Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.

A new series of calamitic liquid crystal materials with bisazobenzene moieties as a core has been synthesised and characterised by spectroscopic methods. The mesomorphic properties were investigated by differential scanning calorimetry, optical polarising microscopy and X-ray diffraction. The presen...

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Main Authors: Salisu, Abdulsalam Abubakar, Ab. Rahman, Mohamad Zaki, Silong, Sidik, Lutfor, Md Rahman, Ahmad @ Ayob, Mansor
Format: Article
Language:English
Published: Taylor & Francis 2011
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author Salisu, Abdulsalam Abubakar
Ab. Rahman, Mohamad Zaki
Silong, Sidik
Lutfor, Md Rahman
Ahmad @ Ayob, Mansor
author_facet Salisu, Abdulsalam Abubakar
Ab. Rahman, Mohamad Zaki
Silong, Sidik
Lutfor, Md Rahman
Ahmad @ Ayob, Mansor
author_sort Salisu, Abdulsalam Abubakar
collection UPM
description A new series of calamitic liquid crystal materials with bisazobenzene moieties as a core has been synthesised and characterised by spectroscopic methods. The mesomorphic properties were investigated by differential scanning calorimetry, optical polarising microscopy and X-ray diffraction. The presence of nematic and smectic A mesophases was confirmed by the textures and X-ray diffraction studies. All the compounds are found to show enantiotropic mesophase behaviour. The compounds show a significant photoisomerisation under appropriate light irradiation.
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spelling upm.eprints-247972014-08-06T05:39:15Z http://psasir.upm.edu.my/id/eprint/24797/ Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. Salisu, Abdulsalam Abubakar Ab. Rahman, Mohamad Zaki Silong, Sidik Lutfor, Md Rahman Ahmad @ Ayob, Mansor A new series of calamitic liquid crystal materials with bisazobenzene moieties as a core has been synthesised and characterised by spectroscopic methods. The mesomorphic properties were investigated by differential scanning calorimetry, optical polarising microscopy and X-ray diffraction. The presence of nematic and smectic A mesophases was confirmed by the textures and X-ray diffraction studies. All the compounds are found to show enantiotropic mesophase behaviour. The compounds show a significant photoisomerisation under appropriate light irradiation. Taylor & Francis 2011 Article PeerReviewed Salisu, Abdulsalam Abubakar and Ab. Rahman, Mohamad Zaki and Silong, Sidik and Lutfor, Md Rahman and Ahmad @ Ayob, Mansor (2011) Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. Liquid Crystals , 38 (4). pp. 423-431. ISSN 0267-8292 http://www.tandf.co.uk/ 10.1080/02678292.2010.550141 English
spellingShingle Salisu, Abdulsalam Abubakar
Ab. Rahman, Mohamad Zaki
Silong, Sidik
Lutfor, Md Rahman
Ahmad @ Ayob, Mansor
Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.
title Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.
title_full Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.
title_fullStr Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.
title_full_unstemmed Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.
title_short Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.
title_sort calamitic bisazobenzene liquid crystal series synthesis and mesomorphic properties of 1 methoxyalkyloxy 4 4 phenylazo azobenzene
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