Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.

Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial...

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Main Authors: Cheong, Kok Whye, Tan, Chin Ping, Hamed, Mirhosseini, Chin, Sung Tong, Yaakob, Che Man, Nazimah, Sheikh Abdul Hamid, Osman, Azizah, Basri, Mahiran
Format: Article
Language:English
English
Published: Elsevier 2011
Online Access:http://psasir.upm.edu.my/id/eprint/15971/1/Optimization%20of%20equilibrium%20headspace%20analysis%20of%20volatile%20flavor%20compounds%20of%20Malaysian%20soursop.pdf
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author Cheong, Kok Whye
Tan, Chin Ping
Hamed, Mirhosseini
Chin, Sung Tong
Yaakob, Che Man
Nazimah, Sheikh Abdul Hamid
Osman, Azizah
Basri, Mahiran
author_facet Cheong, Kok Whye
Tan, Chin Ping
Hamed, Mirhosseini
Chin, Sung Tong
Yaakob, Che Man
Nazimah, Sheikh Abdul Hamid
Osman, Azizah
Basri, Mahiran
author_sort Cheong, Kok Whye
collection UPM
description Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial design (25-1) was used to determine the effect of SPME variables, namely, SPME fibers, adsorption temperature, extraction time, amount of salt, sample amount and sample concentration on the extraction efficiency of volatile flavor compounds. A total of 37 volatile compounds were identified, comprising 21 esters, 6 alcohols, 3 terpenes, 2 acids, 2 ketones, 2 aldehydes and an aromatic with different hydrophobicities (log P) ranging between −0.14 and 4.83. Extraction using 10 g of diluted (5% w/w) blended soursop pulp with CAR/PDMS fiber at 25 °C for 30 min and 30% (w/w) of NaCl under stirring mode resulted in the highest extraction efficiency of volatile flavor compounds. The principal component analysis score discriminated the influence of SPME variables on the equilibrium headspace concentration of target volatile compounds.
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spelling upm.eprints-159712015-10-16T07:13:07Z http://psasir.upm.edu.my/id/eprint/15971/ Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. Cheong, Kok Whye Tan, Chin Ping Hamed, Mirhosseini Chin, Sung Tong Yaakob, Che Man Nazimah, Sheikh Abdul Hamid Osman, Azizah Basri, Mahiran Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial design (25-1) was used to determine the effect of SPME variables, namely, SPME fibers, adsorption temperature, extraction time, amount of salt, sample amount and sample concentration on the extraction efficiency of volatile flavor compounds. A total of 37 volatile compounds were identified, comprising 21 esters, 6 alcohols, 3 terpenes, 2 acids, 2 ketones, 2 aldehydes and an aromatic with different hydrophobicities (log P) ranging between −0.14 and 4.83. Extraction using 10 g of diluted (5% w/w) blended soursop pulp with CAR/PDMS fiber at 25 °C for 30 min and 30% (w/w) of NaCl under stirring mode resulted in the highest extraction efficiency of volatile flavor compounds. The principal component analysis score discriminated the influence of SPME variables on the equilibrium headspace concentration of target volatile compounds. Elsevier 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/15971/1/Optimization%20of%20equilibrium%20headspace%20analysis%20of%20volatile%20flavor%20compounds%20of%20Malaysian%20soursop.pdf Cheong, Kok Whye and Tan, Chin Ping and Hamed, Mirhosseini and Chin, Sung Tong and Yaakob, Che Man and Nazimah, Sheikh Abdul Hamid and Osman, Azizah and Basri, Mahiran (2011) Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. Food Chemistry, 125 (4). pp. 1481-1489. ISSN 0308-8146 http://dx.doi.org/10.1016/j.foodchem.2010.10.067 English
spellingShingle Cheong, Kok Whye
Tan, Chin Ping
Hamed, Mirhosseini
Chin, Sung Tong
Yaakob, Che Man
Nazimah, Sheikh Abdul Hamid
Osman, Azizah
Basri, Mahiran
Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.
title Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.
title_full Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.
title_fullStr Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.
title_full_unstemmed Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.
title_short Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.
title_sort optimization of equilibrium headspace analysis of volatile flavor compounds of malaysian soursop annona muricata comprehensive two dimensional gas chromatography time of flight mass spectrometry
url http://psasir.upm.edu.my/id/eprint/15971/1/Optimization%20of%20equilibrium%20headspace%20analysis%20of%20volatile%20flavor%20compounds%20of%20Malaysian%20soursop.pdf
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