Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc
The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
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International Union of Crystallography
2011
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Online Access: | http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf |
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author | Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_facet | Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
author_sort | Abdul Wahab, Nor Asiken |
collection | UPM |
description | The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H...S, C-H...[pi](ZnS2C) and [pi]-[pi] [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] interactions |
first_indexed | 2024-03-06T08:00:53Z |
format | Article |
id | upm.eprints-24786 |
institution | Universiti Putra Malaysia |
language | English |
last_indexed | 2024-03-06T08:00:53Z |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | dspace |
spelling | upm.eprints-247862016-02-10T06:06:14Z http://psasir.upm.edu.my/id/eprint/24786/ Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The ZnII atom in the title compound, [Zn(C5H10NS2)2(C12H8N2)], exists in a distorted cis-octahedral N2S4 donor set defined by two chelating dithiocarbamate anions as well as a 1,10-phenanthroline ligand. Each of the ligands coordinates in a symmetric mode. The crystal packing is stabilized by weak C-H...S, C-H...[pi](ZnS2C) and [pi]-[pi] [ring centroid distance between centrosymmetrically related pyridyl rings = 3.5955 (13) Å] interactions International Union of Crystallography 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf Abdul Wahab, Nor Asiken and Baba, Ibrahim and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2011) Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc. Acta Crystallographica Section E: Structure Reports Online, 67 (7). pp. 553-554. ISSN 1600-5368 http://dx.doi.org/10.1107/S1600536811012499 10.1107/S1600536811012499 |
spellingShingle | Abdul Wahab, Nor Asiken Baba, Ibrahim Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc |
title | Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc |
title_full | Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc |
title_fullStr | Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc |
title_full_unstemmed | Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc |
title_short | Bis(N-isopropyl-N-methyldithiocarbamato-[kappa]2S,S')(1,10-phenanthroline-[kappa]2N,N')zinc |
title_sort | bis n isopropyl n methyldithiocarbamato kappa 2s s 1 10 phenanthroline kappa 2n n zinc |
url | http://psasir.upm.edu.my/id/eprint/24786/1/Bis.pdf |
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