. ISSN 0030-4026 https://www.sciencedirect.com/science/article/pii/S0030402622009457 10.1016/j.ijleo.2022.169658
spellingShingle Cheong, Wei Mun
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Fen, Yap Wing
Tee, Tan Sin
Loh, Zhi Wei
Schmid, Siegbert
Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass
title Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass
title_full Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass
title_fullStr Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass
title_full_unstemmed Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass
title_short Structural, elastic and mechanical analysis of samarium doped zinc-borosilicate glass
title_sort structural elastic and mechanical analysis of samarium doped zinc borosilicate glass
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