Solid-State P NMR, Far-IR, and Structural Studies on Two-Coordinate (Tris(2,4,6-trimethoxyphenyl)phosphine)copper(I) Chloride and Bromide
The reactions of acetonitrile solutions of copper(I) chloride, CuCl, and copper(I) bromide, CuBr, with the sterically hindered, highly basic tertiary phosphine ligand tris(2,4,6-trimethoxyphenyl)phosphine [=P(2,4,6)3] have been shown to form 1:1 monomeric adducts, [P(2,4,6)3 cux],The two compounds a...
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American Chemical Society
1989
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