A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends.

Polymer blends were prepared by melt blending technique using poly vinyl chloride (PVC) and poly(butylene adipate-co-terephthalate) (PBAT). Different ratios of the blends were studied to investigate their mechanical, thermal and morphological properties. The FTIR spectrum indicated a slight increase...

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Main Authors: Ibrahim, Nor Azowa, M. Rahim, Nazri, Wan Yunus, Wan Md. Zin, Sharif, Jamaliah
Format: Article
Language:English
English
Published: Springer Verlag 2011
Online Access:http://psasir.upm.edu.my/id/eprint/25000/1/A%20study%20of%20poly%20vinyl%20chloride.pdf
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author Ibrahim, Nor Azowa
M. Rahim, Nazri
Wan Yunus, Wan Md. Zin
Sharif, Jamaliah
author_facet Ibrahim, Nor Azowa
M. Rahim, Nazri
Wan Yunus, Wan Md. Zin
Sharif, Jamaliah
author_sort Ibrahim, Nor Azowa
collection UPM
description Polymer blends were prepared by melt blending technique using poly vinyl chloride (PVC) and poly(butylene adipate-co-terephthalate) (PBAT). Different ratios of the blends were studied to investigate their mechanical, thermal and morphological properties. The FTIR spectrum indicated a slight increase of frequencies at C = O peak from 1714 to 1718 cm-1 indicating a chemical interaction between C = O of PBAT and α-hydrogen of PVC. The tensile properties of PVC/PBAT blends highest at weight ratio of 50/50. The dynamic mechanical analysis (DMA) result proves that PVC and PBAT formed a miscible system with one glass transition temperature (Tg). The incorporation of PBAT results in a gradual decrease of the viscosity (loss modulus) and an increase of elasticity (storage modulus). The thermal properties of blend show the decomposition temperature of PVC in the blend decrease with the addition of PBAT. Scanning electron micrograph shows good interfacial adhesion on the tensile fractured surface of PVC/PBAT blend, which played important roles in enhancing the mechanical properties (strength and modulus).
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spelling upm.eprints-250002015-09-22T07:11:30Z http://psasir.upm.edu.my/id/eprint/25000/ A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends. Ibrahim, Nor Azowa M. Rahim, Nazri Wan Yunus, Wan Md. Zin Sharif, Jamaliah Polymer blends were prepared by melt blending technique using poly vinyl chloride (PVC) and poly(butylene adipate-co-terephthalate) (PBAT). Different ratios of the blends were studied to investigate their mechanical, thermal and morphological properties. The FTIR spectrum indicated a slight increase of frequencies at C = O peak from 1714 to 1718 cm-1 indicating a chemical interaction between C = O of PBAT and α-hydrogen of PVC. The tensile properties of PVC/PBAT blends highest at weight ratio of 50/50. The dynamic mechanical analysis (DMA) result proves that PVC and PBAT formed a miscible system with one glass transition temperature (Tg). The incorporation of PBAT results in a gradual decrease of the viscosity (loss modulus) and an increase of elasticity (storage modulus). The thermal properties of blend show the decomposition temperature of PVC in the blend decrease with the addition of PBAT. Scanning electron micrograph shows good interfacial adhesion on the tensile fractured surface of PVC/PBAT blend, which played important roles in enhancing the mechanical properties (strength and modulus). Springer Verlag 2011-09 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25000/1/A%20study%20of%20poly%20vinyl%20chloride.pdf Ibrahim, Nor Azowa and M. Rahim, Nazri and Wan Yunus, Wan Md. Zin and Sharif, Jamaliah (2011) A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends. Journal of Polymer Research, 18 (5). pp. 891-896. ISSN 1022-9760; ESSN:1572-8935 http://link.springer.com/ 10.1007/s10965-010-9486-1 English
spellingShingle Ibrahim, Nor Azowa
M. Rahim, Nazri
Wan Yunus, Wan Md. Zin
Sharif, Jamaliah
A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends.
title A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends.
title_full A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends.
title_fullStr A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends.
title_full_unstemmed A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends.
title_short A study of poly vinyl chloride / poly (butylene adipate-co-terephthalate) blends.
title_sort study of poly vinyl chloride poly butylene adipate co terephthalate blends
url http://psasir.upm.edu.my/id/eprint/25000/1/A%20study%20of%20poly%20vinyl%20chloride.pdf
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