Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension.

The present paper reports the UV-assisted degradation of 1,4-benzoquinone in ZnO suspensions. The variables studied include the concentration of 1,4-benzoquinone, photocatalyst, pH and the total organic carbon. The concentration of 1,4-benzoquinone and residue organic carbon were measured using UV-V...

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Main Authors: Abdollahi, Yadollah, Abdullah, Abdul Halim, I. Gaya, Umar, Ahmadzadeh, Saeid, Zakaria, Azmi, Shameli, Kamyar, Zainal, Zulkarnain, Jahangirian, Hossein, Yusof, Nor Azah
Format: Article
Language:English
English
Published: Sociedade Brasileira de Química, SBQ 2012
Online Access:http://psasir.upm.edu.my/id/eprint/25223/1/Photocatalytic%20degradaton%20of%201.pdf
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author Abdollahi, Yadollah
Abdullah, Abdul Halim
I. Gaya, Umar
Ahmadzadeh, Saeid
Zakaria, Azmi
Shameli, Kamyar
Zainal, Zulkarnain
Jahangirian, Hossein
Yusof, Nor Azah
author_facet Abdollahi, Yadollah
Abdullah, Abdul Halim
I. Gaya, Umar
Ahmadzadeh, Saeid
Zakaria, Azmi
Shameli, Kamyar
Zainal, Zulkarnain
Jahangirian, Hossein
Yusof, Nor Azah
author_sort Abdollahi, Yadollah
collection UPM
description The present paper reports the UV-assisted degradation of 1,4-benzoquinone in ZnO suspensions. The variables studied include the concentration of 1,4-benzoquinone, photocatalyst, pH and the total organic carbon. The concentration of 1,4-benzoquinone and residue organic carbon were measured using UV-Visible spectrophotometer and TOC analyzer, respectively. The results showed that 1,4-benzoquinone photodegradation was independent of pH. The photoactivity of ZnO was maximum at 1.0 g L-1 concentration and at 100 mg L-1 1,4-benzoquinone levels. Within pH 4-10 more than 80% of 1,4-benzoquinone can be removed. ZnO has demonstrated reusability in the process.
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spelling upm.eprints-252232015-09-29T01:12:29Z http://psasir.upm.edu.my/id/eprint/25223/ Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension. Abdollahi, Yadollah Abdullah, Abdul Halim I. Gaya, Umar Ahmadzadeh, Saeid Zakaria, Azmi Shameli, Kamyar Zainal, Zulkarnain Jahangirian, Hossein Yusof, Nor Azah The present paper reports the UV-assisted degradation of 1,4-benzoquinone in ZnO suspensions. The variables studied include the concentration of 1,4-benzoquinone, photocatalyst, pH and the total organic carbon. The concentration of 1,4-benzoquinone and residue organic carbon were measured using UV-Visible spectrophotometer and TOC analyzer, respectively. The results showed that 1,4-benzoquinone photodegradation was independent of pH. The photoactivity of ZnO was maximum at 1.0 g L-1 concentration and at 100 mg L-1 1,4-benzoquinone levels. Within pH 4-10 more than 80% of 1,4-benzoquinone can be removed. ZnO has demonstrated reusability in the process. Sociedade Brasileira de Química, SBQ 2012 Article PeerReviewed application/pdf en http://psasir.upm.edu.my/id/eprint/25223/1/Photocatalytic%20degradaton%20of%201.pdf Abdollahi, Yadollah and Abdullah, Abdul Halim and I. Gaya, Umar and Ahmadzadeh, Saeid and Zakaria, Azmi and Shameli, Kamyar and Zainal, Zulkarnain and Jahangirian, Hossein and Yusof, Nor Azah (2012) Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension. Journal of the Brazilian Chemical Society, 23 (2). pp. 236-240. ISSN 0103-5053; ESSN:1678-4790 http://www.sbq.org.br/ 10.1590/S0103-50532012000200007 English
spellingShingle Abdollahi, Yadollah
Abdullah, Abdul Halim
I. Gaya, Umar
Ahmadzadeh, Saeid
Zakaria, Azmi
Shameli, Kamyar
Zainal, Zulkarnain
Jahangirian, Hossein
Yusof, Nor Azah
Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension.
title Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension.
title_full Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension.
title_fullStr Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension.
title_full_unstemmed Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension.
title_short Photocatalytic degradaton of 1,4-Benzoquinone in aqueous ZnO suspension.
title_sort photocatalytic degradaton of 1 4 benzoquinone in aqueous zno suspension
url http://psasir.upm.edu.my/id/eprint/25223/1/Photocatalytic%20degradaton%20of%201.pdf
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