Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels

Waste peels are considered an environmental burden and typically disposed in landfills. The aim of this study was to investigate the effects of various solvents on the luminescence properties of carbon quantum dots (CQDs). Watermelon peels were recycled and reuse as precursors for the synthesis of b...

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Main Authors: Zaini, Muhammad Safwan, Liew, Josephine Ying Chyi, Paiman, Suriati, Tee, Tan Sin, Kamarudin, Mazliana Ahmad
Format: Article
Published: Springer New York 2023
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author Zaini, Muhammad Safwan
Liew, Josephine Ying Chyi
Paiman, Suriati
Tee, Tan Sin
Kamarudin, Mazliana Ahmad
author_facet Zaini, Muhammad Safwan
Liew, Josephine Ying Chyi
Paiman, Suriati
Tee, Tan Sin
Kamarudin, Mazliana Ahmad
author_sort Zaini, Muhammad Safwan
collection UPM
description Waste peels are considered an environmental burden and typically disposed in landfills. The aim of this study was to investigate the effects of various solvents on the luminescence properties of carbon quantum dots (CQDs). Watermelon peels were recycled and reuse as precursors for the synthesis of biomass CQDs via a green carbonization method. The colloidal stability, surface charge, and particle size were characterized using zeta potential and dynamic light scattering (DLS). DLS revealed that the size of the CQDs was approximately 5.80 ± 0.4 nm to 9.74 ± 0.8 nm. The high-resolution transmission electron microscopy (HRTEM) results demonstrated a correlation with the DLS results. The optical properties were characterized by photoluminescence (PL) and UV-Visible (UV-Vis) spectroscopy. PL measurements at different excitation wavelengths revealed that the CQDs emissions were influenced by the polarity of the solvents. Meanwhile, the Fourier transform infra-red (FTIR) results showed the presence of oxygen-containing groups on the surface of the CQDs. These results deepen our understanding of the solvent-dependent behavior and colloidal stability of the CQDs
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spelling upm.eprints-1086522024-10-03T04:32:33Z http://psasir.upm.edu.my/id/eprint/108652/ Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels Zaini, Muhammad Safwan Liew, Josephine Ying Chyi Paiman, Suriati Tee, Tan Sin Kamarudin, Mazliana Ahmad Waste peels are considered an environmental burden and typically disposed in landfills. The aim of this study was to investigate the effects of various solvents on the luminescence properties of carbon quantum dots (CQDs). Watermelon peels were recycled and reuse as precursors for the synthesis of biomass CQDs via a green carbonization method. The colloidal stability, surface charge, and particle size were characterized using zeta potential and dynamic light scattering (DLS). DLS revealed that the size of the CQDs was approximately 5.80 ± 0.4 nm to 9.74 ± 0.8 nm. The high-resolution transmission electron microscopy (HRTEM) results demonstrated a correlation with the DLS results. The optical properties were characterized by photoluminescence (PL) and UV-Visible (UV-Vis) spectroscopy. PL measurements at different excitation wavelengths revealed that the CQDs emissions were influenced by the polarity of the solvents. Meanwhile, the Fourier transform infra-red (FTIR) results showed the presence of oxygen-containing groups on the surface of the CQDs. These results deepen our understanding of the solvent-dependent behavior and colloidal stability of the CQDs Springer New York 2023-12-01 Article PeerReviewed Zaini, Muhammad Safwan and Liew, Josephine Ying Chyi and Paiman, Suriati and Tee, Tan Sin and Kamarudin, Mazliana Ahmad (2023) Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels. Journal of Fluorescence. pp. 1-12. ISSN 1053-0509; eISSN: 1573-4994 https://link.springer.com/article/10.1007/s10895-023-03528-1 10.1007/s10895-023-03528-1
spellingShingle Zaini, Muhammad Safwan
Liew, Josephine Ying Chyi
Paiman, Suriati
Tee, Tan Sin
Kamarudin, Mazliana Ahmad
Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels
title Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels
title_full Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels
title_fullStr Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels
title_full_unstemmed Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels
title_short Solvent-dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels
title_sort solvent dependent photoluminescence emission and colloidal stability of carbon quantum dots from watermelon peels
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AT paimansuriati solventdependentphotoluminescenceemissionandcolloidalstabilityofcarbonquantumdotsfromwatermelonpeels
AT teetansin solventdependentphotoluminescenceemissionandcolloidalstabilityofcarbonquantumdotsfromwatermelonpeels
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