A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power

Developing a conductive cellulose film without any metal compounds remains challenging, though in great demand. However, cellulose film prepared from bacterial cellulose (BC) powder without any metal compounds has poor tensile, physical, and electrical properties, thus limiting its application. Here...

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Main Authors: Rahmadiawan, Dieter, Abral, Hairul, Kotodeli, Rafi Alzues, Sugiarti, Eni, Muslimin, Ahmad Novi, Admi, Ratna Isnanita, Arafat, Andril, Kim, Hyun-Joong, Sapuan, S. M., Kosasih, Engkos Achmad
Format: Article
Published: Multidisciplinary Digital Publishing Institute 2023
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author Rahmadiawan, Dieter
Abral, Hairul
Kotodeli, Rafi Alzues
Sugiarti, Eni
Muslimin, Ahmad Novi
Admi, Ratna Isnanita
Arafat, Andril
Kim, Hyun-Joong
Sapuan, S. M.
Kosasih, Engkos Achmad
author_facet Rahmadiawan, Dieter
Abral, Hairul
Kotodeli, Rafi Alzues
Sugiarti, Eni
Muslimin, Ahmad Novi
Admi, Ratna Isnanita
Arafat, Andril
Kim, Hyun-Joong
Sapuan, S. M.
Kosasih, Engkos Achmad
author_sort Rahmadiawan, Dieter
collection UPM
description Developing a conductive cellulose film without any metal compounds remains challenging, though in great demand. However, cellulose film prepared from bacterial cellulose (BC) powder without any metal compounds has poor tensile, physical, and electrical properties, thus limiting its application. Herein, this study aims to prepare and characterize an all-cellulose film from 2,2,6,6-Tetramethylpiperidin-1-yl)oxyl (TEMPO)-oxidized bacterial cellulose (TOBC) powders without adding metal compounds and treated by ultrasonication. TOBC powders are sonicated with various powers of 250, 500, and 750 W for 20 min without any other substance. It was proved that increasing the ultrasonication power level resulted in a significant improvement in the properties of the film. The ultrasonication of 750 W increased tensile strength by 85, toughness by 308, light transmittance by 542, and electrical conductivity by 174 compared to the nonsonicated film. A light-emitting diode connected to a power source through this sonicated film was much brighter than that connected via a nonsonicated film. For the first time, this study reports the preparation of electrically conductive, transparent, strong, and bendable pure TOBC films by increasing ultrasonic power for environmentally friendly electronic devices application.
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spelling upm.eprints-1065892024-08-06T06:49:20Z http://psasir.upm.edu.my/id/eprint/106589/ A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power Rahmadiawan, Dieter Abral, Hairul Kotodeli, Rafi Alzues Sugiarti, Eni Muslimin, Ahmad Novi Admi, Ratna Isnanita Arafat, Andril Kim, Hyun-Joong Sapuan, S. M. Kosasih, Engkos Achmad Developing a conductive cellulose film without any metal compounds remains challenging, though in great demand. However, cellulose film prepared from bacterial cellulose (BC) powder without any metal compounds has poor tensile, physical, and electrical properties, thus limiting its application. Herein, this study aims to prepare and characterize an all-cellulose film from 2,2,6,6-Tetramethylpiperidin-1-yl)oxyl (TEMPO)-oxidized bacterial cellulose (TOBC) powders without adding metal compounds and treated by ultrasonication. TOBC powders are sonicated with various powers of 250, 500, and 750 W for 20 min without any other substance. It was proved that increasing the ultrasonication power level resulted in a significant improvement in the properties of the film. The ultrasonication of 750 W increased tensile strength by 85, toughness by 308, light transmittance by 542, and electrical conductivity by 174 compared to the nonsonicated film. A light-emitting diode connected to a power source through this sonicated film was much brighter than that connected via a nonsonicated film. For the first time, this study reports the preparation of electrically conductive, transparent, strong, and bendable pure TOBC films by increasing ultrasonic power for environmentally friendly electronic devices application. Multidisciplinary Digital Publishing Institute 2023 Article PeerReviewed Rahmadiawan, Dieter and Abral, Hairul and Kotodeli, Rafi Alzues and Sugiarti, Eni and Muslimin, Ahmad Novi and Admi, Ratna Isnanita and Arafat, Andril and Kim, Hyun-Joong and Sapuan, S. M. and Kosasih, Engkos Achmad (2023) A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power. Polymers, 15 (3). pp. 1-16. ISSN 2073-4360 https://www.mdpi.com/2073-4360/15/3/643 10.3390/polym15030643
spellingShingle Rahmadiawan, Dieter
Abral, Hairul
Kotodeli, Rafi Alzues
Sugiarti, Eni
Muslimin, Ahmad Novi
Admi, Ratna Isnanita
Arafat, Andril
Kim, Hyun-Joong
Sapuan, S. M.
Kosasih, Engkos Achmad
A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power
title A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power
title_full A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power
title_fullStr A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power
title_full_unstemmed A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power
title_short A novel highly conductive, transparent, and strong pure-cellulose film from TEMPO-oxidized bacterial cellulose by increasing sonication power
title_sort novel highly conductive transparent and strong pure cellulose film from tempo oxidized bacterial cellulose by increasing sonication power
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