The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties

This study is mainly focused on the synthesis of compounds of quaternary ammonium compounds. Iodoacetone has been produced through a simple method by reacting crystalline iodine and acetone in aqueous medium without adding any acid or base catalyst. Iodoacetone has been shown to react with variou...

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Main Author: Wong, Chan Hoong
Format: Thesis
Language:English
English
Published: 2002
Subjects:
Online Access:http://psasir.upm.edu.my/id/eprint/11575/1/FSAS_2002_40_.pdf
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author Wong, Chan Hoong
author_facet Wong, Chan Hoong
author_sort Wong, Chan Hoong
collection UPM
description This study is mainly focused on the synthesis of compounds of quaternary ammonium compounds. Iodoacetone has been produced through a simple method by reacting crystalline iodine and acetone in aqueous medium without adding any acid or base catalyst. Iodoacetone has been shown to react with various types of amines to produce tertiary and quarternary ammonium salts. For example, the reaction between pyridine and iodoacetone produced N-acetonyl pyridinium iodide. lodoacetone reacts with triethylamine to produce N-acetonyl triethylammonium iodide and it reacts with triethanolamine to produce N-acetonyl triethanolamonium iodide. The reaction has been shown to be a general one. In many cases, single crystal x-ray analysis was used to solve the structure of the salts. We have found that the crystal system for Nacetonyltrimethylammonium iodide, N-acetonyltriethylammonium iodide, Nacetonylpyridinium iodide, 1-( l -ethyl-2-oxo-propyl)-pyridinium iodide and 2-hydroxy-
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spelling upm.eprints-115752024-06-24T01:22:18Z http://psasir.upm.edu.my/id/eprint/11575/ The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties Wong, Chan Hoong This study is mainly focused on the synthesis of compounds of quaternary ammonium compounds. Iodoacetone has been produced through a simple method by reacting crystalline iodine and acetone in aqueous medium without adding any acid or base catalyst. Iodoacetone has been shown to react with various types of amines to produce tertiary and quarternary ammonium salts. For example, the reaction between pyridine and iodoacetone produced N-acetonyl pyridinium iodide. lodoacetone reacts with triethylamine to produce N-acetonyl triethylammonium iodide and it reacts with triethanolamine to produce N-acetonyl triethanolamonium iodide. The reaction has been shown to be a general one. In many cases, single crystal x-ray analysis was used to solve the structure of the salts. We have found that the crystal system for Nacetonyltrimethylammonium iodide, N-acetonyltriethylammonium iodide, Nacetonylpyridinium iodide, 1-( l -ethyl-2-oxo-propyl)-pyridinium iodide and 2-hydroxy- 2002-07 Thesis NonPeerReviewed text en http://psasir.upm.edu.my/id/eprint/11575/1/FSAS_2002_40_.pdf Wong, Chan Hoong (2002) The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties. Masters thesis, Universiti Putra Malaysia. Quaternary ammonium salts - Synthesis Carbonyl compounds English
spellingShingle Quaternary ammonium salts - Synthesis
Carbonyl compounds
Wong, Chan Hoong
The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties
title The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties
title_full The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties
title_fullStr The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties
title_full_unstemmed The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties
title_short The Synthesis Of Quaternary Ammonium Salts With Carbonyl Functionality And Studies Of Their Physical Properties
title_sort synthesis of quaternary ammonium salts with carbonyl functionality and studies of their physical properties
topic Quaternary ammonium salts - Synthesis
Carbonyl compounds
url http://psasir.upm.edu.my/id/eprint/11575/1/FSAS_2002_40_.pdf
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