The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite.
Layered organic-inorganic hybrid materials of Zn-Al-layered double hydroxide (LDH)-pamoate nanocomposite (ZAPR) were prepared using various initial Zn/Al molar ratios (Ri) from 8:1 to 2:1 which gave initial values of A 3+/(Zn 2+ + Al 3+) mole fractions, (x i) from 0.11 to 0.33. The Al 3+ mole fracti...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English English |
| Published: |
Springer Link
2012
|
| Online Access: | http://psasir.upm.edu.my/id/eprint/25211/1/The%20effect%20of%20substitution%20of%20zinc%20with%20aluminium%20in%20the%20brucite.pdf |
| _version_ | 1796970713715834880 |
|---|---|
| author | Jubri, Zaemah Hussein, Mohd. Zobir Yahya, Asmah Zainal, Zulkarnain |
| author_facet | Jubri, Zaemah Hussein, Mohd. Zobir Yahya, Asmah Zainal, Zulkarnain |
| author_sort | Jubri, Zaemah |
| collection | UPM |
| description | Layered organic-inorganic hybrid materials of Zn-Al-layered double hydroxide (LDH)-pamoate nanocomposite (ZAPR) were prepared using various initial Zn/Al molar ratios (Ri) from 8:1 to 2:1 which gave initial values of A 3+/(Zn 2+ + Al 3+) mole fractions, (x i) from 0.11 to 0.33. The Al 3+ mole fractions in the resulting nanocomposite material (x f) were greater than x i and the difference between x i and x f was found to be a constant value of 0.03. The increase in the x f values will increase the Al 3+ content in the interlayer spaces of layered double hydroxide and therefore increases the charge density of the inorganic brucite-like layers and give stronger electrostatic attraction between the excess positive charge of Al 3+ and the negative charge of the interlayer pamoate anion and hence decreases the d value of the material. However, the BET surface area of the resulting materials will decreases when the x f is increased. This shows that the mole fraction of Zn 2+ replaced by Al 3+ in the inorganic brucite-like layer plays an important role in controlling the physicochemical properties of the resulting material, which is particularly useful in determining tailor-made property required in the designed material. |
| first_indexed | 2024-03-06T08:02:09Z |
| format | Article |
| id | upm.eprints-25211 |
| institution | Universiti Putra Malaysia |
| language | English English |
| last_indexed | 2024-03-06T08:02:09Z |
| publishDate | 2012 |
| publisher | Springer Link |
| record_format | dspace |
| spelling | upm.eprints-252112015-10-05T08:15:35Z http://psasir.upm.edu.my/id/eprint/25211/ The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. Jubri, Zaemah Hussein, Mohd. Zobir Yahya, Asmah Zainal, Zulkarnain Layered organic-inorganic hybrid materials of Zn-Al-layered double hydroxide (LDH)-pamoate nanocomposite (ZAPR) were prepared using various initial Zn/Al molar ratios (Ri) from 8:1 to 2:1 which gave initial values of A 3+/(Zn 2+ + Al 3+) mole fractions, (x i) from 0.11 to 0.33. The Al 3+ mole fractions in the resulting nanocomposite material (x f) were greater than x i and the difference between x i and x f was found to be a constant value of 0.03. The increase in the x f values will increase the Al 3+ content in the interlayer spaces of layered double hydroxide and therefore increases the charge density of the inorganic brucite-like layers and give stronger electrostatic attraction between the excess positive charge of Al 3+ and the negative charge of the interlayer pamoate anion and hence decreases the d value of the material. However, the BET surface area of the resulting materials will decreases when the x f is increased. This shows that the mole fraction of Zn 2+ replaced by Al 3+ in the inorganic brucite-like layer plays an important role in controlling the physicochemical properties of the resulting material, which is particularly useful in determining tailor-made property required in the designed material. Springer Link 2012-02 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25211/1/The%20effect%20of%20substitution%20of%20zinc%20with%20aluminium%20in%20the%20brucite.pdf Jubri, Zaemah and Hussein, Mohd. Zobir and Yahya, Asmah and Zainal, Zulkarnain (2012) The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. Journal of Porous Materials, 19 (1). pp. 45-51. ISSN 1380-2224 http://link.springer.com/ 10.1007/s10934-010-9446-5 English |
| spellingShingle | Jubri, Zaemah Hussein, Mohd. Zobir Yahya, Asmah Zainal, Zulkarnain The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. |
| title | The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. |
| title_full | The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. |
| title_fullStr | The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. |
| title_full_unstemmed | The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. |
| title_short | The effect of substitution of zinc with aluminium in the brucite-like layers on the physicochemical properties of zinc-aluminium-layered double hydroxide-pamoate nanocomposite. |
| title_sort | effect of substitution of zinc with aluminium in the brucite like layers on the physicochemical properties of zinc aluminium layered double hydroxide pamoate nanocomposite |
| url | http://psasir.upm.edu.my/id/eprint/25211/1/The%20effect%20of%20substitution%20of%20zinc%20with%20aluminium%20in%20the%20brucite.pdf |
| work_keys_str_mv | AT jubrizaemah theeffectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite AT husseinmohdzobir theeffectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite AT yahyaasmah theeffectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite AT zainalzulkarnain theeffectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite AT jubrizaemah effectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite AT husseinmohdzobir effectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite AT yahyaasmah effectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite AT zainalzulkarnain effectofsubstitutionofzincwithaluminiuminthebrucitelikelayersonthephysicochemicalpropertiesofzincaluminiumlayereddoublehydroxidepamoatenanocomposite |