Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.
Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial...
| Main Authors: | , , , , , , , |
|---|---|
| 格式: | 文件 |
| 语言: | English English |
| 出版: |
Elsevier
2011
|
| 在线阅读: | http://psasir.upm.edu.my/id/eprint/15971/1/Optimization%20of%20equilibrium%20headspace%20analysis%20of%20volatile%20flavor%20compounds%20of%20Malaysian%20soursop.pdf |
| _version_ | 1825945725099311104 |
|---|---|
| author | Cheong, Kok Whye Tan, Chin Ping Hamed, Mirhosseini Chin, Sung Tong Yaakob, Che Man Nazimah, Sheikh Abdul Hamid Osman, Azizah Basri, Mahiran |
| author_facet | Cheong, Kok Whye Tan, Chin Ping Hamed, Mirhosseini Chin, Sung Tong Yaakob, Che Man Nazimah, Sheikh Abdul Hamid Osman, Azizah Basri, Mahiran |
| author_sort | Cheong, Kok Whye |
| collection | UPM |
| description | Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial design (25-1) was used to determine the effect of SPME variables, namely, SPME fibers, adsorption temperature, extraction time, amount of salt, sample amount and sample concentration on the extraction efficiency of volatile flavor compounds. A total of 37 volatile compounds were identified, comprising 21 esters, 6 alcohols, 3 terpenes, 2 acids, 2 ketones, 2 aldehydes and an aromatic with different hydrophobicities (log P) ranging between −0.14 and 4.83. Extraction using 10 g of diluted (5% w/w) blended soursop pulp with CAR/PDMS fiber at 25 °C for 30 min and 30% (w/w) of NaCl under stirring mode resulted in the highest extraction efficiency of volatile flavor compounds. The principal component analysis score discriminated the influence of SPME variables on the equilibrium headspace concentration of target volatile compounds. |
| first_indexed | 2024-03-06T07:35:56Z |
| format | Article |
| id | upm.eprints-15971 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T07:35:56Z |
| publishDate | 2011 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | upm.eprints-159712015-10-16T07:13:07Z http://psasir.upm.edu.my/id/eprint/15971/ Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. Cheong, Kok Whye Tan, Chin Ping Hamed, Mirhosseini Chin, Sung Tong Yaakob, Che Man Nazimah, Sheikh Abdul Hamid Osman, Azizah Basri, Mahiran Headspace solid-phase microextraction (HS-SPME) coupled to comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOFMS) was applied for equilibrium headspace analysis of Malaysian soursop (Annona muricata) volatile flavor compounds. A two-level fractional factorial design (25-1) was used to determine the effect of SPME variables, namely, SPME fibers, adsorption temperature, extraction time, amount of salt, sample amount and sample concentration on the extraction efficiency of volatile flavor compounds. A total of 37 volatile compounds were identified, comprising 21 esters, 6 alcohols, 3 terpenes, 2 acids, 2 ketones, 2 aldehydes and an aromatic with different hydrophobicities (log P) ranging between −0.14 and 4.83. Extraction using 10 g of diluted (5% w/w) blended soursop pulp with CAR/PDMS fiber at 25 °C for 30 min and 30% (w/w) of NaCl under stirring mode resulted in the highest extraction efficiency of volatile flavor compounds. The principal component analysis score discriminated the influence of SPME variables on the equilibrium headspace concentration of target volatile compounds. Elsevier 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/15971/1/Optimization%20of%20equilibrium%20headspace%20analysis%20of%20volatile%20flavor%20compounds%20of%20Malaysian%20soursop.pdf Cheong, Kok Whye and Tan, Chin Ping and Hamed, Mirhosseini and Chin, Sung Tong and Yaakob, Che Man and Nazimah, Sheikh Abdul Hamid and Osman, Azizah and Basri, Mahiran (2011) Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. Food Chemistry, 125 (4). pp. 1481-1489. ISSN 0308-8146 http://dx.doi.org/10.1016/j.foodchem.2010.10.067 English |
| spellingShingle | Cheong, Kok Whye Tan, Chin Ping Hamed, Mirhosseini Chin, Sung Tong Yaakob, Che Man Nazimah, Sheikh Abdul Hamid Osman, Azizah Basri, Mahiran Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. |
| title | Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. |
| title_full | Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. |
| title_fullStr | Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. |
| title_full_unstemmed | Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. |
| title_short | Optimization of equilibrium headspace analysis of volatile flavor compounds of Malaysian soursop (Annona muricata): Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry. |
| title_sort | optimization of equilibrium headspace analysis of volatile flavor compounds of malaysian soursop annona muricata comprehensive two dimensional gas chromatography time of flight mass spectrometry |
| url | http://psasir.upm.edu.my/id/eprint/15971/1/Optimization%20of%20equilibrium%20headspace%20analysis%20of%20volatile%20flavor%20compounds%20of%20Malaysian%20soursop.pdf |
| work_keys_str_mv | AT cheongkokwhye optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry AT tanchinping optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry AT hamedmirhosseini optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry AT chinsungtong optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry AT yaakobcheman optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry AT nazimahsheikhabdulhamid optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry AT osmanazizah optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry AT basrimahiran optimizationofequilibriumheadspaceanalysisofvolatileflavorcompoundsofmalaysiansoursopannonamuricatacomprehensivetwodimensionalgaschromatographytimeofflightmassspectrometry |