Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc

The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak...

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Main Authors: Abdul Wahab, Nor Asiken, Baba, Ibrahim, Mohamed Tahir, Mohamed Ibrahim, Tiekink, Edward R. T.
Format: Article
Language:English
Published: International Union of Crystallography 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf
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author Abdul Wahab, Nor Asiken
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_facet Abdul Wahab, Nor Asiken
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
author_sort Abdul Wahab, Nor Asiken
collection UPM
description The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H...S, C-H...[pi](ZnS2C) and [pi]-[pi] [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] interactions
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publisher International Union of Crystallography
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spelling upm.eprints-247862016-02-10T06:06:14Z http://psasir.upm.edu.my/id/eprint/24786/ Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H...S, C-H...[pi](ZnS2C) and [pi]-[pi] [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] interactions International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf Abdul Wahab, Nor Asiken and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc. Acta Crystallographica Section E: Structure Reports Online, 67 (7). pp. 553-554. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536811012499 10.1107/S1600536811012499
spellingShingle Abdul Wahab, Nor Asiken
Baba, Ibrahim
Mohamed Tahir, Mohamed Ibrahim
Tiekink, Edward R. T.
Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_full Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_fullStr Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_full_unstemmed Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_short Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
title_sort bis n isopropyl n methyldithiocarbamato kappa 2s s 1 10 phenanthroline kappa 2n n zinc
url http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf
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