Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide.
Poly(lactic acid)/layered double hydroxide (PLA/LDH) nanocomposites were prepared from PLA and stearate-Mg3Al LDH via a solution casting method. The anionic clay Mg3Al LDH was prepared first by coprecipitation method from nitrate salts solution at pH 9 and then modified by stearate anions through an...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
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Wiley
2010
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| Online Access: | http://psasir.upm.edu.my/id/eprint/14782/1/Flexibility%20improvement%20of%20poly.pdf |
| _version_ | 1796968714307895296 |
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| author | Mahboobeh, Eili Wan Yunus, Wan Md Zin Hussein, Zobir Ahmad, Mansor Ibrahim, Nor Azowa |
| author_facet | Mahboobeh, Eili Wan Yunus, Wan Md Zin Hussein, Zobir Ahmad, Mansor Ibrahim, Nor Azowa |
| author_sort | Mahboobeh, Eili |
| collection | UPM |
| description | Poly(lactic acid)/layered double hydroxide (PLA/LDH) nanocomposites were prepared from PLA and stearate-Mg3Al LDH via a solution casting method. The anionic clay Mg3Al LDH was prepared first by coprecipitation method from nitrate salts solution at pH 9 and then modified by stearate anions through an ion exchange reaction. This modification increased the basal spacing of the synthetic clay from 8.72 to 31.68 Å. The presence of stearate ions in the synthesized Mg3Al LDH was shown by the stearate-Mg3Al LDH infrared spectrum. When the stearate-Mg3Al LDH at the low concentration was dispersed in the PLA matrix, its layers were largely delaminated. The presence of 1.0 wt % of the stearate-Mg3Al LDH in the PLA improved drastically (of around 650%) of its elongation at break but retained its tensile strength and modulus as compared to those of the pure PLA. |
| first_indexed | 2024-03-06T07:32:24Z |
| format | Article |
| id | upm.eprints-14782 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T07:32:24Z |
| publishDate | 2010 |
| publisher | Wiley |
| record_format | dspace |
| spelling | upm.eprints-147822015-10-21T03:00:59Z http://psasir.upm.edu.my/id/eprint/14782/ Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. Mahboobeh, Eili Wan Yunus, Wan Md Zin Hussein, Zobir Ahmad, Mansor Ibrahim, Nor Azowa Poly(lactic acid)/layered double hydroxide (PLA/LDH) nanocomposites were prepared from PLA and stearate-Mg3Al LDH via a solution casting method. The anionic clay Mg3Al LDH was prepared first by coprecipitation method from nitrate salts solution at pH 9 and then modified by stearate anions through an ion exchange reaction. This modification increased the basal spacing of the synthetic clay from 8.72 to 31.68 Å. The presence of stearate ions in the synthesized Mg3Al LDH was shown by the stearate-Mg3Al LDH infrared spectrum. When the stearate-Mg3Al LDH at the low concentration was dispersed in the PLA matrix, its layers were largely delaminated. The presence of 1.0 wt % of the stearate-Mg3Al LDH in the PLA improved drastically (of around 650%) of its elongation at break but retained its tensile strength and modulus as compared to those of the pure PLA. Wiley 2010 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/14782/1/Flexibility%20improvement%20of%20poly.pdf Mahboobeh, Eili and Wan Yunus, Wan Md Zin and Hussein, Zobir and Ahmad, Mansor and Ibrahim, Nor Azowa (2010) Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. Journal of Applied Polymer Science, 118 (2). pp. 1077-1083. ISSN 0021-8995; ESSN: 1097-4628 10.1002/app.32461 English |
| spellingShingle | Mahboobeh, Eili Wan Yunus, Wan Md Zin Hussein, Zobir Ahmad, Mansor Ibrahim, Nor Azowa Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. |
| title | Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. |
| title_full | Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. |
| title_fullStr | Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. |
| title_full_unstemmed | Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. |
| title_short | Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. |
| title_sort | flexibility improvement of poly lactic acid by stearate modified layered double hydroxide |
| url | http://psasir.upm.edu.my/id/eprint/14782/1/Flexibility%20improvement%20of%20poly.pdf |
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