Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed
Multiple interactions of geogenic and anthropogenic activities can trigger groundwater pollution in the tropical savanna watershed. These interactions and resultant contamination have been studied using applied geochemical modeling, conventional hydrochemical plots, and multivariate geochemometric m...
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| Format: | Article |
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Springer Science and Business Media B.V.
2023
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| _version_ | 1825939582345019392 |
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| author | Mohammed, Adamu Usman Aris, Ahmad Zaharin Ramli, Mohammad Firuz Mohd Isa, Noorain Arabi, Abdullahi Suleiman Jabbo, Josiah Nuhu |
| author_facet | Mohammed, Adamu Usman Aris, Ahmad Zaharin Ramli, Mohammad Firuz Mohd Isa, Noorain Arabi, Abdullahi Suleiman Jabbo, Josiah Nuhu |
| author_sort | Mohammed, Adamu Usman |
| collection | UPM |
| description | Multiple interactions of geogenic and anthropogenic activities can trigger groundwater pollution in the tropical savanna watershed. These interactions and resultant contamination have been studied using applied geochemical modeling, conventional hydrochemical plots, and multivariate geochemometric methods, and the results are presented in this paper. The high alkalinity values recorded for the studied groundwater samples might emanate from the leaching of carbonate soil derived from limestone coupled with low rainfall and high temperature in the area. The principal component analysis (PCA) unveils three components with an eigenvalue > 1 and a total dataset variance of 67.37%; this implies that the temporary hardness of the groundwater and water–rock interaction with evaporite minerals (gypsum, halite, calcite, and trona) is the dominant factor affecting groundwater geochemistry. Likewise, the PCA revealed anthropogenic contamination by discharging SO42-,NO3-,Cl- and K + from agricultural activities and probable sewage leakages. Hierarchical cluster analysis (HCA) also revealed three clusters; cluster I reflects the dissolution of gypsum and halite with a high elevated load of NO3- released by anthropogenic activities. However, cluster II exhibited high KHCO32- and KCl- loading in the groundwater from weathering of bicarbonate and sylvite minerals. Sulfate (SO42-) dominated cluster III mineralogy resulting from weathering of anhydrite. The three clusters in the Maiganga watershed indicated anhydrite, gypsum, and halite undersaturation. These results suggest that combined anthropogenic and natural processes in the study area are linked with saturation indexes that regulate the modification of groundwater quality. |
| first_indexed | 2024-09-25T03:40:29Z |
| format | Article |
| id | upm.eprints-108125 |
| institution | Universiti Putra Malaysia |
| last_indexed | 2024-09-25T03:40:29Z |
| publishDate | 2023 |
| publisher | Springer Science and Business Media B.V. |
| record_format | dspace |
| spelling | upm.eprints-1081252024-09-24T07:23:54Z http://psasir.upm.edu.my/id/eprint/108125/ Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed Mohammed, Adamu Usman Aris, Ahmad Zaharin Ramli, Mohammad Firuz Mohd Isa, Noorain Arabi, Abdullahi Suleiman Jabbo, Josiah Nuhu Multiple interactions of geogenic and anthropogenic activities can trigger groundwater pollution in the tropical savanna watershed. These interactions and resultant contamination have been studied using applied geochemical modeling, conventional hydrochemical plots, and multivariate geochemometric methods, and the results are presented in this paper. The high alkalinity values recorded for the studied groundwater samples might emanate from the leaching of carbonate soil derived from limestone coupled with low rainfall and high temperature in the area. The principal component analysis (PCA) unveils three components with an eigenvalue > 1 and a total dataset variance of 67.37%; this implies that the temporary hardness of the groundwater and water–rock interaction with evaporite minerals (gypsum, halite, calcite, and trona) is the dominant factor affecting groundwater geochemistry. Likewise, the PCA revealed anthropogenic contamination by discharging SO42-,NO3-,Cl- and K + from agricultural activities and probable sewage leakages. Hierarchical cluster analysis (HCA) also revealed three clusters; cluster I reflects the dissolution of gypsum and halite with a high elevated load of NO3- released by anthropogenic activities. However, cluster II exhibited high KHCO32- and KCl- loading in the groundwater from weathering of bicarbonate and sylvite minerals. Sulfate (SO42-) dominated cluster III mineralogy resulting from weathering of anhydrite. The three clusters in the Maiganga watershed indicated anhydrite, gypsum, and halite undersaturation. These results suggest that combined anthropogenic and natural processes in the study area are linked with saturation indexes that regulate the modification of groundwater quality. Springer Science and Business Media B.V. 2023 Article PeerReviewed Mohammed, Adamu Usman and Aris, Ahmad Zaharin and Ramli, Mohammad Firuz and Mohd Isa, Noorain and Arabi, Abdullahi Suleiman and Jabbo, Josiah Nuhu (2023) Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed. Environmental Geochemistry and Health, 45 (6). pp. 3891-3906. ISSN 0269-4042; ESSN: 1573-2983 https://link.springer.com/article/10.1007/s10653-022-01468-6?error=cookies_not_supported&code=26f6ba50-a715-4a99-af5e-c683c9e1192c 10.1007/s10653-022-01468-6 |
| spellingShingle | Mohammed, Adamu Usman Aris, Ahmad Zaharin Ramli, Mohammad Firuz Mohd Isa, Noorain Arabi, Abdullahi Suleiman Jabbo, Josiah Nuhu Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed |
| title | Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed |
| title_full | Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed |
| title_fullStr | Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed |
| title_full_unstemmed | Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed |
| title_short | Groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed |
| title_sort | groundwater pollutants characterization by geochemometric technique and geochemical modeling in tropical savanna watershed |
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