Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate
In the title compound, C14H14N2S3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragment...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2003
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| Online Access: | http://psasir.upm.edu.my/id/eprint/25098/1/Benzyl%20N-%5B1-%28thiophen-2-yl%29ethylidene%5D-hydrazinecarbodithioate.pdf |
| _version_ | 1796970691311960064 |
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| author | Chan, Eddy Mun Hoe Crouse, Karen Anne Tarafder, M. Tofazzal H. Mohd Yamin, Bohari |
| author_facet | Chan, Eddy Mun Hoe Crouse, Karen Anne Tarafder, M. Tofazzal H. Mohd Yamin, Bohari |
| author_sort | Chan, Eddy Mun Hoe |
| collection | UPM |
| description | In the title compound, C14H14N2S3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragments, respectively. In the crystal structure, the molecules are linked by N-H...S hydrogen bonds between the amino group and the thiono S atoms and are arranged as dimers parallel to ab face. |
| first_indexed | 2024-03-06T08:01:49Z |
| format | Article |
| id | upm.eprints-25098 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T08:01:49Z |
| publishDate | 2003 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-250982018-01-15T06:00:34Z http://psasir.upm.edu.my/id/eprint/25098/ Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate Chan, Eddy Mun Hoe Crouse, Karen Anne Tarafder, M. Tofazzal H. Mohd Yamin, Bohari In the title compound, C14H14N2S3, the benzyl and 1-(thiophen-2-yl)ethylideneamine groups are cis and trans to the thiono S atom across the C-S and C-N bonds, respectively. The dithiocarbazate plane makes dihedral angles of 9.14 (6) and 85.40 (8)° with the thiophenemethyleneamine and benzyl fragments, respectively. In the crystal structure, the molecules are linked by N-H...S hydrogen bonds between the amino group and the thiono S atoms and are arranged as dimers parallel to ab face. International Union of Crystallography 2003-05 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25098/1/Benzyl%20N-%5B1-%28thiophen-2-yl%29ethylidene%5D-hydrazinecarbodithioate.pdf Chan, Eddy Mun Hoe and Crouse, Karen Anne and Tarafder, M. Tofazzal H. and Mohd Yamin, Bohari (2003) Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate. Acta Crystallographica Section E: Structure Reports Online, 59 (5). pp. 628-629. ISSN 1600-5368 http://scripts.iucr.org/cgi-bin/paper?S1600536803007517 10.1107/S1600536803007517 |
| spellingShingle | Chan, Eddy Mun Hoe Crouse, Karen Anne Tarafder, M. Tofazzal H. Mohd Yamin, Bohari Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate |
| title | Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate |
| title_full | Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate |
| title_fullStr | Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate |
| title_full_unstemmed | Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate |
| title_short | Benzyl N-[1-(thiophen-2-yl)ethylidene)]-hydrazinecarbodithioate |
| title_sort | benzyl n 1 thio phen 2 yl ethyl idene hydrazinecarbodi thioate |
| url | http://psasir.upm.edu.my/id/eprint/25098/1/Benzyl%20N-%5B1-%28thiophen-2-yl%29ethylidene%5D-hydrazinecarbodithioate.pdf |
| work_keys_str_mv | AT chaneddymunhoe benzyln1thiophen2ylethylidenehydrazinecarbodithioate AT crousekarenanne benzyln1thiophen2ylethylidenehydrazinecarbodithioate AT tarafdermtofazzalh benzyln1thiophen2ylethylidenehydrazinecarbodithioate AT mohdyaminbohari benzyln1thiophen2ylethylidenehydrazinecarbodithioate |