Protonation and complexation approaches for production of protic eutectic ionic liquids
4-formyl-N,N-dimethylbenzenaminium chloride (FDBC), carboxymethanami-nium chloride (CMAC), 1,3-dihydroxy-2-(hydroxymethyl)propan-2-aminium chloride (DHPC), (R)-1-carboxy-2-mercaptoethanaminium chloride (CMEC) and 1-methyl-2-oxopyrrolidinium chloride (MOPC) were synthesised and complexed with either...
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| Format: | Article |
| Language: | English |
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Penerbit Universiti Sains Malaysia
2010
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| Online Access: | http://psasir.upm.edu.my/id/eprint/16384/1/Protonation%20and%20complexation%20approaches%20for%20production%20of%20protic%20eutectic%20ionic%20liquids.pdf |
| _version_ | 1796969044309442560 |
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| author | Shamsuri, Ahmad Adlie Abdullah, Dzulkefly Kuang |
| author_facet | Shamsuri, Ahmad Adlie Abdullah, Dzulkefly Kuang |
| author_sort | Shamsuri, Ahmad Adlie |
| collection | UPM |
| description | 4-formyl-N,N-dimethylbenzenaminium chloride (FDBC), carboxymethanami-nium chloride (CMAC), 1,3-dihydroxy-2-(hydroxymethyl)propan-2-aminium chloride (DHPC), (R)-1-carboxy-2-mercaptoethanaminium chloride (CMEC) and 1-methyl-2-oxopyrrolidinium chloride (MOPC) were synthesised and complexed with either urea or oxalic acid at different molar ratios to form protic eutectic ionic liquids (PEILs). The melting point of the PEILs was measured using differential scanning calorimetry (DSC). Based on the melting point results, MOPC complexed with oxalic acid ([MOPC][O]) at a 1:1 molar ratio and DHPC complexed with urea ([DHPC][U]) at a 1:2 molar ratio were regarded as room temperature ionic liquids (RTILs). The solubility study showed that [MOPC][O] was able to fully dissolve soluble starch and rice starch (10 wt%) and partially dissolve sago starch. |
| first_indexed | 2024-03-06T07:37:16Z |
| format | Article |
| id | upm.eprints-16384 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T07:37:16Z |
| publishDate | 2010 |
| publisher | Penerbit Universiti Sains Malaysia |
| record_format | dspace |
| spelling | upm.eprints-163842016-11-29T05:07:36Z http://psasir.upm.edu.my/id/eprint/16384/ Protonation and complexation approaches for production of protic eutectic ionic liquids Shamsuri, Ahmad Adlie Abdullah, Dzulkefly Kuang 4-formyl-N,N-dimethylbenzenaminium chloride (FDBC), carboxymethanami-nium chloride (CMAC), 1,3-dihydroxy-2-(hydroxymethyl)propan-2-aminium chloride (DHPC), (R)-1-carboxy-2-mercaptoethanaminium chloride (CMEC) and 1-methyl-2-oxopyrrolidinium chloride (MOPC) were synthesised and complexed with either urea or oxalic acid at different molar ratios to form protic eutectic ionic liquids (PEILs). The melting point of the PEILs was measured using differential scanning calorimetry (DSC). Based on the melting point results, MOPC complexed with oxalic acid ([MOPC][O]) at a 1:1 molar ratio and DHPC complexed with urea ([DHPC][U]) at a 1:2 molar ratio were regarded as room temperature ionic liquids (RTILs). The solubility study showed that [MOPC][O] was able to fully dissolve soluble starch and rice starch (10 wt%) and partially dissolve sago starch. Penerbit Universiti Sains Malaysia 2010 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/16384/1/Protonation%20and%20complexation%20approaches%20for%20production%20of%20protic%20eutectic%20ionic%20liquids.pdf Shamsuri, Ahmad Adlie and Abdullah, Dzulkefly Kuang (2010) Protonation and complexation approaches for production of protic eutectic ionic liquids. Journal of Physical Science, 21 (1). pp. 15-28. ISSN 1675-3402; ESSN: 2180-4230 http://web.usm.my/jps/21-1.html |
| spellingShingle | Shamsuri, Ahmad Adlie Abdullah, Dzulkefly Kuang Protonation and complexation approaches for production of protic eutectic ionic liquids |
| title | Protonation and complexation approaches for production of protic eutectic ionic liquids |
| title_full | Protonation and complexation approaches for production of protic eutectic ionic liquids |
| title_fullStr | Protonation and complexation approaches for production of protic eutectic ionic liquids |
| title_full_unstemmed | Protonation and complexation approaches for production of protic eutectic ionic liquids |
| title_short | Protonation and complexation approaches for production of protic eutectic ionic liquids |
| title_sort | protonation and complexation approaches for production of protic eutectic ionic liquids |
| url | http://psasir.upm.edu.my/id/eprint/16384/1/Protonation%20and%20complexation%20approaches%20for%20production%20of%20protic%20eutectic%20ionic%20liquids.pdf |
| work_keys_str_mv | AT shamsuriahmadadlie protonationandcomplexationapproachesforproductionofproticeutecticionicliquids AT abdullahdzulkeflykuang protonationandcomplexationapproachesforproductionofproticeutecticionicliquids |