Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas

Gasification of dry palm oil empty fruit bunch (EFB), by using a temperature-programmed instrument was performed to determine the amount of synthesis gas produced. Dry and finely crushed EFB was pre-mixed with calcium oxide. Temperature-programmed gasification (TPG) was done at temperature from 50°C...

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Main Authors: Ismail, Khomah, Yarmo, Mohd Ambar, Yap, Taufiq Yun Hin, Ahmad, Aishah
Format: Article
Language:English
Published: Trans Tech Publications 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24843/1/Calcium%20oxide%20as%20potential%20catalyst%20for%20gasification%20of%20palm%20oil%20empty%20fruit%20bunch%20to%20produce%20syngas.pdf
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author Ismail, Khomah
Yarmo, Mohd Ambar
Yap, Taufiq Yun Hin
Ahmad, Aishah
author_facet Ismail, Khomah
Yarmo, Mohd Ambar
Yap, Taufiq Yun Hin
Ahmad, Aishah
author_sort Ismail, Khomah
collection UPM
description Gasification of dry palm oil empty fruit bunch (EFB), by using a temperature-programmed instrument was performed to determine the amount of synthesis gas produced. Dry and finely crushed EFB was pre-mixed with calcium oxide. Temperature-programmed gasification (TPG) was done at temperature from 50°C - 550°C and also from 50°C - 700°C using 5% oxygen in He. Both experiments were held for 1hr at the final temperature. The products were monitored using an online mass spectrometer. Major products detected from this reaction were H2, CO, CO2 and CH4. The effect of calcium oxide amount (CaO: EFB ratio) was also investigated. A very significant increase of H2 and CO was observed when nano-sized calcium oxide was used as catalyst compared to bulk one. Reaction at 700°C using nano-sized CaO reduces the production of carbon dioxide during gasification. The characteristics of the catalyst used were analyzed by using XRD and XPS show some significant changes from CaO to CaCO3.
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spelling upm.eprints-248432015-12-02T09:10:13Z http://psasir.upm.edu.my/id/eprint/24843/ Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas Ismail, Khomah Yarmo, Mohd Ambar Yap, Taufiq Yun Hin Ahmad, Aishah Gasification of dry palm oil empty fruit bunch (EFB), by using a temperature-programmed instrument was performed to determine the amount of synthesis gas produced. Dry and finely crushed EFB was pre-mixed with calcium oxide. Temperature-programmed gasification (TPG) was done at temperature from 50°C - 550°C and also from 50°C - 700°C using 5% oxygen in He. Both experiments were held for 1hr at the final temperature. The products were monitored using an online mass spectrometer. Major products detected from this reaction were H2, CO, CO2 and CH4. The effect of calcium oxide amount (CaO: EFB ratio) was also investigated. A very significant increase of H2 and CO was observed when nano-sized calcium oxide was used as catalyst compared to bulk one. Reaction at 700°C using nano-sized CaO reduces the production of carbon dioxide during gasification. The characteristics of the catalyst used were analyzed by using XRD and XPS show some significant changes from CaO to CaCO3. Trans Tech Publications 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24843/1/Calcium%20oxide%20as%20potential%20catalyst%20for%20gasification%20of%20palm%20oil%20empty%20fruit%20bunch%20to%20produce%20syngas.pdf Ismail, Khomah and Yarmo, Mohd Ambar and Yap, Taufiq Yun Hin and Ahmad, Aishah (2011) Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas. Advanced Materials Research, 173. pp. 178-183. ISSN 1022-6680; ESSN: 1662-8985 http://www.scientific.net/AMR.173.178 10.4028/www.scientific.net/AMR.173.178
spellingShingle Ismail, Khomah
Yarmo, Mohd Ambar
Yap, Taufiq Yun Hin
Ahmad, Aishah
Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas
title Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas
title_full Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas
title_fullStr Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas
title_full_unstemmed Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas
title_short Calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas
title_sort calcium oxide as potential catalyst for gasification of palm oil empty fruit bunch to produce syngas
url http://psasir.upm.edu.my/id/eprint/24843/1/Calcium%20oxide%20as%20potential%20catalyst%20for%20gasification%20of%20palm%20oil%20empty%20fruit%20bunch%20to%20produce%20syngas.pdf
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