Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate.
In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octahedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atom...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012
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| _version_ | 1825925735937736704 |
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| author | Begum, Thahira Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne |
| author_facet | Begum, Thahira Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne |
| author_sort | Begum, Thahira |
| collection | UPM |
| description | In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octahedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H(...)N hydrogen-bonding interactions. |
| first_indexed | 2024-03-06T08:02:13Z |
| format | Article |
| id | upm.eprints-25231 |
| institution | Universiti Putra Malaysia |
| language | English |
| last_indexed | 2024-03-06T08:02:13Z |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | upm.eprints-252312013-10-31T01:50:13Z http://psasir.upm.edu.my/id/eprint/25231/ Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. Begum, Thahira Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne In the title compound, [Zn(C20H16N3S2)2]·CH3CN, two different Schiff base moieties coordinate to the central ZnII ion as tridentate N,N′,S-chelating ligands, creating a distorted octahedral environment [the smallest angle being 73.24 (6)° and the widest angle being 155.73 (7)°], with the two S atoms in cis positions. The dihedral angle between the mean planes of the two coordinating ligands is 83.65 (5)°. The crystal packing is consolidated by weak C—H(...)N hydrogen-bonding interactions. International Union of Crystallography 2012 Article PeerReviewed Begum, Thahira and Omar, Siti Aminah and Mohamed Tahir, Mohamed Ibrahim and Crouse, Karen Anne (2012) Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. Acta Crystallographica Section E: Structure Reports Online, E68 (4). pp. 390-391. ISSN 1600-5368 http://www.iucr.org/ 10.1107/S1600536812009592 English |
| spellingShingle | Begum, Thahira Omar, Siti Aminah Mohamed Tahir, Mohamed Ibrahim Crouse, Karen Anne Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. |
| title | Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. |
| title_full | Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. |
| title_fullStr | Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. |
| title_full_unstemmed | Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. |
| title_short | Bis{S-benzyl 3-[(phenyl)(pyridin-2-yl)- methylidene]dithiocarbazato}zinc acetonitrile monosolvate. |
| title_sort | bis s benzyl 3 phenyl pyridin 2 yl methylidene dithiocarbazato zinc acetonitrile monosolvate |
| work_keys_str_mv | AT begumthahira bissbenzyl3phenylpyridin2ylmethylidenedithiocarbazatozincacetonitrilemonosolvate AT omarsitiaminah bissbenzyl3phenylpyridin2ylmethylidenedithiocarbazatozincacetonitrilemonosolvate AT mohamedtahirmohamedibrahim bissbenzyl3phenylpyridin2ylmethylidenedithiocarbazatozincacetonitrilemonosolvate AT crousekarenanne bissbenzyl3phenylpyridin2ylmethylidenedithiocarbazatozincacetonitrilemonosolvate |