Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon

Combination of adsorption and photodegradation processes induces strong beneficial effects in dye removals. Adding high adsorption capacity activated carbon to photoactive titanium dioxide is an attractive solution due to their potential in removing dyes of diverse chemical characteristics. Recently...

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Main Authors: Chang, Sook Ken, Zainal, Zulkarnain, Abdullah, Abdul Halim
Format: Article
Language:English
Published: Malaysian Society of Analytical Sciences 2008
Online Access:http://psasir.upm.edu.my/id/eprint/16515/1/Removal%20of%20cationic%20and%20anionic%20dyes%20by%20immobilised%20titanium%20dioxide%20loaded%20activated%20carbon.pdf
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author Chang, Sook Ken
Zainal, Zulkarnain
Abdullah, Abdul Halim
author_facet Chang, Sook Ken
Zainal, Zulkarnain
Abdullah, Abdul Halim
author_sort Chang, Sook Ken
collection UPM
description Combination of adsorption and photodegradation processes induces strong beneficial effects in dye removals. Adding high adsorption capacity activated carbon to photoactive titanium dioxide is an attractive solution due to their potential in removing dyes of diverse chemical characteristics. Recently, immobilisation has been an acceptable approach to overcome the drawbacks encountered with powder suspensions. The present study involves the removals of Victoria Blue R (VBR), a cationic dye and Indigo Carmine (IC), an anionic using approximately one gram of immobilised titanium dioxide (TiO2), activated carbon (AC) and mixture titanium dioxide/activated carbon (TiO2/AC) from 200 mL solution at the concentration of 20 ppm under UV illumination for 4 hours. Comparisons were made in terms of their removal efficiency by applying first-order kinetics model. Immobilised TiO2 showed total removal of IC in 40 minutes whereas only 44% of VBR was removed in 2 hours. On the other hand, in the case of immobilised AC, about 87% of VBR and 6% of IC were removed in 2 hours. The results obtained using immobilised TiO 2/AC proved the prominence of this immobilised sample in dealing with VBR and IC by achieving 95% and 62% removal respectively in 2 hours.
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spelling upm.eprints-165152015-11-24T03:58:48Z http://psasir.upm.edu.my/id/eprint/16515/ Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon Chang, Sook Ken Zainal, Zulkarnain Abdullah, Abdul Halim Combination of adsorption and photodegradation processes induces strong beneficial effects in dye removals. Adding high adsorption capacity activated carbon to photoactive titanium dioxide is an attractive solution due to their potential in removing dyes of diverse chemical characteristics. Recently, immobilisation has been an acceptable approach to overcome the drawbacks encountered with powder suspensions. The present study involves the removals of Victoria Blue R (VBR), a cationic dye and Indigo Carmine (IC), an anionic using approximately one gram of immobilised titanium dioxide (TiO2), activated carbon (AC) and mixture titanium dioxide/activated carbon (TiO2/AC) from 200 mL solution at the concentration of 20 ppm under UV illumination for 4 hours. Comparisons were made in terms of their removal efficiency by applying first-order kinetics model. Immobilised TiO2 showed total removal of IC in 40 minutes whereas only 44% of VBR was removed in 2 hours. On the other hand, in the case of immobilised AC, about 87% of VBR and 6% of IC were removed in 2 hours. The results obtained using immobilised TiO 2/AC proved the prominence of this immobilised sample in dealing with VBR and IC by achieving 95% and 62% removal respectively in 2 hours. Malaysian Society of Analytical Sciences 2008 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/16515/1/Removal%20of%20cationic%20and%20anionic%20dyes%20by%20immobilised%20titanium%20dioxide%20loaded%20activated%20carbon.pdf Chang, Sook Ken and Zainal, Zulkarnain and Abdullah, Abdul Halim (2008) Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon. The Malaysian Journal of Analytical Sciences, 12 (2). pp. 451-457. ISSN 1394-2506
spellingShingle Chang, Sook Ken
Zainal, Zulkarnain
Abdullah, Abdul Halim
Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon
title Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon
title_full Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon
title_fullStr Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon
title_full_unstemmed Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon
title_short Removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon
title_sort removal of cationic and anionic dyes by immobilised titanium dioxide loaded activated carbon
url http://psasir.upm.edu.my/id/eprint/16515/1/Removal%20of%20cationic%20and%20anionic%20dyes%20by%20immobilised%20titanium%20dioxide%20loaded%20activated%20carbon.pdf
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AT zainalzulkarnain removalofcationicandanionicdyesbyimmobilisedtitaniumdioxideloadedactivatedcarbon
AT abdullahabdulhalim removalofcationicandanionicdyesbyimmobilisedtitaniumdioxideloadedactivatedcarbon