S-Quinolin-2-ylmethyldithiocarbazate.
In the title compound, C11H11N2S2, there is an intramolecular N-H...N [2.778 (2) Å] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1)° with the dithiocarbazate group. Bond angles for both S-C-S [115.66 (8)°] and N-C-S [119.05...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English English English |
| Published: |
International Union of Crystallography
2007
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| Online Access: | http://psasir.upm.edu.my/id/eprint/24956/1/S.pdf http://psasir.upm.edu.my/id/eprint/24956/2/S.pdf |
| _version_ | 1796970662762381312 |
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| author | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_facet | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim |
| author_sort | How, Fiona Ni Foong |
| collection | UPM |
| description | In the title compound, C11H11N2S2, there is an intramolecular N-H...N [2.778 (2) Å] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1)° with the dithiocarbazate group. Bond angles for both S-C-S [115.66 (8)°] and N-C-S [119.05 (11)°] are comparable with cis-trans S-methyldithiocarbazate but differ from those found in trans-cis S-methyldithiocarbazate and trans-cis S-benzyldithiocarbazate. This is due to the N-H...N hydrogen bond that exists only in the cis-trans conformation found for the title compound. |
| first_indexed | 2024-03-06T08:01:24Z |
| format | Article |
| id | upm.eprints-24956 |
| institution | Universiti Putra Malaysia |
| language | English English English |
| last_indexed | 2024-03-06T08:01:24Z |
| publishDate | 2007 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-249562015-09-17T03:30:59Z http://psasir.upm.edu.my/id/eprint/24956/ S-Quinolin-2-ylmethyldithiocarbazate. How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim In the title compound, C11H11N2S2, there is an intramolecular N-H...N [2.778 (2) Å] hydrogen bond linking the quinoline N atom and the imino N atom. The planar quinoline ring system forms an angle of 67.7 (1)° with the dithiocarbazate group. Bond angles for both S-C-S [115.66 (8)°] and N-C-S [119.05 (11)°] are comparable with cis-trans S-methyldithiocarbazate but differ from those found in trans-cis S-methyldithiocarbazate and trans-cis S-benzyldithiocarbazate. This is due to the N-H...N hydrogen bond that exists only in the cis-trans conformation found for the title compound. International Union of Crystallography 2007-06-06 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/24956/1/S.pdf application/pdf en http://psasir.upm.edu.my/id/eprint/24956/2/S.pdf How, Fiona Ni Foong and Watkin, David J. and Crouse, Karen Anne and Mohamed Tahir, Mohamed Ibrahim (2007) S-Quinolin-2-ylmethyldithiocarbazate. Acta Crystallographica Section E: Structure Reports Online, 63 (7). pp. 3137-3138. ISSN 1600-5368 10.1107/S1600536807024609 English |
| spellingShingle | How, Fiona Ni Foong Watkin, David J. Crouse, Karen Anne Mohamed Tahir, Mohamed Ibrahim S-Quinolin-2-ylmethyldithiocarbazate. |
| title | S-Quinolin-2-ylmethyldithiocarbazate. |
| title_full | S-Quinolin-2-ylmethyldithiocarbazate. |
| title_fullStr | S-Quinolin-2-ylmethyldithiocarbazate. |
| title_full_unstemmed | S-Quinolin-2-ylmethyldithiocarbazate. |
| title_short | S-Quinolin-2-ylmethyldithiocarbazate. |
| title_sort | s quinolin 2 ylmethyldithiocarbazate |
| url | http://psasir.upm.edu.my/id/eprint/24956/1/S.pdf http://psasir.upm.edu.my/id/eprint/24956/2/S.pdf |
| work_keys_str_mv | AT howfionanifoong squinolin2ylmethyldithiocarbazate AT watkindavidj squinolin2ylmethyldithiocarbazate AT crousekarenanne squinolin2ylmethyldithiocarbazate AT mohamedtahirmohamedibrahim squinolin2ylmethyldithiocarbazate |