Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene.
A new series of calamitic liquid crystal materials with bisazobenzene moieties as a core has been synthesised and characterised by spectroscopic methods. The mesomorphic properties were investigated by differential scanning calorimetry, optical polarising microscopy and X-ray diffraction. The presen...
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Format: | Article |
Language: | English |
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Taylor & Francis
2011
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author | Salisu, Abdulsalam Abubakar Ab. Rahman, Mohamad Zaki Silong, Sidik Lutfor, Md Rahman Ahmad @ Ayob, Mansor |
author_facet | Salisu, Abdulsalam Abubakar Ab. Rahman, Mohamad Zaki Silong, Sidik Lutfor, Md Rahman Ahmad @ Ayob, Mansor |
author_sort | Salisu, Abdulsalam Abubakar |
collection | UPM |
description | A new series of calamitic liquid crystal materials with bisazobenzene moieties as a core has been synthesised and characterised by spectroscopic methods. The mesomorphic properties were investigated by differential scanning calorimetry, optical polarising microscopy and X-ray diffraction. The presence of nematic and smectic A mesophases was confirmed by the textures and X-ray diffraction studies. All the compounds are found to show enantiotropic mesophase behaviour. The compounds show a significant photoisomerisation under appropriate light irradiation. |
first_indexed | 2024-03-06T08:00:55Z |
format | Article |
id | upm.eprints-24797 |
institution | Universiti Putra Malaysia |
language | English |
last_indexed | 2024-03-06T08:00:55Z |
publishDate | 2011 |
publisher | Taylor & Francis |
record_format | dspace |
spelling | upm.eprints-247972014-08-06T05:39:15Z http://psasir.upm.edu.my/id/eprint/24797/ Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. Salisu, Abdulsalam Abubakar Ab. Rahman, Mohamad Zaki Silong, Sidik Lutfor, Md Rahman Ahmad @ Ayob, Mansor A new series of calamitic liquid crystal materials with bisazobenzene moieties as a core has been synthesised and characterised by spectroscopic methods. The mesomorphic properties were investigated by differential scanning calorimetry, optical polarising microscopy and X-ray diffraction. The presence of nematic and smectic A mesophases was confirmed by the textures and X-ray diffraction studies. All the compounds are found to show enantiotropic mesophase behaviour. The compounds show a significant photoisomerisation under appropriate light irradiation. Taylor & Francis 2011 Article PeerReviewed Salisu, Abdulsalam Abubakar and Ab. Rahman, Mohamad Zaki and Silong, Sidik and Lutfor, Md Rahman and Ahmad @ Ayob, Mansor (2011) Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. Liquid Crystals , 38 (4). pp. 423-431. ISSN 0267-8292 http://www.tandf.co.uk/ 10.1080/02678292.2010.550141 English |
spellingShingle | Salisu, Abdulsalam Abubakar Ab. Rahman, Mohamad Zaki Silong, Sidik Lutfor, Md Rahman Ahmad @ Ayob, Mansor Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. |
title | Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. |
title_full | Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. |
title_fullStr | Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. |
title_full_unstemmed | Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. |
title_short | Calamitic bisazobenzene liquid crystal series: synthesis and mesomorphic properties of 1-methoxyalkyloxy-4'-(4-phenylazo)azobenzene. |
title_sort | calamitic bisazobenzene liquid crystal series synthesis and mesomorphic properties of 1 methoxyalkyloxy 4 4 phenylazo azobenzene |
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