Effects of solution concentration on the properties of Cu4SnS4 thin films.

Copper tin sulfide thin films were electrodeposited on the indium tin oxide substrate from an aqueous solution containing CuSO4, SnCl2 and Na2S2O3 at pH 1. Deposition at various concentrations was attempted in order to study the effect of electrolytes concentration on the film properties. The th...

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Main Authors: Kassim, Anuar, Ho, Soon Min, Tan, Wee Tee, Atan, Mohd Sharif, Kuang, Dzulkefly, Haron, Md. Jelas, Saravanan, Nagalingam
Format: Article
Language:English
English
Published: Kaunas University of Technology 2008
Online Access:http://psasir.upm.edu.my/id/eprint/14412/1/Effects%20of%20solution%20concentration%20on%20the%20properties%20of%20Cu4SnS4%20thin%20films.pdf
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author Kassim, Anuar
Ho, Soon Min
Tan, Wee Tee
Atan, Mohd Sharif
Kuang, Dzulkefly
Haron, Md. Jelas
Saravanan, Nagalingam
author_facet Kassim, Anuar
Ho, Soon Min
Tan, Wee Tee
Atan, Mohd Sharif
Kuang, Dzulkefly
Haron, Md. Jelas
Saravanan, Nagalingam
author_sort Kassim, Anuar
collection UPM
description Copper tin sulfide thin films were electrodeposited on the indium tin oxide substrate from an aqueous solution containing CuSO4, SnCl2 and Na2S2O3 at pH 1. Deposition at various concentrations was attempted in order to study the effect of electrolytes concentration on the film properties. The thin films were characterized using X-ray diffraction and atomic force microscopy. The absorption properties, band gap energy and transition type was determined using UV-Vis Spectrophotometer. The thin films produced were polycrystalline in nature. The XRD data showed that the most intense peak is at 2θ = 30.2° which belongs to (221) plane of Cu4SnS4. The AFM images indicated that the lower concentration leads to smaller crystal size, as well as higher optical absorption values. The optimum bath composition was found to be 0.01 M for CuSO4, Na2S2O3 and SnCl2. The band gap value was found to be 1.7 eV with indirect transition.
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spelling upm.eprints-144122015-09-28T04:14:38Z http://psasir.upm.edu.my/id/eprint/14412/ Effects of solution concentration on the properties of Cu4SnS4 thin films. Kassim, Anuar Ho, Soon Min Tan, Wee Tee Atan, Mohd Sharif Kuang, Dzulkefly Haron, Md. Jelas Saravanan, Nagalingam Copper tin sulfide thin films were electrodeposited on the indium tin oxide substrate from an aqueous solution containing CuSO4, SnCl2 and Na2S2O3 at pH 1. Deposition at various concentrations was attempted in order to study the effect of electrolytes concentration on the film properties. The thin films were characterized using X-ray diffraction and atomic force microscopy. The absorption properties, band gap energy and transition type was determined using UV-Vis Spectrophotometer. The thin films produced were polycrystalline in nature. The XRD data showed that the most intense peak is at 2θ = 30.2° which belongs to (221) plane of Cu4SnS4. The AFM images indicated that the lower concentration leads to smaller crystal size, as well as higher optical absorption values. The optimum bath composition was found to be 0.01 M for CuSO4, Na2S2O3 and SnCl2. The band gap value was found to be 1.7 eV with indirect transition. Kaunas University of Technology 2008 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/14412/1/Effects%20of%20solution%20concentration%20on%20the%20properties%20of%20Cu4SnS4%20thin%20films.pdf Kassim, Anuar and Ho, Soon Min and Tan, Wee Tee and Atan, Mohd Sharif and Kuang, Dzulkefly and Haron, Md. Jelas and Saravanan, Nagalingam (2008) Effects of solution concentration on the properties of Cu4SnS4 thin films. Materials Science, 14 (2). pp. 101-105. ISSN 1392–1320; E-SSN: 2029–7289 http://www.matsc.ktu.lt/index.php/MatSc English
spellingShingle Kassim, Anuar
Ho, Soon Min
Tan, Wee Tee
Atan, Mohd Sharif
Kuang, Dzulkefly
Haron, Md. Jelas
Saravanan, Nagalingam
Effects of solution concentration on the properties of Cu4SnS4 thin films.
title Effects of solution concentration on the properties of Cu4SnS4 thin films.
title_full Effects of solution concentration on the properties of Cu4SnS4 thin films.
title_fullStr Effects of solution concentration on the properties of Cu4SnS4 thin films.
title_full_unstemmed Effects of solution concentration on the properties of Cu4SnS4 thin films.
title_short Effects of solution concentration on the properties of Cu4SnS4 thin films.
title_sort effects of solution concentration on the properties of cu4sns4 thin films
url http://psasir.upm.edu.my/id/eprint/14412/1/Effects%20of%20solution%20concentration%20on%20the%20properties%20of%20Cu4SnS4%20thin%20films.pdf
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