Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film

Polymers are flexible materials that can be easily processed and are formed into a thin film by several methods such as spin-coating, dip-coating, film-casting, and printing. The spin coating method has been extensively utilized in fabricating solution-prepared organic/inorg...

Full description

Bibliographic Details
Main Authors: Zakaria, Nabila Anis, Mohd Azmi, Mohd Syahriman, Naning @ Zin, Fatin Hana, Capan, Rifat, Syed Mohamad, Syed Abdul Malik
Format: Article
Published: Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris 2023
_version_ 1825939682378121216
author Zakaria, Nabila Anis
Mohd Azmi, Mohd Syahriman
Naning @ Zin, Fatin Hana
Capan, Rifat
Syed Mohamad, Syed Abdul Malik
author_facet Zakaria, Nabila Anis
Mohd Azmi, Mohd Syahriman
Naning @ Zin, Fatin Hana
Capan, Rifat
Syed Mohamad, Syed Abdul Malik
author_sort Zakaria, Nabila Anis
collection UPM
description Polymers are flexible materials that can be easily processed and are formed into a thin film by several methods such as spin-coating, dip-coating, film-casting, and printing. The spin coating method has been extensively utilized in fabricating solution-prepared organic/inorganic electronic devices, this technique is positively efficient in generating thin film apart from being a flexible method to execute. In this study, poly(3-hexylthiophene) (P3HT) material is selected as polymer and cadmium sulphide (CdS) as nanoparticles to produce a hybrid nanocomposite thin film through the process spin-coating method. The P3HT and cadmium ion solution were used to fabricate a thin film onto a quartz glass substrate at a spin speed of 500 rpm for 10 seconds. This spin-coated thin film was heated at different temperatures such as 40°C, 80°C, 120°C, and 160°C for optical properties using a UV-Vis spectrophotometer. The UV-Vis absorption spectra of P3HT: CdS indicated absorption peaks in the UV region, which were ascribed to the band gap of the P3HT: CdS thin film. Our results showed that the optical properties of the P3HT: CdS be contingent on the annealing temperature. The film at room temperature yielded a band gap value of 1.98 eV, at 40°C it resulted in 1.99 eV. The band gap value was increased when annealed at 80°C with 2.02eV. Annealing temperatures were then raised to 120°C and 160°C, leading to band gap values of 3.11 eV and 2.80 eV respectively.
first_indexed 2024-09-25T03:41:10Z
format Article
id upm.eprints-108936
institution Universiti Putra Malaysia
last_indexed 2024-09-25T03:41:10Z
publishDate 2023
publisher Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris
record_format dspace
spelling upm.eprints-1089362024-05-11T15:07:14Z http://psasir.upm.edu.my/id/eprint/108936/ Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film Zakaria, Nabila Anis Mohd Azmi, Mohd Syahriman Naning @ Zin, Fatin Hana Capan, Rifat Syed Mohamad, Syed Abdul Malik Polymers are flexible materials that can be easily processed and are formed into a thin film by several methods such as spin-coating, dip-coating, film-casting, and printing. The spin coating method has been extensively utilized in fabricating solution-prepared organic/inorganic electronic devices, this technique is positively efficient in generating thin film apart from being a flexible method to execute. In this study, poly(3-hexylthiophene) (P3HT) material is selected as polymer and cadmium sulphide (CdS) as nanoparticles to produce a hybrid nanocomposite thin film through the process spin-coating method. The P3HT and cadmium ion solution were used to fabricate a thin film onto a quartz glass substrate at a spin speed of 500 rpm for 10 seconds. This spin-coated thin film was heated at different temperatures such as 40°C, 80°C, 120°C, and 160°C for optical properties using a UV-Vis spectrophotometer. The UV-Vis absorption spectra of P3HT: CdS indicated absorption peaks in the UV region, which were ascribed to the band gap of the P3HT: CdS thin film. Our results showed that the optical properties of the P3HT: CdS be contingent on the annealing temperature. The film at room temperature yielded a band gap value of 1.98 eV, at 40°C it resulted in 1.99 eV. The band gap value was increased when annealed at 80°C with 2.02eV. Annealing temperatures were then raised to 120°C and 160°C, leading to band gap values of 3.11 eV and 2.80 eV respectively. Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris 2023 Article PeerReviewed Zakaria, Nabila Anis and Mohd Azmi, Mohd Syahriman and Naning @ Zin, Fatin Hana and Capan, Rifat and Syed Mohamad, Syed Abdul Malik (2023) Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film. Journal of Science and Mathematics Letters, 11 (spec.). pp. 81-87. ISSN 2462-2052; ESSN: 2600-8718 https://ejournal.upsi.edu.my/index.php/JSML/article/view/8745 10.37134/jsml.vol11.sp.9.2023
spellingShingle Zakaria, Nabila Anis
Mohd Azmi, Mohd Syahriman
Naning @ Zin, Fatin Hana
Capan, Rifat
Syed Mohamad, Syed Abdul Malik
Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film
title Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film
title_full Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film
title_fullStr Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film
title_full_unstemmed Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film
title_short Thermal annealing impact on optical properties of spin-coated P3HT: CdS thin film
title_sort thermal annealing impact on optical properties of spin coated p3ht cds thin film
work_keys_str_mv AT zakarianabilaanis thermalannealingimpactonopticalpropertiesofspincoatedp3htcdsthinfilm
AT mohdazmimohdsyahriman thermalannealingimpactonopticalpropertiesofspincoatedp3htcdsthinfilm
AT naningzinfatinhana thermalannealingimpactonopticalpropertiesofspincoatedp3htcdsthinfilm
AT capanrifat thermalannealingimpactonopticalpropertiesofspincoatedp3htcdsthinfilm
AT syedmohamadsyedabdulmalik thermalannealingimpactonopticalpropertiesofspincoatedp3htcdsthinfilm