Recovery of Nickel from spent hydrogenation catalyst using Chelating resin
Spent catalyst samples from hydrogenation of palm and palm kernel oils were subjected to soxhlet extraction to remove oil residue, digestion with concentrated sulfuric acid and nickel extraction using chelating ion exchange resin. The results showed that the spent catalysts contained oil residue (42...
| المؤلفون الرئيسيون: | , , , |
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| التنسيق: | مقال |
| اللغة: | English |
| منشور في: |
Japan Oil Chemists’ Society
2002
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| الوصول للمادة أونلاين: | http://psasir.upm.edu.my/id/eprint/114048/1/114048.pdf |
| _version_ | 1825940428690554880 |
|---|---|
| author | Dzulkefly, K. Haron, M.J. Lim, Wen Huei Woon, Chin Chan |
| author_facet | Dzulkefly, K. Haron, M.J. Lim, Wen Huei Woon, Chin Chan |
| author_sort | Dzulkefly, K. |
| collection | UPM |
| description | Spent catalyst samples from hydrogenation of palm and palm kernel oils were subjected to soxhlet extraction to remove oil residue, digestion with concentrated sulfuric acid and nickel extraction using chelating ion exchange resin. The results showed that the spent catalysts contained oil residue (42.2-54.0%), nickel (11.32-15.63%), Mg (1.65-2.51%), Ca (3.84-5.68%). Other metals, Fe, K, Na, K, Al, Zn, Cu, Cr and Mn are minor components (<0.1%). The Amberlite IRC-718 resin has extracted more than 90% Ni in the spent catalysts (as nickel nitrate) with purity of higher than 90% with regards to the amount of Mg and Ca in the sample. The Amberlite resin showed the highest sorption capacity for Ni(II) (56.8 mg/g) at pH 5. |
| first_indexed | 2024-12-09T02:27:35Z |
| format | Article |
| id | upm.eprints-114048 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-12-09T02:27:35Z |
| publishDate | 2002 |
| publisher | Japan Oil Chemists’ Society |
| record_format | dspace |
| spelling | upm.eprints-1140482024-12-08T08:25:23Z http://psasir.upm.edu.my/id/eprint/114048/ Recovery of Nickel from spent hydrogenation catalyst using Chelating resin Dzulkefly, K. Haron, M.J. Lim, Wen Huei Woon, Chin Chan Spent catalyst samples from hydrogenation of palm and palm kernel oils were subjected to soxhlet extraction to remove oil residue, digestion with concentrated sulfuric acid and nickel extraction using chelating ion exchange resin. The results showed that the spent catalysts contained oil residue (42.2-54.0%), nickel (11.32-15.63%), Mg (1.65-2.51%), Ca (3.84-5.68%). Other metals, Fe, K, Na, K, Al, Zn, Cu, Cr and Mn are minor components (<0.1%). The Amberlite IRC-718 resin has extracted more than 90% Ni in the spent catalysts (as nickel nitrate) with purity of higher than 90% with regards to the amount of Mg and Ca in the sample. The Amberlite resin showed the highest sorption capacity for Ni(II) (56.8 mg/g) at pH 5. Japan Oil Chemists’ Society 2002 Article PeerReviewed text en http://psasir.upm.edu.my/id/eprint/114048/1/114048.pdf Dzulkefly, K. and Haron, M.J. and Lim, Wen Huei and Woon, Chin Chan (2002) Recovery of Nickel from spent hydrogenation catalyst using Chelating resin. Journal of Oleo Science, 51 (12). pp. 749-751. ISSN 1345-8957; eISSN: 1347-3352 https://www.jstage.jst.go.jp/article/jos/51/12/51_12_749/_article 10.5650/jos.51.749 |
| spellingShingle | Dzulkefly, K. Haron, M.J. Lim, Wen Huei Woon, Chin Chan Recovery of Nickel from spent hydrogenation catalyst using Chelating resin |
| title | Recovery of Nickel from spent hydrogenation catalyst using Chelating resin |
| title_full | Recovery of Nickel from spent hydrogenation catalyst using Chelating resin |
| title_fullStr | Recovery of Nickel from spent hydrogenation catalyst using Chelating resin |
| title_full_unstemmed | Recovery of Nickel from spent hydrogenation catalyst using Chelating resin |
| title_short | Recovery of Nickel from spent hydrogenation catalyst using Chelating resin |
| title_sort | recovery of nickel from spent hydrogenation catalyst using chelating resin |
| url | http://psasir.upm.edu.my/id/eprint/114048/1/114048.pdf |
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