Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle

Eu3+ incorporated zinc-borosilicate glass was synthesized using melt-quenching method. XRD and FTIR verified the amorphous nature of the samples. The absorption spectra indicate the Eu3+ ions in the UV-visible region at ∼394 nm. The direct and indirect band gap decrease from 5.152 eV to 5.082 eV and...

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Main Authors: Cheong, Wei Mun, Mohd Zaid, Mohd Hafiz, Matori, Khamirul Amin, Fen, Yap Wing, Tee, Tan Sin, Loh, Zhi Wei, Hilmi Mayzan, Mohd Zul
Format: Article
Language:English
Published: Taylor & Francis 2023
Online Access:http://psasir.upm.edu.my/id/eprint/108731/1/108731.pdf
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author Cheong, Wei Mun
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Fen, Yap Wing
Tee, Tan Sin
Loh, Zhi Wei
Hilmi Mayzan, Mohd Zul
author_facet Cheong, Wei Mun
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Fen, Yap Wing
Tee, Tan Sin
Loh, Zhi Wei
Hilmi Mayzan, Mohd Zul
author_sort Cheong, Wei Mun
collection UPM
description Eu3+ incorporated zinc-borosilicate glass was synthesized using melt-quenching method. XRD and FTIR verified the amorphous nature of the samples. The absorption spectra indicate the Eu3+ ions in the UV-visible region at ∼394 nm. The direct and indirect band gap decrease from 5.152 eV to 5.082 eV and 4.133 eV to 3.837 eV, respectively. Meanwhile, the refractive index decrease from 2.145 to 2.202, while the Urbach energy ranges from 0.682 eV to 0.733 eV. All the samples have a good transmission percentage at 70–75. Under the excitation of 400 nm, the intensity of the PL spectra increased when the Eu3+ dopant increased. The optimum content for Eu3+ incorporated ZnO–B2O3–GB glass is 3 wt. among the other Eu3+ content (0, 1, and 2 wt.) in this work. The reddish-orange emission at 612 nm (5D0 → 7F2) indicates the most intense emission and the CIE chromaticity coordinates imply in the reddish-orange region.
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spelling upm.eprints-1087312024-10-11T08:52:34Z http://psasir.upm.edu.my/id/eprint/108731/ Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle Cheong, Wei Mun Mohd Zaid, Mohd Hafiz Matori, Khamirul Amin Fen, Yap Wing Tee, Tan Sin Loh, Zhi Wei Hilmi Mayzan, Mohd Zul Eu3+ incorporated zinc-borosilicate glass was synthesized using melt-quenching method. XRD and FTIR verified the amorphous nature of the samples. The absorption spectra indicate the Eu3+ ions in the UV-visible region at ∼394 nm. The direct and indirect band gap decrease from 5.152 eV to 5.082 eV and 4.133 eV to 3.837 eV, respectively. Meanwhile, the refractive index decrease from 2.145 to 2.202, while the Urbach energy ranges from 0.682 eV to 0.733 eV. All the samples have a good transmission percentage at 70–75. Under the excitation of 400 nm, the intensity of the PL spectra increased when the Eu3+ dopant increased. The optimum content for Eu3+ incorporated ZnO–B2O3–GB glass is 3 wt. among the other Eu3+ content (0, 1, and 2 wt.) in this work. The reddish-orange emission at 612 nm (5D0 → 7F2) indicates the most intense emission and the CIE chromaticity coordinates imply in the reddish-orange region. Taylor & Francis 2023-09-19 Article PeerReviewed text en cc_by_nc_4 http://psasir.upm.edu.my/id/eprint/108731/1/108731.pdf Cheong, Wei Mun and Mohd Zaid, Mohd Hafiz and Matori, Khamirul Amin and Fen, Yap Wing and Tee, Tan Sin and Loh, Zhi Wei and Hilmi Mayzan, Mohd Zul (2023) Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle. Journal of Taibah University for Science, 17 (1). art. no. 2260080. pp. 1-12. ISSN 1658-3655 https://www.tandfonline.com/doi/full/10.1080/16583655.2023.2260080 10.1080/16583655.2023.2260080
spellingShingle Cheong, Wei Mun
Mohd Zaid, Mohd Hafiz
Matori, Khamirul Amin
Fen, Yap Wing
Tee, Tan Sin
Loh, Zhi Wei
Hilmi Mayzan, Mohd Zul
Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle
title Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle
title_full Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle
title_fullStr Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle
title_full_unstemmed Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle
title_short Promising reddish-orange light as Eu3+ incorporated in zinc-borosilicate glass derived from the waste glass bottle
title_sort promising reddish orange light as eu3 incorporated in zinc borosilicate glass derived from the waste glass bottle
url http://psasir.upm.edu.my/id/eprint/108731/1/108731.pdf
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