Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol
The kinetics of wax ester synthesis from oleic acid and oleyl alcohol using immobilized lipase from Candida antartica as catalyst was studied with different types of impeller (Rushton turbine and AL-hydrofoil) to create different mixing conditions in 2l stirred tank reactor. The effects of catalyst...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Japan Oil Chemists' Society
2010
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| Online Access: | http://psasir.upm.edu.my/id/eprint/15389/1/Kinetics%20of%20enzymatic%20synthesis%20of%20liquid%20wax%20ester%20from%20oleic%20acid%20and%20oleyl%20alcohol.pdf |
| _version_ | 1796968838754992128 |
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| author | Mat Radzi, Salina Mohamad, Rosfarizan Basri, Mahiran Salleh, Abu Bakar Ariff, Arbakariya Abdul Rahman, Mohd Basyaruddin Raja Abdul Rahman, Raja Noor Zaliha |
| author_facet | Mat Radzi, Salina Mohamad, Rosfarizan Basri, Mahiran Salleh, Abu Bakar Ariff, Arbakariya Abdul Rahman, Mohd Basyaruddin Raja Abdul Rahman, Raja Noor Zaliha |
| author_sort | Mat Radzi, Salina |
| collection | UPM |
| description | The kinetics of wax ester synthesis from oleic acid and oleyl alcohol using immobilized lipase from Candida antartica as catalyst was studied with different types of impeller (Rushton turbine and AL-hydrofoil) to create different mixing conditions in 2l stirred tank reactor. The effects of catalyst concentration, reaction temperature, and impeller tip speed on the synthesis were also evaluated. Rushton turbine impeller exhibited highest conversion rate at lower impeller tip speed as compared to AL-hydrofoil impeller. A second-order reversible kinetic model from single progress curve for the prediction of fractional conversion at given reaction time was proposed and the corresponding kinetic parameter values were calculated by non-linear regression method. The results from the simulation using the proposed model showed satisfactory agreement with the experimental data. Activation energy shows a value of 21.77 Kcal/mol. The thermodynamic parameters of the process, enthalpy and entropy, were 21.15 Kcal/mol and 52.07 cal/mol.K, respectively. |
| first_indexed | 2024-03-06T07:34:12Z |
| format | Article |
| id | upm.eprints-15389 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T07:34:12Z |
| publishDate | 2010 |
| publisher | Japan Oil Chemists' Society |
| record_format | dspace |
| spelling | upm.eprints-153892015-10-21T03:57:28Z http://psasir.upm.edu.my/id/eprint/15389/ Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol Mat Radzi, Salina Mohamad, Rosfarizan Basri, Mahiran Salleh, Abu Bakar Ariff, Arbakariya Abdul Rahman, Mohd Basyaruddin Raja Abdul Rahman, Raja Noor Zaliha The kinetics of wax ester synthesis from oleic acid and oleyl alcohol using immobilized lipase from Candida antartica as catalyst was studied with different types of impeller (Rushton turbine and AL-hydrofoil) to create different mixing conditions in 2l stirred tank reactor. The effects of catalyst concentration, reaction temperature, and impeller tip speed on the synthesis were also evaluated. Rushton turbine impeller exhibited highest conversion rate at lower impeller tip speed as compared to AL-hydrofoil impeller. A second-order reversible kinetic model from single progress curve for the prediction of fractional conversion at given reaction time was proposed and the corresponding kinetic parameter values were calculated by non-linear regression method. The results from the simulation using the proposed model showed satisfactory agreement with the experimental data. Activation energy shows a value of 21.77 Kcal/mol. The thermodynamic parameters of the process, enthalpy and entropy, were 21.15 Kcal/mol and 52.07 cal/mol.K, respectively. Japan Oil Chemists' Society 2010 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/15389/1/Kinetics%20of%20enzymatic%20synthesis%20of%20liquid%20wax%20ester%20from%20oleic%20acid%20and%20oleyl%20alcohol.pdf Mat Radzi, Salina and Mohamad, Rosfarizan and Basri, Mahiran and Salleh, Abu Bakar and Ariff, Arbakariya and Abdul Rahman, Mohd Basyaruddin and Raja Abdul Rahman, Raja Noor Zaliha (2010) Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol. Journal of Oleo Science, 59 (3). pp. 127-134. ISSN 1345-8957; ESSN: 1347-3352 https://www.jstage.jst.go.jp/article/jos/59/3/59_3_127/_article 10.5650/jos.59.127 |
| spellingShingle | Mat Radzi, Salina Mohamad, Rosfarizan Basri, Mahiran Salleh, Abu Bakar Ariff, Arbakariya Abdul Rahman, Mohd Basyaruddin Raja Abdul Rahman, Raja Noor Zaliha Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol |
| title | Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol |
| title_full | Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol |
| title_fullStr | Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol |
| title_full_unstemmed | Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol |
| title_short | Kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol |
| title_sort | kinetics of enzymatic synthesis of liquid wax ester from oleic acid and oleyl alcohol |
| url | http://psasir.upm.edu.my/id/eprint/15389/1/Kinetics%20of%20enzymatic%20synthesis%20of%20liquid%20wax%20ester%20from%20oleic%20acid%20and%20oleyl%20alcohol.pdf |
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