(2,2'-Bipyridyl-[kappa]2N,N')bis(N-butyl-N-methyldithiocarbamato-[kappa]2S,S')cadmium(II).
The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chain...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2011
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24787/1/2.pdf |
| Summary: | The CdII atom in the title compound, [Cd(C6H12NS2)2(C10H8N2)], is hexacoordinated by two dithiocarbamate ligands and the N atoms from a bidentate 2,2'-bipyridyl molecule. The coordination geometry is based on a distorted trigonal-prismatic arrangement of the N2S4 donor set. Supramolecular chains, aligned along the a-axis direction, are mediated by C-H...S interactions and these are connected into layers that stack along the c axis via [pi]-[pi] interactions [Cg(pyridyl)...Cg(pyridyl) = 3.6587 (13) Å]. |
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