Photodegradation of m-cresol by zinc oxide under visible-light irradiation.

The photodegradation of m-cresol was carried out under visible light (46% sunlight) by ZnO as photocatalyst. To measure the efficiency of photodegradation, the different variables studied included amount of photocatalyst, concentration of m-cresol and pH. The maximum amount of photocatalyst and co...

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Main Authors: Abdollahi, Yadollah, Abdullah, Abdul Halim, Zainal, Zulkarnain, Yusof, Nor Azah
Format: Article
Language:English
Published: Canadian Center of Science and Education 2011
Online Access:http://psasir.upm.edu.my/id/eprint/25111/1/Photodegradation%20of%20m.pdf
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author Abdollahi, Yadollah
Abdullah, Abdul Halim
Zainal, Zulkarnain
Yusof, Nor Azah
author_facet Abdollahi, Yadollah
Abdullah, Abdul Halim
Zainal, Zulkarnain
Yusof, Nor Azah
author_sort Abdollahi, Yadollah
collection UPM
description The photodegradation of m-cresol was carried out under visible light (46% sunlight) by ZnO as photocatalyst. To measure the efficiency of photodegradation, the different variables studied included amount of photocatalyst, concentration of m-cresol and pH. The maximum amount of photocatalyst and concentration of m-cresol was 1.5 g/L and 25 ppm respectively. The photodegradation was favorable in the pH 6-9 range. The detected intermediates were 2-methyl-1,4-benzodiol, 2-methyl-para-benzoquinone, 3,5-dihydroxytoluene and 2,5-dihydroxy-benzaldehyde. TOC studies show that 78% of total organic carbon is removed from solution during irradiation time. This study indicates the great potential of ZnO to remove aqueous m-cresol under visible-light irradiation which is part of sunlight.
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spelling upm.eprints-251112016-06-30T05:19:14Z http://psasir.upm.edu.my/id/eprint/25111/ Photodegradation of m-cresol by zinc oxide under visible-light irradiation. Abdollahi, Yadollah Abdullah, Abdul Halim Zainal, Zulkarnain Yusof, Nor Azah The photodegradation of m-cresol was carried out under visible light (46% sunlight) by ZnO as photocatalyst. To measure the efficiency of photodegradation, the different variables studied included amount of photocatalyst, concentration of m-cresol and pH. The maximum amount of photocatalyst and concentration of m-cresol was 1.5 g/L and 25 ppm respectively. The photodegradation was favorable in the pH 6-9 range. The detected intermediates were 2-methyl-1,4-benzodiol, 2-methyl-para-benzoquinone, 3,5-dihydroxytoluene and 2,5-dihydroxy-benzaldehyde. TOC studies show that 78% of total organic carbon is removed from solution during irradiation time. This study indicates the great potential of ZnO to remove aqueous m-cresol under visible-light irradiation which is part of sunlight. Canadian Center of Science and Education 2011-08 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25111/1/Photodegradation%20of%20m.pdf Abdollahi, Yadollah and Abdullah, Abdul Halim and Zainal, Zulkarnain and Yusof, Nor Azah (2011) Photodegradation of m-cresol by zinc oxide under visible-light irradiation. International Journal of Chemistry, 3 (3). pp. 31-43. ISSN 1916-9752 10.5539/ijc.v3n3p31
spellingShingle Abdollahi, Yadollah
Abdullah, Abdul Halim
Zainal, Zulkarnain
Yusof, Nor Azah
Photodegradation of m-cresol by zinc oxide under visible-light irradiation.
title Photodegradation of m-cresol by zinc oxide under visible-light irradiation.
title_full Photodegradation of m-cresol by zinc oxide under visible-light irradiation.
title_fullStr Photodegradation of m-cresol by zinc oxide under visible-light irradiation.
title_full_unstemmed Photodegradation of m-cresol by zinc oxide under visible-light irradiation.
title_short Photodegradation of m-cresol by zinc oxide under visible-light irradiation.
title_sort photodegradation of m cresol by zinc oxide under visible light irradiation
url http://psasir.upm.edu.my/id/eprint/25111/1/Photodegradation%20of%20m.pdf
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