Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol

Polypyrrole-poly ethylene glycol (Ppy -PEG) composites were synthesized by electrochemical method using p-toluene sulfonate as a dopant in aqueous medium. Polyethylene glycol was used as the insulating material in order to impart enhanced mechanical properties to the conducting polymer composite fil...

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Main Authors: Lim, Mei Yee, Kassim, Anuar, Mahmud, Habibun Nabi Muhammad Ekramul, Mohd Sharif, Atan, Haron, Md Jelas
Format: Article
Language:English
Published: Malaysian Analytical Sciences Society 2007
Online Access:http://psasir.upm.edu.my/id/eprint/11567/1/Preparation%20and%20characterization%20of%20conducting%20polymer%20composite%20films.pdf
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author Lim, Mei Yee
Kassim, Anuar
Mahmud, Habibun Nabi Muhammad Ekramul
Mohd Sharif, Atan
Haron, Md Jelas
author_facet Lim, Mei Yee
Kassim, Anuar
Mahmud, Habibun Nabi Muhammad Ekramul
Mohd Sharif, Atan
Haron, Md Jelas
author_sort Lim, Mei Yee
collection UPM
description Polypyrrole-poly ethylene glycol (Ppy -PEG) composites were synthesized by electrochemical method using p-toluene sulfonate as a dopant in aqueous medium. Polyethylene glycol was used as the insulating material in order to impart enhanced mechanical properties to the conducting polymer composite films. The composite films were synthesized with various percentages of PEG, and were characterized by FT-IR spectroscopy, conductivity measurement, optical microscopy (OP), X-ray diffraction (XRD) and dynamic mechanical analysis (DMA). The FT-IR result reveals the successful incorporation of PEG into the polypyrrole structure forming Ppy-PEG composite films. The conductivity of the composite films prepared from using 0.20% PEG was found to exhibit the highest conductivity (61.28 Scm-1) among all the prepared composite films measured at room temperature. The optical microscopy of Ppy -PEG shows the globular surface morphology. The XRD analysis of Ppy -PEG composite films shows that the composite films are amorphous. The enhanced mechanical properties of the Ppy -PEG composite films are the direct consequence of incorporating PEG in the polypyrrole structure.
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spelling upm.eprints-115672017-01-03T11:16:43Z http://psasir.upm.edu.my/id/eprint/11567/ Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol Lim, Mei Yee Kassim, Anuar Mahmud, Habibun Nabi Muhammad Ekramul Mohd Sharif, Atan Haron, Md Jelas Polypyrrole-poly ethylene glycol (Ppy -PEG) composites were synthesized by electrochemical method using p-toluene sulfonate as a dopant in aqueous medium. Polyethylene glycol was used as the insulating material in order to impart enhanced mechanical properties to the conducting polymer composite films. The composite films were synthesized with various percentages of PEG, and were characterized by FT-IR spectroscopy, conductivity measurement, optical microscopy (OP), X-ray diffraction (XRD) and dynamic mechanical analysis (DMA). The FT-IR result reveals the successful incorporation of PEG into the polypyrrole structure forming Ppy-PEG composite films. The conductivity of the composite films prepared from using 0.20% PEG was found to exhibit the highest conductivity (61.28 Scm-1) among all the prepared composite films measured at room temperature. The optical microscopy of Ppy -PEG shows the globular surface morphology. The XRD analysis of Ppy -PEG composite films shows that the composite films are amorphous. The enhanced mechanical properties of the Ppy -PEG composite films are the direct consequence of incorporating PEG in the polypyrrole structure. Malaysian Analytical Sciences Society 2007 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/11567/1/Preparation%20and%20characterization%20of%20conducting%20polymer%20composite%20films.pdf Lim, Mei Yee and Kassim, Anuar and Mahmud, Habibun Nabi Muhammad Ekramul and Mohd Sharif, Atan and Haron, Md Jelas (2007) Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol. The Malaysian Journal of Analytical Sciences, 11 (1). pp. 133-138. ISSN 1394-2506 http://www.ukm.my/mjas/new_mjas/
spellingShingle Lim, Mei Yee
Kassim, Anuar
Mahmud, Habibun Nabi Muhammad Ekramul
Mohd Sharif, Atan
Haron, Md Jelas
Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol
title Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol
title_full Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol
title_fullStr Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol
title_full_unstemmed Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol
title_short Preparation and characterization of conducting polymer composite films: polypyrrole and polyethylene glycol
title_sort preparation and characterization of conducting polymer composite films polypyrrole and polyethylene glycol
url http://psasir.upm.edu.my/id/eprint/11567/1/Preparation%20and%20characterization%20of%20conducting%20polymer%20composite%20films.pdf
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AT mahmudhabibunnabimuhammadekramul preparationandcharacterizationofconductingpolymercompositefilmspolypyrroleandpolyethyleneglycol
AT mohdsharifatan preparationandcharacterizationofconductingpolymercompositefilmspolypyrroleandpolyethyleneglycol
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