Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV).
The title compound, [Sn(C4H9)2(C9H10NS2)2], features a tetrahedrally coordinated SnIV atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the SnIV atom [3.0136 (7) and 2.9865 (8) Å], giv...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
| Published: |
International Union of Crystallography
2012
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| Online Access: | http://psasir.upm.edu.my/id/eprint/25080/1/Di.pdf |
| _version_ | 1825925704630403072 |
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| author | Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_facet | Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. |
| author_sort | Kamaludin, Nurul Farahana |
| collection | UPM |
| description | The title compound, [Sn(C4H9)2(C9H10NS2)2], features a tetrahedrally coordinated SnIV atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the SnIV atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H(...)S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C—H(...)π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites. |
| first_indexed | 2024-03-06T08:01:46Z |
| format | Article |
| id | upm.eprints-25080 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T08:01:46Z |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-250802015-09-21T00:09:18Z http://psasir.upm.edu.my/id/eprint/25080/ Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. The title compound, [Sn(C4H9)2(C9H10NS2)2], features a tetrahedrally coordinated SnIV atom; the dithiocarbamate ligands coordinate in a monodentate fashion, accompanied by two n-butyl chains. The non-coordinating thione S atoms are each proximate to the SnIV atom [3.0136 (7) and 2.9865 (8) Å], giving rise to distortions from the ideal geometry as evident in the wide C—Sn—C bond angle of 139.06 (12) °. In the crystal, C—H(...)S interactions lead to the formation of a linear supramolecular chain along the b axis. The chains are aligned into layers by C—H(...)π interactions, and the layers stack along [001]. One of the ethyl groups is statistically disordered over two sets of sites. International Union of Crystallography 2012 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25080/1/Di.pdf Kamaludin, Nurul Farahana and Baba, Ibrahim and Awang, Normah and Mohamed Tahir, Mohamed Ibrahim and Tiekink, Edward R. T. (2012) Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). Acta Crystallographica Section E: Structure Reports Online, E68 (1). m79-m80. ISSN 1600-5368 http://www.iucr.org/ 10.1107/S160053681105392X English |
| spellingShingle | Kamaludin, Nurul Farahana Baba, Ibrahim Awang, Normah Mohamed Tahir, Mohamed Ibrahim Tiekink, Edward R. T. Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). |
| title | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). |
| title_full | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). |
| title_fullStr | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). |
| title_full_unstemmed | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). |
| title_short | Di-n-butylbis(N-ethyl-N-phenyldithiocarbamato- kS)tin(IV). |
| title_sort | di n butylbis n ethyl n phenyldithiocarbamato ks tin iv |
| url | http://psasir.upm.edu.my/id/eprint/25080/1/Di.pdf |
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