Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker.

Chemical treatment is often used to improve the physical and mechanical properties of wood materials. In this study, wood polymer composites (WPC) were prepared from five types of tropical wood species by impregnating the woods with methyl methacrylate (MMA) combined with a cross-linker hexamethylen...

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Main Authors: Talib, Zainal Abidin, Hamdan, S., Islam, Md. Saiful, Jusoh, Ismail, Rahman, Md. Rezaur
Format: Article
Language:English
English
Published: American Chemical Society 2011
Online Access:http://psasir.upm.edu.my/id/eprint/24847/1/Dimensional%20stability%20and%20dynamic%20young.pdf
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author Talib, Zainal Abidin
Hamdan, S.
Islam, Md. Saiful
Jusoh, Ismail
Rahman, Md. Rezaur
author_facet Talib, Zainal Abidin
Hamdan, S.
Islam, Md. Saiful
Jusoh, Ismail
Rahman, Md. Rezaur
author_sort Talib, Zainal Abidin
collection UPM
description Chemical treatment is often used to improve the physical and mechanical properties of wood materials. In this study, wood polymer composites (WPC) were prepared from five types of tropical wood species by impregnating the woods with methyl methacrylate (MMA) combined with a cross-linker hexamethylene diisocyanate (HMDIC). Their dimensional stability and mechanical properties were then investigated. The impregnation of wood with monomer systems and polymerization was accomplished through vacuum-pressure and catalyst heat treatment method, respectively. The manufacturing of WPC was confirmed through FT-IR spectroscopy and X-ray diffraction (XRD) analyses. The dimensional stability of manufactured WPC in terms of volumetric swelling (S) and antishrink efficiency (ASE) was measured and found to be improved on treatment. In addition, the modified WPC had lower moisture absorption and higher water repellent efficiency compared to raw wood. The mechanical property of treated samples in terms of dynamics Young’s modulus (Ed) was also shown to improve. These improvements in properties were observed as more effective with MMA-HMDIC combination.
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spelling upm.eprints-248472016-01-12T03:15:26Z http://psasir.upm.edu.my/id/eprint/24847/ Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker. Talib, Zainal Abidin Hamdan, S. Islam, Md. Saiful Jusoh, Ismail Rahman, Md. Rezaur Chemical treatment is often used to improve the physical and mechanical properties of wood materials. In this study, wood polymer composites (WPC) were prepared from five types of tropical wood species by impregnating the woods with methyl methacrylate (MMA) combined with a cross-linker hexamethylene diisocyanate (HMDIC). Their dimensional stability and mechanical properties were then investigated. The impregnation of wood with monomer systems and polymerization was accomplished through vacuum-pressure and catalyst heat treatment method, respectively. The manufacturing of WPC was confirmed through FT-IR spectroscopy and X-ray diffraction (XRD) analyses. The dimensional stability of manufactured WPC in terms of volumetric swelling (S) and antishrink efficiency (ASE) was measured and found to be improved on treatment. In addition, the modified WPC had lower moisture absorption and higher water repellent efficiency compared to raw wood. The mechanical property of treated samples in terms of dynamics Young’s modulus (Ed) was also shown to improve. These improvements in properties were observed as more effective with MMA-HMDIC combination. American Chemical Society 2011 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24847/1/Dimensional%20stability%20and%20dynamic%20young.pdf Talib, Zainal Abidin and Hamdan, S. and Islam, Md. Saiful and Jusoh, Ismail and Rahman, Md. Rezaur (2011) Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker. Industrial & Engineering Chemistry Research, 50 (50). pp. 3900-3906. ISSN 0888-5885 http://pubs.acs.org/ English
spellingShingle Talib, Zainal Abidin
Hamdan, S.
Islam, Md. Saiful
Jusoh, Ismail
Rahman, Md. Rezaur
Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker.
title Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker.
title_full Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker.
title_fullStr Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker.
title_full_unstemmed Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker.
title_short Dimensional stability and dynamic young's modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with Hexamethylene Diisocyanate cross-linker.
title_sort dimensional stability and dynamic young s modulus of tropical light hardwood chemically treated with methyl methacrylate in combination with hexamethylene diisocyanate cross linker
url http://psasir.upm.edu.my/id/eprint/24847/1/Dimensional%20stability%20and%20dynamic%20young.pdf
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