Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set
The synthesis and structural characterization of the condensation product formed by a template reaction of 2, 6-diacetylpyridine and 3, 6, 9-trithiaundecane-1, 11-diamine about silver(1) (as perchlorate) are described. Crystals are monoclinic, C2/c, a 27.114(10), b 7.546(5), c 22.137(10) Å, β 105.35...
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| Format: | Article |
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CSIRO Publishing
1989
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| _version_ | 1825940630948282368 |
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| author | Bin, Sidik Silong Kildea, John D. White, Allan H. |
| author_facet | Bin, Sidik Silong Kildea, John D. White, Allan H. |
| author_sort | Bin, Sidik Silong |
| collection | UPM |
| description | The synthesis and structural characterization of the condensation product formed by a template reaction of 2, 6-diacetylpyridine and 3, 6, 9-trithiaundecane-1, 11-diamine about silver(1) (as perchlorate) are described. Crystals are monoclinic, C2/c, a 27.114(10), b 7.546(5), c 22.137(10) Å, β 105.35(3)°, Z=8×[AgL]+(ClO4)- (L = C17H25N3S3). R was 0.057 for 2372 'observed' reflections. The six-coordinate silver(l) atom lies in a novel environment comprised of a mer-triaza moiety derived from 2, 6-diacetylpyridine [Ag-N, 2.422(8) (central), 2.538(8), 2.546(9) Å (distal)] and a fac-trithia moiety straddling its plane [Ag-S, 2.603(6) (central), 2-815(4), 2.881(3) Å (distal)]. The complex cation is a different conformational isomer to that found in the previously studied tetraphenylborate salt. In the latter, Ag-N are 2.422(9) (central), 2.613(9), 2.399(7) Å (distal), with Ag-S 2.670(3) (central), 2.655(3), 2.949(4) Å (distal). |
| first_indexed | 2025-03-07T13:04:43Z |
| format | Article |
| id | upm.eprints-115194 |
| institution | Universiti Putra Malaysia |
| last_indexed | 2025-03-07T13:04:43Z |
| publishDate | 1989 |
| publisher | CSIRO Publishing |
| record_format | dspace |
| spelling | upm.eprints-1151942025-02-26T02:19:13Z http://psasir.upm.edu.my/id/eprint/115194/ Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set Bin, Sidik Silong Kildea, John D. White, Allan H. The synthesis and structural characterization of the condensation product formed by a template reaction of 2, 6-diacetylpyridine and 3, 6, 9-trithiaundecane-1, 11-diamine about silver(1) (as perchlorate) are described. Crystals are monoclinic, C2/c, a 27.114(10), b 7.546(5), c 22.137(10) Å, β 105.35(3)°, Z=8×[AgL]+(ClO4)- (L = C17H25N3S3). R was 0.057 for 2372 'observed' reflections. The six-coordinate silver(l) atom lies in a novel environment comprised of a mer-triaza moiety derived from 2, 6-diacetylpyridine [Ag-N, 2.422(8) (central), 2.538(8), 2.546(9) Å (distal)] and a fac-trithia moiety straddling its plane [Ag-S, 2.603(6) (central), 2-815(4), 2.881(3) Å (distal)]. The complex cation is a different conformational isomer to that found in the previously studied tetraphenylborate salt. In the latter, Ag-N are 2.422(9) (central), 2.613(9), 2.399(7) Å (distal), with Ag-S 2.670(3) (central), 2.655(3), 2.949(4) Å (distal). CSIRO Publishing 1989 Article PeerReviewed Bin, Sidik Silong and Kildea, John D. and White, Allan H. (1989) Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set. Australian Journal of Chemistry, 42 (8). pp. 1387-1391. ISSN 0004-9425; eISSN: 1445-0038 https://www.publish.csiro.au/ch/CH9891387 10.1071/CH9891387 |
| spellingShingle | Bin, Sidik Silong Kildea, John D. White, Allan H. Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set |
| title | Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set |
| title_full | Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set |
| title_fullStr | Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set |
| title_full_unstemmed | Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set |
| title_short | Novel conformational isomerism in a six-coordinate silver(i) complex of a sexadentate macrocycle with an 'N3S3' donor set |
| title_sort | novel conformational isomerism in a six coordinate silver i complex of a sexadentate macrocycle with an n3s3 donor set |
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